Levels of dioxins, furans and PCBs in human serum and milk of people living in Greece

In an attempt to evaluate the background levels of polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), non-ortho, mono-ortho and indicator polychlorinated biphenyls (PCBs) in people living in an urban (Athens) and a rural (Kozani) area of Greece, blood serum and mother milk samples were analyzed. Analytical results are reported in this study. Statistically significantly differences were observed between regions, sexes and ages. Contamination levels in blood and human milk from Greece reported here are low compared to the previously reported dioxin data from other European countries and give no indication of particular health risk.     

Factors affecting accident severity inside and outside urban areas in Greece

Objectives: This research aims to identify and analyze the factors affecting accident severity through a macroscopic analysis, with a focus on the comparison between inside and outside urban areas. Disaggregate road accident data for Greece for the year 2008 were used. Methods: Two models were developed, one for inside and one for outside urban areas. Because the dependent variable had 2 categories, killed/severely injured (KSI) and slightly injured (SI), the binary logistic regression analysis was selected. Furthermore, this research aims to estimate the probability of fatality/severe injury versus slight injury as well as to calculate the odds ratios (relative probabilities) for various road accident configurations. The Hosmer and Lemeshow statistic and other diagnostic tests were conducted in order to assess the goodness-of-fit of the model. Results: From the application of the models, it appears that inside urban areas 3 types of collisions (sideswipe, rear-end, with fixed object/parked car), as well as involvement of motorcycles, bicycles, buses, 2 age groups (18-30 and older than 60?years old), time of accident, and location of the accident, seem to affect accident severity. Outside urban areas, 4 types of collisions (head-on, rear-end, side, sideswipe), weather conditions, time of accident, one age group (older than 60?years old), and involvement of motorcycles and buses were found to be significant. Conclusions: Factors affecting road accident severity only inside urban areas include young driver age, bicycles, intersections, and collision with fixed objects, whereas factors affecting severity only outside urban areas are weather conditions and head-on and side collisions, demonstrating the particular road users and traffic situations that should be focused on for road safety interventions for the 2 different types of networks (inside and outside urban areas). The methodology and the results of this research may provide a promising tool to prioritize programs and measures to improve road safety in Greece and worldwide.     

Re-Establishing a Sustainable Wetland at Former Lake Karla,Greece, Using Ramsar Restoration Guidelines

Lake Karla, Greece, was almost completely drained in 1962 both to protect surrounding farmlands from flooding and to increase agricultural area. Loss of wetland functions and values resulted in environmental, social, and economic problems. A number of restoration plans were proposed to address these problems. The plan approved by the government in the early 1990s proposed construction of a 4200-ha reservoir solely to improve water storage and flood attenuation functions. However, the Ramsar Scientific and Technical Review Panel states that the primary goal of any restoration project is to create resilient and sustainable ecosystems, as measured on a human timescale, in order to improve the ecological character and enhance the socioeconomic role that the wetland plays in the watershed. This study utilizes Ramsar guidelines for sustainable restoration of Lake Karla. Eight additional restoration measures are proposed based on functional analysis of the wetland to enhance additional wetland functions and support multiple values for humans and nature.     

Evaluation of the pollution of the surface waters of Greece from the priority compounds of list II, 76/464/EEC directive, and other toxic compounds

The pollution of the surface waters of Greece from the priority compounds of 76/464/EEC Directive was evaluated. The occurrence of 92 toxic compounds, 64 of which belong to priority compounds of List II, candidates for List I, of 76/464/EEC Directive, was studied in surface waters and wastewater through the developed network of 62 sampling stations, which covers the whole Greek territory. The analytical determination was performed by Purge and Trap-Gas chromatography-Mass spectrometry for volatile and semivolatile organic compounds (VOCs), Gas Chromatography-Electron Capture Detection for organochlorine insecticides, Gas Chromatography-Nitrogen Phosphorous Detection for organophosphorous insecticides, High Performance Liquid Chromatography-Photodiode Array Detection for herbicides, and Electrothermal Atomic Absorption Spectrophotometry and Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) for metals and the toluene extractable organotin compounds. The concentrations of VOCs and insecticides detected in the surface waters of Greece were very low, whereas the concentrations of herbicides and metals ranged generally at moderate levels. VOCs were detected almost exclusively in the rivers and very rarely in the lakes, while the frequency of occurrence of insecticides, herbicides and metals was similar for rivers and lakes. Water quality objectives (WQO) and emission limit values (ELV) have been laid down in national legal framework for a number of compounds detected in the samples, in order to safeguard the quality of surface waters from any future deterioration.     

Investigation of powered 2-wheeler accident involvement in urban arterials by considering real-time traffic and weather data

Objective: Understanding the various factors that affect accident risk is of particular concern to decision makers and researchers. The incorporation of real-time traffic and weather data constitutes a fruitful approach when analyzing accident risk. However, the vast majority of relevant research has no specific focus on vulnerable road users such as powered 2-wheelers (PTWs). Moreover, studies using data from urban roads and arterials are scarce. This study aims to add to the current knowledge by considering real-time traffic and weather data from 2 major urban arterials in the city of Athens, Greece, in order to estimate the effect of traffic, weather, and other characteristics on PTW accident involvement.

Methods: Because of the high number of candidate variables, a random forest model was applied to reveal the most important variables. Then, the potentially significant variables were used as input to a Bayesian logistic regression model in order to reveal the magnitude of their effect on PTW accident involvement.

Results: The results of the analysis suggest that PTWs are more likely to be involved in multivehicle accidents than in single-vehicle accidents. It was also indicated that increased traffic flow and variations in speed have a significant influence on PTW accident involvement. On the other hand, weather characteristics were found to have no effect.

Conclusions: The findings of this study can contribute to the understanding of accident mechanisms of PTWs and reduce PTW accident risk in urban arterials.     

Investigation of Cr(VI) reduction in continuous-flow activated sludge systems

The aim of this research was to investigate hexavalent chromium, Cr(VI), reduction by activated sludge and to evaluate the use of continuous-flow activated sludge systems for the treatment of Cr(VI)-containing wastewater. Three series of experiments were conducted using two parallel lab-scale activated sludge systems. During the first experiment, one system was used as a control, while the other received Cr(VI) concentrations equal to 0.5, 1, 3 and 5mg l(-1). For all concentrations added, approximately 40% of the added Cr(VI) was removed during the activated sludge process. Determination of chromium species in the dissolved and particulate phase revealed that the removed Cr(VI) was sorbed by the activated sludge flocs mainly as trivalent chromium, Cr(III), while the residual chromium in the dissolved phase was mainly detected as Cr(VI). Activated sludge ability to reduce Cr(VI) was independent of the acclimatization of biomass to Cr(VI) and it was not affected by the toxic effect of Cr(VI) on autotrophic and heterotrophic microorganisms. During the second experiment, both systems were operated under two different hydraulic residence time (theta equal to 20 and 28h) and three different initial organic substrate concentration (COD equal to 300, 150 and 0mg l(-1)). Cr(VI) reduction was favored by an increase of theta, while it was limited by influent COD concentration. Finally, at the last experiment the effect of anoxic and anaerobic reactors on Cr(VI) reduction was investigated. It was observed that the use of an anoxic zone or an anaerobic-anoxic zone ahead of the aerobic reactor favored Cr(VI) reduction, increasing mean percentage Cr(VI) reduction to almost 80%.     

Toxic and essential trace elements in human milk from Greek lactating women: association with dietary habits and other factors

The aim of this study was to determine the concentration of some essential and toxic metals in the colostrum and transitory human milk in conjunction with various factors that may influence their concentrations i.e. diet, supplementation, place of residence, smoking, as well as socioeconomic and somatometric characteristics. Zinc, iron, copper, manganese, cadmium and lead were measured by AAS in 180 colostrum samples from healthy lactating women collected on third day postpartum. A second milk sample was collected in 95 (53%) subjects 14 days later. Dietary habits were assessed by a 7-day food frequency questionnaire and various characteristics and socio-economic factors were also recorded. The mean (+/-standard deviation) values of colostrum samples were: Zn 4905 +/- 1725 microg l(-1), Fe 544 +/- 348 microg l(-1), Mn 4.79 +/- 3.23 microg l(-1), Cu 381 +/- 132 microg l(-1), Cd 0.190 +/- 0.150 microg l(-1), Pb 0.48 +/- 0.60 microg l(-1). All metals with the exception of copper were found in lower concentrations in transitory samples. Cadmium and lead weekly intakes were found to be below the Maximum Tolerable Weekly Intakes as they have been established for infants by WHO or NRC. Our results revealed: higher Pb concentration in the samples from urban areas; effect of smoking on Cu level; dietary habits seem to play a role in metal levels in human milk as the logistic regression models revealed.     

Assessing risk of and adaptation to sea-level rise in the European Union: an application of DIVA

This paper applies the DIVA model to assess the risk of and adaptation to sea-level rise for the European Union in the 21st century under the A2 and B1 scenarios of the Intergovernmental Panel on Climate Change. For each scenario, impacts are estimated without and with adaptation in the form of increasing dike heights and nourishing beaches. Before 2050, the level of impacts is primarily determined by socio-economic development. In 2100 and assuming no adaptation, 780?×?10³ people/year are estimated to be affected by coastal flooding under A2 and 200?×?10³ people/year under B1. The total monetary damage caused by flooding, salinity intrusion, land erosion and migration is projected to be about US$ 17?×?10⁹ under both scenarios in 2100; damage costs relative to GDP are highest for the Netherlands (0.3% of GDP under A2). Adaptation reduces the number of people flooded by factors of 110 to 288 and total damage costs by factors of 7 to 9. In 2100 adaptation costs are projected to be US$ 3.5?×?10⁹ under A2 and 2.6?×?10⁹ under B1; adaptation costs relative to GDP are highest for Estonia (0.16% under A2) and Ireland (0.05% under A2). These results suggest that adaptation measures to sea-level rise are beneficial and affordable, and will be widely applied throughout the European Union.     

Arsenic and Other Metal Contamination of Groundwaters in the Industrial Area of Thessaloniki, Northern Greece

In groundwater, used for drinking water supply in the greater industrial area of Thessaloniki, in Northern Greece, concentrations of total arsenic exceeded the WHO provisional guideline value and the EU maximum contaminant level (MCL) of 10 μg/L. The concentration of total arsenic was in the range between 4–130 μg/L, whereas the median value was 36 μg/L and the average concentration 46 μg/L. Nine out of the eleven wells contained total arsenic at concentration higher than 10 μg/L and it should be stressed that 6 of them contain arsenic at concentrations between 10 (new MCL) and 50 μg/L (previous MCL). The examined groundwaters were found to contain elevated concentrations of manganese and phosphate. Arsenic had a positive correlation with the pH, indicating the possible effect of pH on arsenic mobilisation. These findings emerge the problem of contamination from arsenic, since, according to the EU directive 98/83, all drinking water sources within the European Union should have achieved compliance with the new limits by 12/2003, implying that the situation requires urgent remedial action.     

Case studies on summertime measurements of O3, NO2, and SO2 with a DOAS system in an urban semi-industrial region in Athens, Greece

The objective of this study is to analyze the concentrations of SO₂, NO₂, and O₃ measured by a Differential Optical Absorption Spectroscopy (DOAS) system that was operating at the campus of Technological Education Institute of Piraeus during 2008 and 2009 warm periods (July to September) in relation to the prevailing meteorological conditions. The DOAS system was operating in a particularly polluted area of the West part of Attica basin on a continuous basis, measuring the concentration levels of the main pollutants (O₃, NO₂, and SO₂) as well as aromatic hydrocarbon substances (benzene, toluene, and xylene). According to the analysis, the SO₂ concentration levels at this measuring site are rather high and this may be attributed to the characteristics of this measuring site. Proximity of roadways and local circulation are just some of the factors that can affect the concentration levels of monitoring of pollutant concentrations such as NO₂ and surface ozone. The results provide evidence for the occurrence of an atmospheric phenomenon that produces higher ozone concentrations during weekends despite lower concentrations of ozone precursors. This phenomenon is known as the weekend effect.