Adsorption of 17β-estradiol from aqueous solution by raw and direct/pre/post-KOH treated lotus seedpod biochar

Five biochars derived from lotus seedpod(LSP) were applied to examine and compare the adsorption capacity of 17β-estradiol(E2) from aqueous solution.The effect of KOH activation and the order of activation steps on material properties were discussed.The effect of contact time,initial concentration,p H,ionic strength and humic acid on E2 adsorption were investigated in a batch adsorption process.Experimental results demonstrated that the pseudo second-order model fitted the experimental data best and that adsorption equilibrium was reached within 20 hr.The efficiency of E2 removal increased with increasing E2 concentration and decreased with the increase of ionic strength.E2 adsorption on LSP-derived biochar(BCs) was influenced little by humic acid,and slightly affected by the solution p H when its value ranged from 4.0 to 9.0,but considerably affected at p H 10.0.Low environmental temperature is favorable for E2 adsorption.Chemisorption,π–π interactions,monolayer adsorption and electrostatic interaction are the possible adsorption mechanisms.Comparative studies indicated that KOH activation and the order of activation steps had significant impacts on the material.Post-treated biochar exhibited better adsorption capacity for E2 than direct treated,pretreated,and raw LSP biochar.Pyrolyzed biochar at higher temperature improved E2 removal.The excellent performance of BCs in removing E2 suggested that BCs have potential in E2 treatment and that the biochar directly treated by KOH would be a good choice for the treatment of E2 in aqueous solution,with its advantages of good efficiency and simple technology.     

2006-2017年四川盆地MODIS气溶胶光学厚度时空变化特征

四川盆地地形复杂、气候特殊,是我国颗粒物污染高发地.为探究四川盆地气溶胶分布和周期变化特征,深入认识气溶胶污染特性及其气候效应,结合卫星遥感探测方法,利用2006-2017年MODIS C006 3 km AOD（气溶胶光学厚度）产品,分析了四川盆地AOD的时空特征.结果表明:①MODIS AOD（MODIS数据反演的气溶胶光学厚度）与太阳光度计CE318观测的AOD、ρ（PM_2.5）、ρ（PM₁₀）线性相关系数分别为0.78、0.77、0.75,表明MODIS C006 3 km AOD产品适用于四川盆地颗粒物污染研究.②四川盆地AOD平均值范围为0.1~1.3,其中,成都平原和四川盆地东南部地区是AOD高值（AOD值>1.0）中心,四川盆地周边高海拔区AOD均小于0.3.③2006-2017年AOD年均值范围为0~2.5,整体呈"倒N型"曲线下降,其峰值和谷值分别出现在2013年和2017年;2013年AOD大于1.0的区域占四川盆地的34.1%,是12 a中颗粒物污染最重的一年;2017年AOD小于0.3的面积占57.1%.④AOD季节性变化呈春季最大、夏季次之、秋季最小的特征.⑤AOD月变化呈"双峰型"波动特征,AOD月均值范围为0~2.5,其中,2-5月AOD月均值均大于0.7,8月AOD月均值为0.6,11-12月AOD月均值均小于0.5.研究显示,四川盆地颗粒物污染防治应以成都平原城市群和四川省南部城市群为主,应重点控制细颗粒物排放,合理安排工业企业的周期性生产强度.      

Application of PCR and probe hybridization techniques in detection of airborne fungal spores in environmental samples

Specific PCR amplification and probe hybridization techniques were applied to examine the compositions of airborne fungi in samples from three different environments. The results from microscopic and CFU counting were compared to those of the molecular-based detections. The detection sensitivity for PCR amplifications was 9 to 73 spores and 1.3 to 19.3 CFUs per PCR reaction. The hybridization detection limit was 2 to 4 spores and 0.2 to 1.2 CFU. The hybridization method was more sensitive than PCR amplification and showed less variation among samples. Using specific PCR primers and probes we identified the presence of several fungal groups and species in the air samples. Specific detections through probe hybridization to PCR products amplified with universal or group-specific fungal primers have promising applications in the examination of air samples for environmental monitoring.     

用等维灰色动态预测法预测大连湾污染物排放量

用少量数据建立的长期预测模型所得预测结果一出散性较大，本文介绍的等维灰色动态预测去弥补了这一缺陷。依据这一方法编制的“灰色原理应用系统”软件包，在获得预测结果的同时，还可得到预测值的变化过程及模型的相应参数，可即时对预测结果的可靠性作出判断。     

“华夏古陆”考异

自葛利普创名“华夏古陆”以来,经过半个多世纪的论辩与考订,对其地质构造属性,至今仍然否定与肯定交迭起伏,莫衷一是,本文从推覆构造,陆地漂移等实际资料着手,加以论证,认为它是经历深刻改造和发生巨大位移的变质岩断片体,地质构造属性已非“华夏古陆”原义。     

西辽河上游河水水质污染趋势分析与防治对策

文中利用市及旗县区监测站近几年监测数据对西辽河上游的污染程序进行了讨论 ,并进行了趋势分析 ,提出污染防治对策 ,旨在为辽河治理提供参考     

应用LDN-1氮氧化物脱除剂实现催化再生烟气NOx达标排放

独山子炼油厂催化裂化装置再生烟气中NOx含量达到1300-1400mg／m3(国家排放标准<420mg／m3),对周围环境造成严重影响。应用LDN-1氮氧化物脱除剂后,催化再生烟气中的NOx含量由1300-1400 mg／m3降至420 mg／m3以下,实现了达标排放。     

水深变化对波高与周期联合概率密度分布影响的分析

本文研究了水深的变化以波高与周期联合概率密度分布造成影响。本文将２３６组实测数据按水深因子Ｈ的大小进行了分组，分别对其进行了谱分析和统计分析，得到了各组数据的联合分布图。利用数值模拟的方法扩大水深因子的变化幅度，得到了模拟联合分布图。研究发现，水深因子的改变不会对联合分布构成大的影响，因此得现一般水的波高与周期联合概率密度分布模式适用于浅海的结论。     

Effect of domestic sewage on growth of phytoplankton-mathematical model

A mathematical model relating to the change in phytoplankton biomass in the period of growth and nutrient concentration in the media was proposed on the basis of the Monod equation and was testified by simulation experiments. Analysis of the experiment data showed that: the half-saturation constants for growth Kp (μmol/L) for Skeletonema, Chaetoceros and Prorocentrum were 5.52, 1.90 and 0.46, respectively; the balance between stimulation of nutrients and the inhibition of some other materials was found in the effect of domestic sewage on algal growth and the stimulation played a leading role; domestic sewage was more stimulative on dinoflag-ellate than on diatom and chlorophyte when the assemblage of the algae was cultured. The experiment suggested that mathematical model reasonably explained the characteristics of phytoplankton growth in different nutrient conditions and was worthy to be further improved for eutrophication prediction in off-shore water.     

Soil-plant nitrogen isotope composition and nitrogen cycling after biochar applications

Environmental Science and Pollution Research - Biochar has strong potential to improve nitrogen (N) use efficiency in both agricultural and horticultural systems. Biochar is usually co-applied with...