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111.
Atsushi Terazono Yuichi Moriguchi Shin-ichi Sakai Hiroshi Takatsuki 《Journal of Material Cycles and Waste Management》2000,2(2):80-88
This study evaluated the environmental impacts of sprayed-on asbestos, which had been used as insulation material in buildings,
from multiple perspectives, mainly at the disposal stage. The health risks from asbestos emission and energy consumption were
estimated. Two disposal scenarios were assumed for the asbestos: melting for reduced-risk disposal and ordinary packaging/landfilling.
We estimated the asbestos emission and health risk in the case of packaging/landfilling, assuming uncontrolled management
of the landfill site. A difficulty with introducing health-risk concepts into life cycle assessment (LCA) is the pulse–flux
problem, which is discussed in the light of these estimations. In order to solve this problem, we proposed a method using
a conversion factor representing exposure-dose/emission, and showed that emission could be converted into health risk. We
also estimated the energy consumption for melting asbestos in the disposal stage, which can decrease the health risk. If we
consider the energy consumption for the life cycle of asbestos, only a little energy is required for melting, compared with
the large amount of energy saved in the use stage owing to the insulating effect of the asbestos. The trade-off relationship
between health risk and energy consumption for the disposal scenarios indicated the need for weighting methods to handle trade-offs
such as this.
Received: July 2, 1998 / Accepted: December 20, 1999 相似文献
112.
Aikawa M Hiraki T Tamaki M Kasahara M Kondo A Uno I Mukai H Shimizu A Murano K 《Environmental monitoring and assessment》2006,122(1-3):61-79
An intensive field survey, with 6-h measurement intervals, of concentrations of chemical species in particulate matter and gaseous compounds was carried out at coastal sites on the Sea of Japan during winter. The concentration variation of SO2(g) and HNO3(g) were well correlated, whereas the NH3(g) concentration variation had no correlation with those of SO2(g) and HNO3(g). The NH4
+ (p)/non-sea-salt- (nss-)SO4
2 −(p) ratio in particulate matter was mainly affected by the location of the sampling site. One or more concentration peaks of nss-Ca2 + for survey period were observed. Backward trajectories analyses for the highest nss-Ca2 + concentration peaks showed some inconsistency in pathways. We consider that insufficient mixing of the atmosphere and/or insufficient time for the transported air pollutants to react with those discharged locally are the most likely explanations for the discrepancies between the measured products [HNO3][NH3] and the calculated values. 相似文献
113.
Tomoyuki Imai Toshiki Matsui Yasuhiko Fujii Tasuku Nakai Suminori Tanaka 《Journal of Material Cycles and Waste Management》2001,3(2):103-109
A new iron oxide catalyst, which has a superior oxidation activity in carbon monoxide and polyethylene (PE) combustion, was
synthesized by an aqueous solution reaction. Catalytic oxidation of carbon monoxide over six kinds of hematite obtained from
the goethite was done using a microcatalytic pulse reactor, and the composition of the hematite with the highest oxidation
activity was determined. With the aim of suppressing dioxin formation on combustion, incineration tests of solid wastes in
PE refuse bags with and without the goethite were carried out using a commercial semibatch-type incinerator with a combustion
chamber of 6.2 m3. The result confirmed that the concentration of dioxins in the flue gas decreased considerably when the refuse was incinerated
in PE bags manufactured with goethite.
Received: July 24, 2000 / Accepted: October 18, 2000 相似文献
114.
Takahiro Ishizaka Susumu Tohno Chang-Jin Ma Atsushi Morikawa Masaki Takaoka Fumitaka Nishiyama Kouhei Yamamoto 《Atmospheric environment (Oxford, England : 1994)》2009,43(16):2550-2560
During the transboundary transport of anthropogenic heavy metals by mineral particles providing reaction sites, the divalent metal salt PbSO4 can be converted to PbCO3 in the presence of water. We carried out laboratory experiments to study the transformation process under various conditions by incorporating test particles comprising CaCO3 of a particulate mineral component, PbSO4, and NaCl. After the immersion of PbSO4 particles in contact with CaCO3 particles in a water droplet, the conversion of PbSO4 into PbCO3 was confirmed by the change in morphology of the original particles to stick or needle form; the percentages of the chemical forms relative to the total Pb were determined by X-ray absorption near edge structure (XANES) analysis. Approximately 60–80% of PbSO4 was converted to PbCO3 after 24 h. A small amount of stick particles was detected when NaCl particles attached to PbSO4/CaCO3 particles were exposed to air with a relative humidity (RH) of 80–90% for 24 h. XANES measurements of the samples revealed that the molar percentage of PbCO3 relative to the total Pb content was 4%.Field experiments were also conducted to determine the chemical forms of the Pb particles during the Kosa (Asian dust storm) event. Samples were collected from two remote sites in Japan and Korea. The mass size distribution of Pb aerosols collected in Japan was bimodal with two peaks in the coarse mode; the enrichment factor of Pb suggested that its source was anthropogenic. Pb L3 edge XANES measurements of both samples indicated that they had similar shapes. These measurements also indicated that the major Pb components for the samples collected in Japan were PbO, PbSO4 PbCl2, and PbCO3, with molar percentages of 44%, 30%, 21%, and 5%, respectively. No significant differences were found between the component ratios of the samples collected in Japan and Korea, suggesting that definite transformation did not occur during the transport of the Kosa particles from Korea to Japan. On the basis of these observations, we postulate that the transformation process either occurred mainly before the particles arrived at Korea or did not take place after the particles left continental Asia. 相似文献
115.
Noriyoshi Kakuta Atsushi Shimizu Hironobu Ohkita Takanori Mizushima 《Journal of Material Cycles and Waste Management》2009,11(1):23-26
The dehydrochlorination behavior of plasticizer (DOP) and inorganic filler (CaCO3) contained in PVC samples and the properties of the activated carbons produced from those carbon residues have been investigated.
In the dehydrochlorination process, both additives contributed not only to a decrease in HCl yield but also to the prolonged
evolution of HCl. Part of the Cl species were observed to be stabilized as CaCl2 by reaction with calcium ions when CaCO3 was added. More than 80% of chlorine removal was achieved in all samples at 533 K. The use of potassium as an activation
agent led to the production of activated carbon with a specific surface area greater than 1000 m2/g at the low temperature of 1023 K and assisted also in the elimination of residual Cl species by the formation of KCl during
activation.
Chemical Feedstock Recycling & Other Innovative Recycling Techniques 6 相似文献
116.
Comparative survey of levels of chlorinated cyclodiene pesticides in breast milk from some cities of China, Korea and Japan 总被引:2,自引:0,他引:2
Exposure of mothers to organochlorine pesticides (OCPs) was assessed by measuring the levels of 20 OCPs in 70 human breast milk samples pooled from 210 individuals from China, Korea and Japan. The OCPs were analyzed using gas chromatography/mass spectrometry (GC/MS) in electron capture negative ionization (ECNI) monitoring. The results showed that β-hexachlorocyclohexane and hexachlorobenzene were one order of magnitude higher in China than in the other nations, whereas chlordanes and polychlorinated biphenyl levels were highest in Japan. Heptachlor epoxide, dieldrin, endrin, toxaphenes and mirex were detected in most samples, and levels of these chemicals were significantly higher in Japan (0.8-4.5 ng g−1 lipid), followed by Korea (0.2-4.7 ng g−1 lipid), and lowest in China (less than 1.0 ng g−1 lipid). α- and β-endosulfans were detected at a range of 0.9-1.5 ng g−1 lipid levels in all samples analyzed, and their levels were higher in Korean than in Chinese samples. 相似文献
117.
Suzuki Y Nakamura M Otsuka Y Suzuki N Ohyama K Kawakami T Sato K Kajita S Hishiyama S Fujii T Takahashi A Katayama Y 《Chemosphere》2011,83(6):868-872
We characterized the ability of the cell free extract from polychlorinated dibenzo-p-dioxins degrading bacterium Geobacillus sp. UZO 3 to reduce even highly chlorinated dibenzo-p-dioxins such as octachlorodibenzo-p-dioxins in incineration fly ash. The degradation of 2,7-dichlorodibenzo-p-dioxin (2,7-DCDD) as a model dioxin catalyzed by the cell free extract from this strain implicates that the ether bonds of 2,7-DCDD molecule undergo reductive cleavage, since 4′,5-dichloro-2-hydroxydiphenyl ether and 4-chlorophenol were detected as intermediate products of 2,7-DCDD degradation. 相似文献
118.
Anaerobic biodegradation of 4-alkylphenols in a paddy soil microcosm supplemented with nitrate 总被引:1,自引:0,他引:1
Anaerobic degradation of phenol, p-cresol, 4-n-propylphenol (n-PP), 4-i-propylphenol (i-PP), 4-n-butylphenol (n-BP) and 4-sec-butylphenol (sec-BP) was observed in a paddy soil supplemented with nitrate. We detected the metabolites 4′-hydroxypropiophenone (HPP) from n-PP, 4-i-propenylphenol from i-PP, and 4-(1-butenyl)phenol and 4′-hydroxybutyrophenone (HBP) from n-BP. Compared with the original soils, Betaproteobacteria became predominant in the microcosm during the degradation of phenol and p-cresol whereas no remarkable change was observed in the community degrading propylphenols and butylphenols. The microcosm, however, did not degrade 4-t-butylphenol (t-BP), 4-t-octylphenol (t-OP) and 4-n-octylphenol (n-OP). Paddy soil supplemented with sulfate or iron (III) as electron acceptors did not degrade phenol and 4-alkylphenols with the exception of the degradation of p-cresol in sulfate-reducing conditions. It was demonstrated for the first time that anaerobic microbial degradation of alkylphenols, in a paddy soil supplemented with nitrate as an electron acceptor, occurred via oxidation of the alpha carbon in the alkyl chain. 相似文献
119.
Masami Fukushima Xuefei Tu Apichaya Aneksampant Atsushi Tanaka 《Journal of Material Cycles and Waste Management》2018,20(1):176-184
Parameters that affect the degree of humification for humic substances (HSs) are deeply related to the maturity of the compost. In general, the matured composts contain HSs with a higher degree of humification. In addition, microbial activities during composting are also one of the indices for compost maturation. Branched-chain fatty acids are metabolites as the result of microbial activities in a soil environment. Such branched-chain fatty acids, regarded as humic precursors, are incorporated into HSs during the composting process. To determine whether branched-chain fatty acids in HSs can be used as biomarkers during composting processes or not, HSs were extracted from three types of composts with the different maturation, and the branched-chain fatty acids in the HSs were analyzed by pyrolysis–gas chromatography/mass spectrometry with tetramethylammonium hydroxide (TMAH-py–GC/MS). HSs with a higher degree of humification (higher aromaticity and lower molecular weight) contained higher levels of branched-chain fatty acids. These results show that branched-chain fatty acids in HSs from matured compost samples can be used as biomarkers, which indicate the history of microbial activities during overall composting process. 相似文献
120.
Adsorption of 2,4-dichlorophenoxyacetic acid by an Andosol 总被引:1,自引:0,他引:1
To identify the important soil components involved in 2,4-dichlorophenoxyacetic acid (2,4-D) adsorption on Andosols, 2,4-D adsorption on a surface horizon of an Andosol was compared with that on hydrogen peroxide (H2O2)-treated (soil organic matter [SOM] was removed), acid-oxalate (OX)-treated (active metal hydroxides and SOM were removed), and dithionite-citrate-bicarbonate (DCB)-treated (free and active metal [hydr]oxides and SOM were removed) soil samples at equilibrium pHs ranging from 4 to 8. Although the untreated soil contained a large amount of organic C (71.9 g kg-1), removal of SOM had little effect on 2,4-D adsorption. Active surface hydroxyls, which were attached to the active and free metal (hydr)oxides and metal SOM complexes, were identified as the most important soil functional group for 2,4-D adsorption. The dominant mechanism of the 2,4-D adsorption was a ligand exchange reaction in which the carboxylic group of 2,4-D displaced the active surface hydroxyl associated with metals and formed a strong coordination bond between the 2,4-D molecule and soil solid phase. The ligand exchange reaction reasonably accounted for the selective adsorption of 2,4-D over Cl-, competitive adsorption of phosphate over 2,4-D, reduction in plant-growth-inhibitory activity of soil-adsorbed 2,4-D, and the high 2,4-D adsorption ability of Andosols. Although a humic acid purified from the soil did not adsorb 2,4-D, the presence of the humic acid increased 2,4-D adsorption on Al and Fe, probably by inhibiting the hydrolysis and polymerization of Al and Fe resulting in the preservation of available adsorption sites on these metals. The adsorption behavior of 2,4-D on soils could be a good index for predicting the adsorption behavior of other organic acids in soils. 相似文献