The Effects of Precipitation on Aquatic and Terrestrial Ecosystems: A Proposed Precipitation Chemistry Network

Precipitation is one of the most important factors determining the nature and productivity of terrestrial and aquatic ecosystems. Detailed historical and contemporary records are available indicating the amount of water deposited at thousands of locations throughout the world. Comparatively, however, knowledge of the changing chemistry of precipitation has developed only recently and is still very fragmentary. Our present ignorance of the total impact of changes in precipitation quality on the productivity and stability of ecosystems is especially profound. This paper has a fourfold purpose: (1) to describe the myriad of trace chemical constituents transferred from the atmosphere into the biosphere of the earth; (2) to define the range of beneficial and injurious ecological effects of perturbations in atmospheric deposition; (3) to explain the concepts of sensitive areas, life stages, and life forms; and (4) to describe briefly plans for a National Deposition Network and associated research on the terrestrial and aquatic ecosystems of the United States.     

Effects of marine biofouling on gas sensor membrane materials

The use of underwater gaseous sensors has increased rapidly in the last 10 years. The majority of such sensors employ a thin membrane through which the gas diffuses. These sensors are potentiometric gas-sensing probes and essentially they are ion-selective electrodes. The deployment time of these membranes is curtailed by the formation of biofouling on the membrane leading to erroneous results. The physical properties of a variety of commonly used membranes were investigated using SEM and AFM. This showed that there were differences in topography between the PTFE membranes, such as pore sizes and surface roughness, which may be attributed to the manner in which they are manufactured. The pore size of the PTFE membranes varied greatly, ranging from circular pores with a diameter of 500 nm to elongated pores measuring 1 x 22 microm. The contact angle of each membrane showed that they were all hydrophobic. The amount of fouling on each was also observed and its affect on oxygen diffusion was monitored. Fouling slowed down the response of the instrument and caused reduced diffusion through the membranes. The amount of fouling varied between the membranes with the YSI membrane fouling least. Some of the membranes tested did foul less than others and there could be lifetime advantages of choosing a membrane with a smoother surface and a small pore size.     

Reactive nitrogen and public policies for environmental protection

A core goal of both US and European pollution control policies has been to establish rules and regulations pertaining to the movement of reactive-nitrogen (Nr) through the environment. This is manifest in US federal legislation such as the Clean Air Act Amendments and the Clean Water Act Amendments and in various protocols of the United Nations Economic Commission for Europe (UNECE) and its Convention on Long-Range Transboundary Air Pollution (CLRTAP). In this paper, we begin by reviewing the two US laws and their effectiveness and make some comparisons with the approaches used mainly in Europe by the UNECE and CLRTAP. Next we use the Mississippi drainage/Gulf of Mexico hypoxia case study to highlight the importance of applying a "systems approach" to address the reactive nitrogen problem at the regional scale. After briefly posing a number of unanswered questions related to nitrogen control policies, we conclude by sketching a blueprint for future actions related to the development of improved policies to regulate reactive nitrogen.     

活性氮和世界:200年的变化

本文通过将19世纪后期和20世纪后期的氮流动情况进行对比,分析了食物和能源生产对全球氮循环的影响.我们虽然对人类产生的活性氮的数量及其释放到环境所产生的主要影响有了充分的认识,但是,我们对于环境库中氮的累积速度缺乏了解,由于积累在环境中的氮具有阶式效应,因此,对其在环境中的积累尚有不明之处.未来活性氮的产生、分布状况及其形成速度增加的可能性(尤其是在亚洲)存在巨大的区域性差异,因而需要制定"总活性氮措施",以优化食物和能源生产,保护环境系统.     

活性氮与环保公共政策

美国和欧洲污染治理政策的一个核心目标,是建立环境中活性氮运移的相关法规和条例.这表现在美国联邦政府的立法上(例如<清洁空气法修正案>和<清洁水法修正案>),以及联合国欧洲经济委员会的各种议定书及其<远程跨边界空气污染公约>上.本文中我们首先回顾一下美国的这两部法规及其实施效果,并将它们与联合国欧洲经济委员会和<远程跨边界空气污染公约>主要在欧洲采用的一些方法进行对比.然后利用密西西比河流域和(或)墨西哥湾氧过少的案例研究结果,重点讨论运用"系统分析方法"处理区域性活性氮问题的重要性.在列举了与氮治理政策有关的一些无法回答的问题后,我们在文末简要描述了在制定完善的活性氮管理政策过程中将要实施的行动计划.     

Meeting report

SUMMARY

In many developing countries, the determination of a ranking of investments designed to improve and extend the road system is a commonplace prerequisite of planning for the transport sector as a whole and the road sub-sector within it. A major objective of determining investment priorities is to secure the greatest efficiency in the use of resources allocated to the sector and, for this reason, any system of assigning priorities must rely upon conventional investment appraisal techniques producing quantifiable measures of worth. Exercises of this kind, in which road investments are identified and ranked, are usually undertaken to produce a road sector investment plan. The implementation of such plans is, however, often compromised because of perceived deficiencies with a methodology which places undue reliance on investment appraisal and fails to properly address the issue of public interest and sustainability. This paper attempts to produce a pragmatic set of ground rules which, while mindful of the need to promote economic efficiency, allow for other factors to be embraced in a more holistic methodology.     

DDT levels in human milk in Hong Kong, 2001-02

High levels of p,p'-DDT were detected in Hong Kong breast milk sampled in 1976 and 1985. Monitoring DDT levels in human breast milk in this region is important to identify trends in exposure. As part of the 2002-03 WHO/EURO coordinated exposure study, the concentrations of DDT and its metabolites were determined in 10 pooled milk samples classified by geographic origin and dietary history, comprising milk samples from 238 primiparous mothers giving birth in Hong Kong. Analysis was performed by Gas Chromatography (GC) with electron capture detector and confirmed by GC/Mass Spectrometry. The sum-DDT concentration (range: 0.92-2.05mg/kg fat) was age-dependent and indicated a decreasing trend since the 1970s. Mothers who recently came from mainland China had higher p,p'-DDT to p,p'-DDE ratios, suggesting a more recent exposure compared to women mainly residing in Hong Kong. The average Hong Kong sum-DDT level (1.50mg/kg fat) was among the highest of the contemporary levels (range: 0.12-1.97mg/kg fat; median: 0.40mg/kg fat) in the 16 countries/regions participating in the 2002-03 WHO/EURO exposure study. This is probably due to the previous extensive DDT exposure and continuing use of DDT in agriculture in mainland China. Despite the apparent decrease of DDT body load over 30 years, the environmental health hazard from DDT contamination in the Pearl River Delta region remains a concern. Measures to eradicate illegal use of DDT in mainland China and regular food monitoring programs are needed in the region. Despite the presence of DDT and other persistent organic pollutants in human breast milk, breastfeeding should continue to be strongly supported for its life-long benefits to infants.