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201.
Nicola Paltrinieri Alessandro Tugnoli Jonathan Buston Mike Wardman Valerio Cozzani 《Journal of Loss Prevention in the Process Industries》2013,26(4):683-695
The availability of a hazard identification methodology based on early warnings is a crucial factor in the identification of emerging risks. In the present study, a specific method named Dynamic Procedure for Atypical Scenarios Identification (DyPASI) was conceived as a development of bow-tie identification techniques. The main aim of the methodology is to provide a comprehensive hazard identification of the industrial process analysed, joined to a process of continuous improvement of the results of the assessment. DyPASI is a method for the continuous systematization of information from early signals of risk related to past events. The technique provides a support to the identification and assessment of atypical potential accident scenarios related to the substances, the equipment and the site considered, capturing available early warnings or risk notions. DyPASI features as a tool to support emerging risk management process, having the potentiality to contribute to an integrated approach aimed at breaking “vicious circles”, helping to trigger a gradual process of identification and assimilation of previously unrecognised atypical scenarios. 相似文献
202.
Silvia Nava Paolo Prati Franco Lucarelli Pier Andrea Mandò Alessandro Zucchiatti 《Water, Air, & Soil Pollution: Focus》2002,2(5-6):247-260
We describe the results of an aerosol sampling campaign performedin 1999 in the medium-size industrial town of La Spezia, in theNorthwest of Italy. We used two-stage continuous streakersamplers in three different sites and periods of the year. This kind of samplers allows the separation of the PM10 andPM2.2 fractions of the particulate matter. Moreover, the hourly resolution in the aerosol collection is particularly useful inan urban environment where, typically, many pollution sourceswith fast variations are present. Up to 1700 samples have beenanalysed by Particle Induced X-ray Emission (PIXE) at the INFNaccelerator facility in Florence, obtaining hourly concentrationfor about 20 elements from Na to Pb, with a sensitivity rangingfrom below 1 to about 10 ng m-3. The total hourly aerosolmass has been estimated with an optical analysis of the samesamples performed (before the PIXE analysis) by an equipment designed and mounted in Genoa. An extensive statistical analysisof the data included standard and Absolute Principal ComponentFactor Analysis (PCFA and APCFA) to deduce the compositionand the weight of the major aerosol sources in both fractions.Thorough different statistical approaches, we generally resolvedcontributions from vehicle emission, fossil fuel combustion,soil-road dust and sea salt aerosol. 相似文献
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204.
The great barracuda (Sphyraena barracuda) is a widespread, ecologically and socioeconomically important coastal fish, yet very little is known about its larvae. We
examined spawning and larval ecology of Western Atlantic sphyraenids using monthly ichthyoplankton samples collected over
2 years along a transect spanning the east–west axis of the Straits of Florida (SOF). Samples were dominated by the great
barracuda (92.8%) and sennets (Sphyraena borealis and Sphyraena picudilla; 6.6%). While larval sennets and S. barracuda displayed similar vertical distributions (majority in upper 25 m), horizontal and temporal patterns of abundance suggested
a spatial and temporal species replacement between larval S. barracuda and sennets that tracks adult ecology. The diet of both taxa consisted largely of copepods, with inclusion of fish larvae
at 8 mm SL, and in S. barracuda alone, a switch in the wet season to exclusive piscivory by 12 mm SL (18 days post-hatch). A lack of piscivory in S. barracuda larvae captured in the dry season corresponded to slower larval growth than in the wet season. Larval growth was also related
to size-at-hatch and larval age such that larvae that were larger at hatch or larger (older) at capture grew faster at earlier
ages, suggesting faster larval growth, and indirectly larger hatch size, conveys a survival advantage. Unlike larval growth,
instantaneous mortality rate did not differ with season, and no lunar cyclic patterns in spawning output were identified.
Our results provide insight into the pelagic phase of sphyraenids and highlight the importance of both diet and hatch size
to the growth and survival of fish larvae in low latitude oceanic environments. 相似文献
205.
Stavroula Tasiopoulou Alessandro M. Chiodini Francesca Vellere Sara Visentin 《Journal of environmental science and health. Part. B》2013,48(7):835-841
Organic agriculture, with its restrictions on the use of synthetic chemical inputs, seems to offer a low-residue alternative to conventional methods. In Europe, the Council Regulation n. 2092/91/EEC regulates the production and trade of organic products and foodstuffs; national and regional legislation in Italy gives specific guidance on the surveillance of organic agriculture. However, monitoring of specific chemical residues in organic foodstuffs is part of the regular controls on food, aiming to safeguard consumer's health. Monitoring programs are coordinated at the national level by the Ministry of Health and at local level by Regional authorities. In Lombardy, in accordance with the provisions of the General Directorate of Health of the Region and under the supervision of the 15 Local Health Units, a monitoring program of pesticide residues in food of plant origin is undertaken every year. The International Centre for Pesticides and Health Risk Prevention (ICPS), on behalf of the General Directorate of Health of the Region of Lombardy, has been collecting and elaborating the data resulting from the analysis of food samples, carried out by the local laboratories. During the period 2002–2005, a total of 3508 samples food of plant origin were analyzed for pesticide residues, among which were 266 samples of organic farming products. Commodities were classified into groups (citrus fruits, legumes, vegetables, potatoes, processed products, cereals, and fruit other than citrus) and the outcomes of the analyses were reported by year, origin of the sample and presence/absence of pesticide residues. Results showed that the vast majority of organic farming products were in conformity with the relevant legislation and did not contain detectable pesticide residues. A limited amount of samples had residues at concentration below the Maximum Residue Limit (MRL). Only in one sample the residue level was above the MRL, however it did not pose a concern for public health, as demonstrated by the outcomes of dietary risk assessment. Organic fruits and vegetables can be expected to contain fewer agrochemical residues than conventionally grown alternatives. There is a widespread belief that organic agriculture products are safer and healthier than conventional foods. It is difficult to come to conclusions, but what should be made clear to the consumer is that “organic” does not automatically equal “safe”. In the absence of adequate comparative data, additional studies in this area of research are required. 相似文献
206.
Water Security in Uzbekistan: Implication of Return Waters on the Amu Darya Water Quality 总被引:1,自引:0,他引:1
Crosa G Stefani F Bianchi C Fumagalli A 《Environmental science and pollution research international》2006,13(1):37-42
- DOI: http://dx.doi.org/10.1065/espr2006.01.007
Goal, Scope and Background Amu Darya river, one of the main water resources of Uzbekistan, shows a relevant longitudinal enrichment of soluble contents
which strongly limits the human uses of its waters. Because of the low natural run-off processes, salts and pollutants are
mainly driven to the river by the return waters used for washing and irrigating the surrounding lands. The influence of return
waters on stream quality is dramatically relevant in the lower reaches of the river where almost all the flowing waters have
been previously used for the agriculture practises. To provide analytical evidence on the potential effects of return waters
on the quality of the Amu Darya river, the paper reports and comments data on salinity and metals contents of the waters flowing
in the artificial channel network of Bukhara and in the Amu Darya river, from Bukhara up to the dam forming the Tuyamuyn Hydro
Complex (THC).
Methods A total of 15 sampling sites were selected for the analytical survey: Two sites were located on the Amu Darya river downstream
from the inflow of the return waters from Bukhara, two in the river entering in the THC, and three downstream from the dam
forming the reservoir complex. The waters entering and leaving the Bukhara agricultural area were sampled in two main collectors,
while the waters flowing in the channel system were sampled in six distinct collectors. The following parameters were considered
in the survey: pH, Oxygen, Hardness, Salinity, Conductivity, P-PO4 3–, P tot, N tot, N-NO3 2–, N-NO2 –, COD, Ca2+, Mg2+, Fe,
Mn, Zn, Cr, Cu, Ni, Cd, Pb.
Results and Discussion Salt concentrations below 1000 mg/l were measured in the Amu Darya waters upstream to Bukhara. In the drainage system, salinity
exceeds the palatability limit and reaches the maximum peak of 3200 mg/l in the outflow collector. Due to dilution effects,
salinity returns to lower values (400–700 mg/l) along the Amu Darya river downstream from Bukhara; calcium and magnesium resulted
the major constituents of the overall salinity. No serious metal contaminations were detected in the waters entering and leaving
the examined channel system. Differently, the Amu Darya waters upstream to the THC showed a relevant metal contamination,
with Cr, Ni, Fe concentrations exceeding the limits for human consumption. In the downstream sites, located in the Tuyamuyn
Hydro Complex and in the Amu Darya river flowing out from this reservoir, excluding Fe, all the examined metals showed lover
concentrations and values below the normative limits.
Conclusion The direct human consumption of the lower Amu Darya waters is strongly limited by salinity and by metal contamination. Although
the salinity of the return waters from the Bukhara drainage system results in above normal limits, no corresponding increases
were measured in the Amu Darya river downstream from the return water inflow at the time of the survey. As for the metal contamination
of the Amu Darya river, the survey revealed the presence of relevant sources of metal contamination downstream from Bukhara
external to the agricultural drainage system. This contamination resulted in reduced sedimentation processes taking place
in the limnetic zones of the Amu Darya river upstream to the dam forming the Tuyamuyn Hydro Complex.
Recommendation and Outlook To fully understand the longitudinal increase of Amu Darya salinity, an evaluation of the cumulative effects of the loads
from the main agricultural areas is required, also by using mass-balance models. As for the metals, an investigation should
be addressed to identify the anthropogenic sources of contaminations present in the lower Amu Darya region and the metal loads
should be diverted. 相似文献
207.
In situ solidification (ISS) is a reliable, EPA‐recognized technology for the treatment of industrial and waste sites. ISS was employed at a former manufactured gas plant (MGP) site in Macon, Georgia, for the treatment of approximately 33,000 cubic yards of coal tar residues in the saturated zone soil. The site is regulated by the Georgia Environmental Protection Division (EPD) under the Hazardous Site Rehabilitation Act (HSRA) and is located approximately four blocks from downtown Macon. This article will review the technical and regulatory basis for the successful use of this technology, provide an overview of the treatability and pilot testing used to develop the design and implementation of the treatment process, and present the results of the application of ISS to an MGP site. The results of groundwater monitoring, pre and postremediation, will also be discussed. © 2004 Wiley Periodicals, Inc. 相似文献
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210.
It is possible to calculate the exergy for organisms based on classic thermodynamics as already demonstrated by Mejer and Jorgensen [Mejer, H., Jorgensen, S.E., 1979. Exergy and ecological buffer capacity. State-of-the-art in Ecol. Model. 7, 829–846]. The calculation of exergy as eco-exergy, which is based on the information stored in the genome, has lately been proposed by Jørgensen and co-workers. Recently, Ludovisi [Ludovisi, A., 2009. Exergy vs information in ecological successions: interpreting community changes by a classical thermodynamic approach. Ecol. Model. 220, 1566–1577] has put forward a method based on classical thermodynamics, which leads to the calculation of “virtual” values of concentration at equilibrium for a number of organic compounds (VEC) and freshwater organisms (VECE). This paper compares the two approaches by analysing the correlation existing between the VECE- and the β-values derived by Jørgensen et al. [Jørgensen, S.E., Ladegaard, N., Debeljak, M., Marques, J.C., 2005. Calculations of exergy for organisms. Ecol. Model. 185, 165–175]. It was found that there was a good correlation, which can be useful for estimating β-values for organisms whose genome is not known in a sufficient detail. The relationship between VECE- and β-values suggests that two proposed thermodynamic orientors based on these quantities – the eco-exergy index and the structural information – should lead to coherent results when applied to the evaluation of the development state of ecosystems. A numerical simulation shows that this expectation is verified in a major case, but also that different, even opposite, responses can arise, depending on the biological composition of the biocoenosis investigated. 相似文献