A study of the distribution of lead, cadmium and copper between water and kaolin, bentonite and a river sediment

Experiments were carried out to monitor the equilibrium distribution of lead, cadmium and copper between an aqueous phase modelling natural water and a solid phase modelling natural sediment, under varying conditions. The aqueous phase was analysed using ETAAS and differential pulse anodic stripping voltammetry (DPASV), whereas XRD and FTIR were used to study the solid phase. Sorption isotherms at constant pH were measured. Conditional distribution constants were calculated as functions of the pH, the time of equilibration and the amount of solid material. The results obtained stress the need for standardization of the approaches to the study of water-sediment interactions in order to be able to evaluate and compare the extensive data from field measurements and to predict these interactions.     

HNO_3─KI─MIBK萃取／原子吸收光谱法测定固体废物浸提液中的微量银

采用选择性较好的ＨＮＯ３—ＫＩ—ＭＩＢＫ萃取体系对铋渣和尾矿渣浸出液中的痕量银进行预分离富集后，用火焰原子吸收法（ＡＡＳ）进行测定。此法不仅变异系数小（约为３．１％），而且检出限比直接火焰ＡＡＳ法降低两个数量级，达０．５ｎｇ／ｍｌ．另外，还就作品细度对银测定结果的影响原因做了初步探讨。     

库仑滴定法测定一氧化碳

本文就一氧化碳的测定条件和CO氧化过程中氧化剂的选择进行了研究。试验表明:ReAO_4-Ⅱ为氧化CO的活性催化剂,转化率可达100％(在300℃以上),本法简便,可用于空气中一氧化碳的测定和催化剂对CO活性测试。     

多介质环境目标值的应用

本文概述了多介质目标德的SAM/Ⅰ的方法。多介质目标值包括环境目标值和排放目标值。点源分析包括SAM/ⅠA,SAM/ⅠB,SAM/Ⅰ,SAM/Ⅱ。在缺少环境质量标准的情况下,使用多介质环境目标值有较强的适用性,且具有省时、省力、经济等特点。本文将多介质目标值的SAM/ⅠA点源分析方法引入聚氯乙烯生产废水的环境评价中,取得较为满意的结果。     

Adsorption of zinc on manganite(γ-MnOOH): particle concentration effect and adsorption reversibility

The adsorption and desorption processes of Zn(Ⅱ) on τ-MnOOH as a function of particle concentrations (Cp) were studied. An obvious Cp effect was observed in this adsorption system. The degree of adsorption hysteresis increased greatly with the increasing of Cp, indicating that the extent of the real metastable-equilibrium states deviating from the ideal equilibrium state was enhanced with the increasing of Cp. The Cp-reversibility relationship confirmed the metastable-equilibrium adsorption (MEA) inequality (Pan, 1998a), which was the core formulation of the MEA theory. Because the MEA inequality was based on the basic hypothesis of MEA theory that adsorption densitιy ι is not a state variable, the Cp-reversibility relationship gave indirect evidence to the basic hypothesis of MEA theory.     

三维虚拟地理环境构建与应用

可量测三维虚拟地理环境是数字地球应用的基础平台。本文研究了三维虚拟地理环境构建空间几何建模与纹理建模关键技术。提出了一种适用于大规模生产建库的可量测三维虚拟地理环境构建的生产工艺模型和三维虚拟模型数据获取的方法。介绍了三维虚拟地理环境在城市规划、房产经营管理等方面的应用。     

分光光度法测定雨水中微量过氧化氢的研究

本文提出了以钛（ＩＶ） 过氧化氢 ２ （３，５ 二溴 ２ 吡啶偶氮） ５ 二乙氨基苯酚（３，５ ｄｉＢｒ ＰＡＤＡＰ）三元配合物体系光度测定雨水中微量过氧化氢的方法，该方法简便，灵敏度和选择性较高，所得结果令人满意     

Preparation of rare-earth metal complex oxide catalysts for catalytic wet air oxidation

Catalytic wet air oxidation (CWAO) is one of the most promising technologies for pollution abatement. Developing catalysts with high activity and stability is crucial for the application of the CWAO process. The Mn/Ce complex oxide catalysts for CWAO of high concentration phenol-containing wastewater were prepared by coprecipitation. The catalyst preparation conditions were optimized by using an orthogonal layout method and single-factor experimental analysis. The Mn/Ce serial catalysts were characterized by Brunauer-Emmett-Teller (BET) analysis and the metal cation leaching was measured by inductively coupled plasma torch-atomic emission spectrometry (ICP-AES). The results show that the catalysts have high catalytic activities even at a low temperature (80°C) and low oxygen partial pressure (0.5 MPa) in a batch reactor. The metallic ion leaching is comparatively low (Mn<6.577 mg/L and Ce<0.6910 mg/L, respectively) in the CWAO process. The phenol, COD_Cr, and TOC removal efficiencies in the solution exceed 98.5% using the optimal catalyst (named CSP). The new catalyst would have a promising application in CWAO treatment of high concentration organic wastewater. Translated from Techniques and Equipment for Environmental Pollution Control, 2005, 6(2): 40–44 [译自: 环境污染治理技术与设备]     

排放系数法估算污染物排放总量

掌握污染物总量动态变化情况，采用排放系统法进行估算是有效的方法。利用１９９５年上海乡镇工业污染调查数据对排放系数进行验证，说明应如何选用排放系数。     

Removal of high concentrated ammonia nitrogen from landfill leachate by landfilled waste layer

The landfill of municipal solid waste(MSW) could be regarded as denitrification reactor and involved in ammonia nitrogen biological removal process. In this research, the process was applied to municipal solid waste collected in Shanghai, China, which was characterized by high food waste content. The NH4^ removal efficiency in the system of SBR nitrifying reactor followed by fresh and matured landfilled waste layer in series was studied. In the nitrifying reactor, above 90% of NH4^ in leachate was oxidized to NO2^- and NO3^- . Then high concentrated NO2^- and NO3^- were removed in the way of denitrification process in fresh landfilled waste layer. At the same time, degradation of fresh landfilled waste was accelerated. Up to the day 120, 136.5 gC/(kg dry waste) and 17.9 gN/(kg dry waste) were converted from waste layer. It accounted for 50.15 % and 86.89 % of the total carbon and nitrogen content of preliminary fresh waste, which was 4.42 times and 5.17 times higher than that of reference column respectively. After filtering through matured landfilled waste, BOD5 concentration in leachate dropped to below 100 mg/L, which would not affect following nitrification adversely. Because the matured landfilled waste acted as a well methanogenic reactor, 23% of carbon produced accumulatively from fresh landfilled waste degradation was converted into CH4.