Struvite precipitation by the dissolved CO2 degasification technique: impact of the airflow rate and pH

In the present work, struvite precipitation was provoked by the dissolved CO(2) degasification technique where precipitation occurred following the degassing of the CO(2) by atmospheric air. The impact of the airflow rate and initial solution pH on struvite precipitation were assessed. For initial solution pH<6.5, no precipitation was observed. For initial solution pH>6.5, the phosphorus removal through struvite precipitation could be improved by increasing the airflow rate up to 25 L min(-1), or by increasing the initial pH for higher airflow rates. Compared to traditional techniques of struvite precipitation such as stirring and aeration, the dissolved CO(2) degasification technique is promising since a high amount of phosphorus (approximately 78%) could be removed at relatively short experiment time.     

中国酸雨控制政策初步评估研究

采用环境政策评估的一般模式,通过构建包括评估目标、评估标准等在内的评估框架,对我国现有酸雨控制政策进行了初步的评估。结果表明,中国酸雨控制政策体系已经初步建立,不仅促进了燃煤火电厂脱硫工程的建设,为SO2排放控制奠定了工程基础,还使单位燃煤量SO2排放量得到降低。但并没有实现排放总量的绝对降低,酸沉降范围仍有扩大趋势,发生重酸雨城市的数量也在增加。主要原因是:现有的地方政府负责的管理体制设计缺乏酸雨外部性的考虑,管理成本大;燃煤火电厂脱硫装置的运行和SO2排放量的削减缺乏有效的政策手段来保证,减排成本较高。现行的政策手段中,事前控制手段由于不具有过程控制的功能,未能有效遏制SO2的排放;总量控制和排放标准的政策对象没有明确界定,无法实现边际减排;排污收费在地方政府与企业利益高度一致的背景下,刺激减排的效果一般;脱硫电价补贴作为刺激减排的经济制度,并未直接对脱硫量进行补贴,而是对上网脱硫电量实行补贴,补贴对象针对性不强。建议实施以排污许可证制度为核心的排放控制政策体系,并将排放控制政策向过程和源头延伸;同时改革排污收费制度,使其成为规费辅助排污许可证制度的实施;建议由国家环保部直接负责酸雨控制,包括燃煤火电厂的环评审批、排污许可证的发放和实施。     

基于GIS淹没模型的城市道路内涝灾害风险区划研究

在求取襄阳中心城区重现期雨量与可抽排雨量的基础上,采用基于GIS暴雨洪涝淹没模型计算不同重现期致灾雨量的淹没水深和范围;依据城市内涝对道路的实际影响,制作城市道路内涝灾害风险区划图。结果表明,该方法能够直观表达研究区域内不同雨量阈值的内涝灾害淹没风险分布,定量评估淹没水深、淹没范围。同时给出了城市道路内涝灾害风险区划图,结合城市道路信息,准确定位高风险易涝街区,为政府部门决策提供科学依据。     

Synthesis of carbon-coated magnetic nanocomposite (Fe3O4@C) and its application for sulfonamide antibiotics removal from water

The occurrence of antibiotics in the environment has recently raised serious concerns regarding their potential threat to human health and aquatic ecosystem. A new magnetic nanocomposite, Fe304@C （Fe304 coated with carbon）, was synthesized, characterized, and then applied to remove five commonly-used sulfonamides （SAs） from water. Due to its combinational merits of the outer functionalized carbon shell and the inner magnetite core, Fe3O4@C exhibited a high adsorption affinity for selected SAs and a fast magnetic separability. The adsorption kinetics of SAs on Fe304 @ C could be expressed by the pseudo second-order model. The adsorption isotherms were fitted well with the Dual-mode model, revealing that the adsorption process consisted of an initial partitioning stage and a subsequent hole-filling stage. Solution pH exerted a strong impact on the adsorption process with the maximum removal efficiencies （74% to 96%） obtained at pH 4.8 for all selected SAs. Electrostatic force and hydrogen bonding were two major driving forces for adsorption, and electron-donor-acceptor interactions may also make a certain contribution. Because the synthesized Fe304@C showed comprehensive advantages of high adsorptivity, fast magnetic separability, and prominent reusability, it has potential applications in water treatment.     

含Br-废水高级氧化过程AOX生成特性研究

在焦化废水中投加Br^-模拟含Br^-难降解废水,研究UV/H₂O₂和UV/PDS两种高级氧化工艺在实现TOC优化去除条件下可吸附有机卤素（Adsorbable Organic Halogens,AOX）的生成特性.通过响应曲面法优化反应条件,实现废水中TOC高效去除,但Br^-浓度从50 mg·L^-1增至150mg·L^-1时,UV/H₂O₂和UV/PDS出水AOX浓度分别从0.56 mg·L^-1和0.65 mg·L^-1升高至1.44 mg·L^-1和1.63 mg·L^-1,远高于进水AOX浓度(0.08mg·L^-1);对活性卤代成分（RHS）稳态浓度的模拟结果表明UV/PDS中RHS浓度总体高于UV/H₂O₂,是造成二者出水AOX浓度区别的重要原...     

An agenda for assessing and improving conservation impacts of sustainability standards in tropical agriculture

Sustainability standards and certification serve to differentiate and provide market recognition to goods produced in accordance with social and environmental good practices, typically including practices to protect biodiversity. Such standards have seen rapid growth, including in tropical agricultural commodities such as cocoa, coffee, palm oil, soybeans, and tea. Given the role of sustainability standards in influencing land use in hotspots of biodiversity, deforestation, and agricultural intensification, much could be gained from efforts to evaluate and increase the conservation payoff of these schemes. To this end, we devised a systematic approach for monitoring and evaluating the conservation impacts of agricultural sustainability standards and for using the resulting evidence to improve the effectiveness of such standards over time. The approach is oriented around a set of hypotheses and corresponding research questions about how sustainability standards are predicted to deliver conservation benefits. These questions are addressed through data from multiple sources, including basic common information from certification audits; field monitoring of environmental outcomes at a sample of certified sites; and rigorous impact assessment research based on experimental or quasi‐experimental methods. Integration of these sources can generate time‐series data that are comparable across sites and regions and provide detailed portraits of the effects of sustainability standards. To implement this approach, we propose new collaborations between the conservation research community and the sustainability standards community to develop common indicators and monitoring protocols, foster data sharing and synthesis, and link research and practice more effectively. As the role of sustainability standards in tropical land‐use governance continues to evolve, robust evidence on the factors contributing to effectiveness can help to ensure that such standards are designed and implemented to maximize benefits for biodiversity conservation.     

Distribution and assessment of heavy metal toxicity in sediment cores from Bizerte Lagoon,Tunisia

To examine the state of pollution of Bizerte Lagoon which is exposed to intense anthropogenic pressure, two sediment cores were taken at two sites, one undergoes the dual effects of both marine waters arriving from the Mediterranean Sea through the Channel, and also of freshwater from the Tinja River; the other core is located at the center of the lagoon where water depth is maximal (12 m). Heavy metal concentrations in the two cores were assessed, with calculated enrichment factors and geo-accumulation indexes. Core sediments were also studied for chemical speciation and their monosulfide contents were measured. Results from enrichment factors and geo-accumulation indexes show an accumulation of Cd, Zn, Cr, and Pb, while chemical speciation revealed a risk only from Cd and Mn. Comparison of sequential extraction values with those of acid volatile sulfides revealed that non-toxic effects may be caused by any of the studied metals in the sediment.     

鄱阳湖区国土资源综合评价和开发整治战略

本文在鄱阳湖区国土资源综合评价的基础上,提出了开发整治的战略。鄱阳湖区自然资源比较丰富,开发潜力大。但是,由于洪涝干旱等自然灾害比较频繁,经济结构不合理,商品生产不发达,人口增长率高,科技文化比较落后,环境恶化等原因,影响了湖区经济的发展。为了开发整治鄱阳湖区,本文提出了整治洪涝灾害,充分发挥湖泊水资源优势;优化经济和产业结构,合理利用国土资源,充分发挥湖区农业优势;严格控制人口增长,增加智力投资,提高人口素质,促进科技进步等战略问题。     

钦州湾近20 a来水环境指标的变化趋势Ⅰ平水期营养盐状况

根据 198 3、1990年和 1998～ 1999年平水期 (春、秋季 )的调查资料 ,分析了钦州湾水域的营养盐状况及其与环境因子的关系。结果表明 :本湾营养盐含量变化显著 ,无机氮呈明显递增趋势 ,无机磷则与此相反 ,而活性硅的最低值则出现在浮游植物量最高的 1990年度 ;相关分析显示 ,陆源输入的多寡和浮游植物的丰度是导致本湾N、P、Si含量变化的主要因素 ;Si/N/P值分析则体现了本湾从明显N限制到显著P限制的演化规律 ,而Si限制状态只有在浮游植物异常丰富的情况下才出现 ;通过营养状态综合指数计算 ,表明本湾水体已由明显贫营养状态上升为中营养和富营养状态