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431.
Züttel A 《Die Naturwissenschaften》2004,91(4):157-172
Hydrogen exhibits the highest heating value per mass of all chemical fuels. Furthermore, hydrogen is regenerative and environmentally friendly. There are two reasons why hydrogen is not the major fuel of todays energy consumption. First of all, hydrogen is just an energy carrier. And, although it is the most abundant element in the universe, it has to be produced, since on earth it only occurs in the form of water and hydrocarbons. This implies that we have to pay for the energy, which results in a difficult economic dilemma because ever since the industrial revolution we have become used to consuming energy for free. The second difficulty with hydrogen as an energy carrier is its low critical temperature of 33 K (i.e. hydrogen is a gas at ambient temperature). For mobile and in many cases also for stationary applications the volumetric and gravimetric density of hydrogen in a storage material is crucial. Hydrogen can be stored using six different methods and phenomena: (1) high-pressure gas cylinders (up to 800 bar), (2) liquid hydrogen in cryogenic tanks (at 21 K), (3) adsorbed hydrogen on materials with a large specific surface area (at T<100 K), (4) absorbed on interstitial sites in a host metal (at ambient pressure and temperature), (5) chemically bonded in covalent and ionic compounds (at ambient pressure), or (6) through oxidation of reactive metals, e.g. Li, Na, Mg, Al, Zn with water. The most common storage systems are high-pressure gas cylinders with a maximum pressure of 20 MPa (200 bar). New lightweight composite cylinders have been developed which are able to withstand pressures up to 80 MPa (800 bar) and therefore the hydrogen gas can reach a volumetric density of 36 kg·m–3, approximately half as much as in its liquid state. Liquid hydrogen is stored in cryogenic tanks at 21.2 K and ambient pressure. Due to the low critical temperature of hydrogen (33 K), liquid hydrogen can only be stored in open systems. The volumetric density of liquid hydrogen is 70.8 kg·m–3, and large volumes, where the thermal losses are small, can cause hydrogen to reach a system mass ratio close to one. The highest volumetric densities of hydrogen are found in metal hydrides. Many metals and alloys are capable of reversibly absorbing large amounts of hydrogen. Charging can be done using molecular hydrogen gas or hydrogen atoms from an electrolyte. The group one, two and three light metals (e.g. Li, Mg, B, Al) can combine with hydrogen to form a large variety of metal–hydrogen complexes. These are especially interesting because of their light weight and because of the number of hydrogen atoms per metal atom, which is two in many cases. Hydrogen can also be stored indirectly in reactive metals such as Li, Na, Al or Zn. These metals easily react with water to the corresponding hydroxide and liberate the hydrogen from the water. Since water is the product of the combustion of hydrogen with either oxygen or air, it can be recycled in a closed loop and react with the metal. Finally, the metal hydroxides can be thermally reduced to metals in a solar furnace. This paper reviews the various storage methods for hydrogen and highlights their potential for improvement and their physical limitations. 相似文献
432.
Andreas Schierling Konrad Dettner Jürgen Schmidt Karlheinz Seifert 《Die Naturwissenschaften》2012,99(8):665-669
To protect themselves from predation and microorganismic infestation, rove beetles of the genus Stenus produce and store bioactive alkaloids like stenusine, 3-(2-methyl-1-butenyl)pyridine, and cicindeloine in their pygidial glands. The biosynthesis of stenusine and 3-(2-methyl-1-butenyl)pyridine was previously investigated in Stenus bimaculatus and Stenus similis, respectively. Both molecules follow the same biosynthetic pathway, where the N-heterocyclic ring is derived from l-lysine and the side chain from l-isoleucine. The different alkaloids are finally obtained by slight modifications of shared precursor molecules. The piperideine alkaloid cicindeloine occurs as a main compound additionally to (E)-3-(2-methyl-1-butenyl)pyridine and traces of stenusine in the pygidial gland secretion of Stenus cicindeloides and Stenus solutus. Feeding of S. solutus beetles with [D,15N]-labeled amino acids followed by GC/MS analysis techniques showed that cicindeloine is synthesized via the identical pathway and precursor molecules as the other two defensive alkaloids. 相似文献
433.
Andreas P. Modlmeier Tobias Pamminger Susanne Foitzik Inon Scharf 《Die Naturwissenschaften》2012,99(10):811-819
Adjusting to low temperatures is important for animals living in cold environments. We studied the chill–coma recovery time in temperate ant workers (Temnothorax nylanderi) from colonies collected in autumn and spring in Germany. We experimentally acclimated these ant colonies to cold temperatures followed by warm temperatures. As expected, cold-acclimated workers recovered faster from freezing temperatures, but subsequent heat acclimation did not change the short recovery times observed after cold acclimation. Hence, either heat acclimation improves cold tolerance, possibly as a general response to stress, or at least it does not negate enhanced cold tolerance following cold acclimation. Colonies collected in spring showed similar cold tolerance levels to cold-acclimated colonies in the laboratory. Next, we compared the chill–coma recovery time of different worker castes and found that exterior workers recovered faster than interior workers. This difference may be related to their more frequent exposure to cold, higher activity level, or distinct physiology. Interior workers were also heavier and showed a higher gaster-to-head ratio and thorax ratio compared to exterior workers. An obvious difference between exterior and interior workers is activity level, but we found no link between activity and cold tolerance. This suggests that physiology rather than behavioral differences could cause the increased cold tolerance of exterior workers. Our study reveals the importance of acclimation for cold tolerance under natural and standardized conditions and demonstrates differences in cold tolerance and body dimensions in monomorphic behavioral castes of an ant. 相似文献
434.
Greenhouse gas emissions from nitrogen fertilizer use in China 总被引:2,自引:0,他引:2
Fredrich Kahrl Yunju Li Yufang Su Timm Tennigkeit Andreas Wilkes Jianchu Xu 《Environmental Science & Policy》2010,13(8):688-694
The use of synthetic nitrogen (N) fertilizers is an important driver of energy use and greenhouse gas (GHG) emissions in China. This paper develops a GHG emission factor for synthetic N fertilizer application in China. Using this emission factor, we estimate the scale of GHG emissions from synthetic nitrogen fertilizer use in Chinese agriculture and explore the potential for GHG emission reductions from efficiency improvements in N fertilizer production and use. The paper concludes with a discussion on costs and financing for a large-scale fertilizer efficiency improvement program in China, and how a GHG mitigation framework might contribute to program design. 相似文献
435.
Petra Quillfeldt Andreas Michalik Gritta Veit-Köhler Ian J. Strange Juan F. Masello 《Marine Biology》2010,157(9):2043-2050
Central place foragers are constrained in their foraging distribution by the necessity to return to their nest site at regular
intervals. In many petrels that feed on patchily distributed prey from the sea surface over large foraging areas, alternating
long and short foraging trips are used to balance the demands of the chick with the requirements of maintaining adult body
condition. When the local conditions are favourable for prey density and quality, adults should be able to reduce the number
of long foraging trips. We studied the flexibility in foraging trip lengths of a small pelagic petrel, the thin-billed prion
Pachyptila belcheri, over three breeding seasons with increasingly favourable, cold-water conditions. During a warm-water influx in February
2006, chicks were fed less frequently and adults carried out foraging trips of up to 8 days. When conditions became more favourable
with colder water temperatures in 2007 and 2008, thin-billed prions decreased trip lengths, more often attended their chick
every day, and long foraging trips of six to eight days were not registered during 2008. Chick growth rates mirrored this,
as chicks grew poorly during 2006, intermediate during 2007 and best during 2008. Thin-billed prions preyed mainly on squid
during incubation and mainly on amphipods and euphausiids during chick-rearing. In the poorest season only, the diet was substantially
supplemented with very small copepods. Together, the present results indicate that during warm-water conditions, thin-billed
prions had difficulties in finding sufficient squid, amphipods or euphausiids and were forced to switch to lower trophic level
prey, which they had to search for over large ocean areas. 相似文献
436.
Mooshammer M Wanek W Schnecker J Wild B Leitner S Hofhansl F Blöchl A Hämmerle I Frank AH Fuchslueger L Keiblinger KM Zechmeister-Boltenstern S Richter A 《Ecology》2012,93(4):770-782
Resource stoichiometry (C:N:P) is an important determinant of litter decomposition. However, the effect of elemental stoichiometry on the gross rates of microbial N and P cycling processes during litter decomposition is unknown. In a mesocosm experiment, beech (Fagus sylvatica L.) litter with natural differences in elemental stoichiometry (C:N:P) was incubated under constant environmental conditions. After three and six months, we measured various aspects of nitrogen and phosphorus cycling. We found that gross protein depolymerization, N mineralization (ammonification), and nitrification rates were negatively related to litter C:N. Rates of P mineralization were negatively correlated with litter C:P. The negative correlations with litter C:N were stronger for inorganic N cycling processes than for gross protein depolymerization, indicating that the effect of resource stoichiometry on intracellular processes was stronger than on processes catalyzed by extracellular enzymes. Consistent with this, extracellular protein depolymerization was mainly limited by substrate availability and less so by the amount of protease. Strong positive correlations between the interconnected N and P pools and the respective production and consumption processes pointed to feed-forward control of microbial litter N and P cycling. A negative relationship between litter C:N and phosphatase activity (and between litter C:P and protease activity) demonstrated that microbes tended to allocate carbon and nutrients in ample supply into the production of extracellular enzymes to mine for the nutrient that is more limiting. Overall, the study demonstrated a strong effect of litter stoichiometry (C:N:P) on gross processes of microbial N and P cycling in decomposing litter; mineralization of N and P were tightly coupled to assist in maintaining cellular homeostasis of litter microbial communities. 相似文献
437.
Movements and site fidelity of the giant manta ray, <Emphasis Type="Italic">Manta birostris,</Emphasis> in the Komodo Marine Park,Indonesia 总被引:2,自引:1,他引:1
Heidi Dewar Peter Mous Michael Domeier Andreas Muljadi Jos Pet Jeff Whitty 《Marine Biology》2008,155(2):121-133
Despite their large size and frequent occurrence in near-shore tropical habitats, little published information is available
on the movements and behaviors of the giant manta ray, Manta birostris, and what factors influence visitation patterns. To examine the movements of manta rays in the Komodo Marine Park, Indonesia,
an acoustic array was installed at up to seven sites in the park between 2000 and 2003. A total of 41 acoustic tags were deployed
in three separate deployments in 2000, 2001 and 2002. Mantas were recorded in the park for up to 526 days with an average
duration of 183 ± 136 days, when mantas made from 3 to 303 individual visits to different sites (median 58 visits). There
was a clear preference for three sites that comprised over 90% of manta activity. The most popular site (German Flag) was
off the southern tip of Komodo Island in an area with a high degree of bathymetric structure. Examination of the longest records
suggests some site preference with 5 of 7 individuals spending greater than 90% of their time at the location where they were
tagged. Using a general linear model it was possible to examine the effects of daytime, lunar phase, aggregation site, season
and tidal phase on visitation patterns. The vast majority of visits were recorded during daylight hours at all sites. The
strongest effects of both the lunar and tidal phase were apparent in the northern sites with the most visits occurring when
tidal intensity was the greatest during full and new moons. The strongest seasonal pattern was observed in the south where
no mantas were recorded during the first quarter in any year. This coincides with an increase in temperature and reduction
of productivity in this region associated with monsoonal shifts. The long-term fidelity indicates that marine-protected areas
centered around aggregation sites could help protect this species from overexploitation. 相似文献
438.
Specialized bees fail to develop on non-host pollen: do plants chemically protect their pollen? 总被引:1,自引:0,他引:1
Bees require large amounts of pollen for their own reproduction. While several morphological flower traits are known to have evolved to protect plants against excessive pollen harvesting by bees, little is known on how selection to minimize pollen loss acts on the chemical composition of pollen. In this study, we traced the larval development of four solitary bee species, each specialized on a different pollen source, when reared on non-host pollen by transferring unhatched eggs of one species onto the pollen provisions of another species. Pollen diets of Asteraceae and Ranunculus (Ranunculaceae) proved to be inadequate for all bee species tested except those specialized on these plants. Further, pollen of Sinapis (Brassicaceae) and Echium (Boraginaceae) failed to support larval development in one bee species specialized on Campanula (Campanulaceae). Our results strongly suggest that pollen of these four taxonomic groups possess protective properties that hamper digestion and thus challenge the general view of pollen as an easy-to-use protein source for flower visitors. 相似文献
439.
Darwin's meticulous observations on the function of floral shape led to his famous prediction of a long-tongued pollinator, which he believed to be the evolutionary trigger for the long-spurred flowers of the Madagascar star orchid. Although tubular flowers are common, long tubes or spurs are an exception, suggesting that selection maintaining short flowers is widespread. Using the butterfly-pollinated carnation Dianthus carthusianorum and two butterfly species differing in proboscis length (Melanargia galathea and Inachis io) as model organisms, we experimentally demonstrate a reduction in pollinator efficiency with an increasing difference between proboscis length and floral tube length. Such a relationship is a prerequisite for the evolution of floral shape in response to pollinator morphology. 相似文献
440.
Loretta Müller Pierre Comte Jan Czerwinski Markus Kasper Andreas C.R. Mayer Adrian Schmid 《毒物与环境化学》2013,95(1):164-180
The aim of this study was to compare the cytotoxicity and the (pro-)inflammatory responses of two-stroke (direct injection and carburetor technology) and four-stroke scooter and diesel car exhaust emissions on lung cells in vitro. This was analyzed by exposing a 3D in vitro model of the epithelial airway (consisting of human bronchial epithelial cells (cell line 16HBE14o?) combined with human whole blood monocyte-derived macrophages and dendritic cells) to physically characterized exhaust emissions. Biological endpoints of cytotoxicity (lactate dehydrogenase release), as well as pro-inflammatory cytokine (tumor necrosis factor (TNF)-α) and inflammatory chemokine (interleukin(IL)-8) stimulation were examined. Two-stroke direct injection scooter exhaust contained the highest particle number concentration and nitrogen oxides (NO x ) concentrations and the emissions from the two-stroke carburetor scooter contained the highest hydrocarbon and lowest NO x concentrations. The four-stroke scooter emitted the highest carbon monoxide concentration whereas the cars emitted the lowest. The combination of various technical optimizations for the two-stroke direct injection scooter (particle filter, oxidative catalyst, better oil and fuel) reduced the total emissions strongly and the TNF-α concentration significantly (p?0.05). The cytotoxicity and the IL-8 concentration showed strong tendencies to be reduced. The analysis of the emissions of all tested two-stroke, four-stroke scooters and diesel cars showed a strong association between the adverse effects and the particle number concentration. 相似文献