Special issue on contamination,remediation and health for pollutants in natural aquatic,soil, sediments and atmospheric environments

Environmental Geochemistry and Health -     

Induction of cytochrome P4501A and endocrine disrupting effects of school incinerator residues

The emission of the dioxin-like compounds from on-site waste incinerators of seven schools in Kyonggi Province of Korea was evaluated by determination of the cytochrome P4501A(CYP1A) catalytic activity and antiestrogenic activity using cell culturemicrobioassay. The residue samples were extracted in a Soxhlet apparatus using toluene for 20 hr. The concentrated crude extractswere fractionated with a basic alumina column. Dioxin-like compounds were then extracted. Induction of CYP1A activity in a rat(H4IIE) hepatoma cell line was used as indicator of biologicaleffect of incinerator residues and measured as 7-ethoxyresorufin-O-deethylase(EROD) activities. The EROD activities of fraction II extracts (one of the two extracts) in the H4IIE cells were from 0.044±0.002 to 4.424±0.351 ng-TEQ g^-1 (TCDD Toxicity equivalent), showing relatively high inducing capacity. Antisetrogenicity of the extracts was measured as decrease in E₂-induced cell proliferation. Most of the extracts showed antiestrogenic activity in MCF7-BUS cell.The TEQ levels of the incinerator residues and the antiestrogenicactivities were in good correlation, strongly suggesting that thepotent toxic emissions were indeed produced from the on-site school waste semi-incinerators and could cause the antiestrogenicity.     

LIDAR Measurements of the Vertical Aerosol Profile and Optical Depth during the ACE-Asia 2001 IOP, at Gosan, Jeju Island, Korea

In order to investigate the characteristic of optical properties of Asian dust particles, the atmospheric aerosol vertical profile was measured with the multi-wavelength LIDAR system, at the Gosan super site (33 degrees 17'N, 126 degrees 10'E) in Jeju Island, Korea, during the ACE-Asia intensive observation period, 11 March-4 May 2001. An air mass backward trajectory analysis, using Hysplit-4, was carried out to track the aerosol plume, with high mass loading, from the Chinese desert regions during the period of Asian dust storm events. Vertical atmospheric aerosol profiles on three major Asian dust storm event days, 22 March and 13 and 26 April 2001, have been analyzed. The LIDAR-derived aerosol optical depth values were compared with those measured by a collocated sunphotometer.     

Tool wear of coated drills in drilling CFRP

This study aimed to investigate the wear of certain coated drills when drilling carbon fiber reinforced composites (CFRP). Three different drills were used in the drilling experiments: uncoated, diamond coated and AlTiN coated carbide (WC–Co) drills. The tool wear in CFRP machining was quite different from that in conventional metal machining. The primary wear type was a dulling or blunting of the cutting edge, which has been referred to as edge rounding wear or edge recession. In this paper, a hypothesis has been developed to explain the edge rounding wear in CFRP machining. Due to the fracture-based chip formation of CFRP, there is lack of the work material stagnation zone in front of the cutting edge, which normally prevents the edge wear in metal machining. Series of wear lead to rapid dulling of the cutting edge. The resistance to edge rounding wear on the coated as well as uncoated drills has been investigated. The diamond coating significantly reduces the edge rounding wear. However, AlTiN coated drills showed no visible improvement over the uncoated carbide drill, despite of their high hardness, thus not protecting the drill. The wear mechanisms of the uncoated carbide drill and coatings are discussed. It is believed that the 2-body and 3-body abrasive wear fail to explain the observed tool wear in CFRP drilling. However, the wear of the coatings and uncoated carbide substrate from tribo-meter tests correlated well with the tool wear in the CFRP drilling. Therefore, the tribo-meter test can be used to screen the prospective tool materials before carrying drilling experiment.     

Factors affecting the direct mineralization of CO2 with olivine

Olivine, one of the most abundant minerals existing in nature, is explored as a CO2 carbonation agent for direct carbonation of CO2 in flue gas. Olivine based CO2 capture is thermodynamically favorable and can form a stable carbonate for long-term storage. Experimental results have shown that water vapor plays an important role in improving CO2 carbonation rate and capacities. Other operation conditions including reaction temperature, initial CO2 concentration, residence time corresponding to the flow rate of CO2 gas stream, and water vapor concentration also considerably affect the performance of the technology.     

A study of compliance with environmental regulations of ISO 14001 certified companies in Korea

This article investigates the impact of ISO 14001 certification on the compliance with environmental regulations by Korean companies. The impact of ISO 14001 certification on the industry was studied through a questionnaire survey and the compliance of environmental regulations were investigated using government-released data. The motivation for an environment management system was a result of the current international situation and the need to maintain fair competition. ISO 14001 certification has been recognized as an essential strategy for industrial competition and to improve company/product recognition. The certified and non-certified companies' environmental regulation violation (ERV) rates were 3.5% and 11.6%, respectively, in 1997. In 1998, the ERV rate had an eight-time difference with 1.0% and 8.5% for certified and non-certified companies, respectively. Annual regulation violation rates were reduced from 3.5% in 1997 to 1.0% in 1998 with certified companies and from 11.6% in 1997 to 8.5% in 1998 with their non-certified counterparts, respectively. ISO 14001 certified companies showed more improvement than non-certified companies in regards to environmental performance.     

Development of vermicast from sludge and powdered oyster shell

Soil acidification is one of the rising land degradation issues facing world agriculture. The risk of acidification is currently being assessed as part of agriculture productivity and sustainable theme. This study was conducted to produce a new vermicomposting cast as a recycling resource derived from municipal sewage sludge and waste oyster shell. The earthworm, Eisenia Andrei, was fed under different conditions. The most suitable mixture was 77:23 w/w% of sewage sludge and waste oyster shell. Powdered oyster shell (POS) sludge blend provided a stable pH, due to its buffering capacity during vermiculture because of the Ca²⁺ and OH^? release effect. The vermicast products fulfilled the cast standards of Korea Ministry of Environment for all the parameters such as moisture content, pH, salinity, organic carbon, TKN, Phosphate, and heavy metals. Slowly released organic matter when added to soil improves the capacity of the soil to hold nutrients for plants, improve soil aeration for roots, and improves soil drainage. This product will be an addition to already-commercialized sludge vermicast as a higher value product.     

A new approach to characterize biodegradation of organics by molecular mass distribution in landfill leachate

This study provides biodegradability of organics in leachate according to their molecular mass distributions (<0.5, 0.5 to 1, 1 to 3, 10, and >10 KDa). Organics with molecular mass values lower than 0.5 KDa were the predominant species in the raw leachate filtrate, and the aerated lagoon process was very effective in treating these highly biodegradable organics; the Fenton's oxidation process was very effective in treating not-so-biodegradable organics with molecular mass values higher than 0.5 KDa, but a portion of these organics were converted into organics <0.5 KDa after Fenton's oxidation. An oxygen uptake measurement using a respirometer was more sensitive than a conventional biochemical oxygen demand measurement to evaluate bioactivities, especially when bioactivities were low.