A previously reported dry ashing procedure for the decomposition of marine samples prior to arsenic determination is demonstrated to be equally applicable to the analysis of selenium. Quantitative recovery of selenium as inorganic or organic compounds in a variety of plants and animal tissues is demonstrated using 75Se tracer and X-ray fluorescence techniques. The dry ashing procedure is simpler than the official AOAC method, which uses a mixture of H2SO4, HNO3 and HC10(4). 相似文献
Two different species of photosynthetic microalgae, Chlorella pyrenoidosa and Scenedesmus sp., were grown in settled and activated sewage filtrates at two different inoculum sizes, aimed to reduce nutrient load from wastewater. Higher growth rates were recorded in cultures with higher inoculum size, and algal cells usually grew better in settled sewage than in activated sewage. As algae started to grow and multiply, both nitrogen and phosphorus content in wastewater decreased significantly. The removal rate was rapid during the first week of growth and more than 2/3 of wastewater N and P was reduced. After the initial period, the removal rate slowed down. At the end of this study, more than 80% of total-P and inorganic N present in settled sewage were reduced but such removal efficiency was lower in activated sewage. In general, high inoculum size of algal cells provided more N and P removal than low inoculum, and Chlorella cells performed better than Scenedesmus. These results suggest that cultivation of Chlorella seems to be one of the feasible methods to reduce the amount of nitrogen and phosphorus entering the nearby coastal water, thus preventing the eutrophication problem. It is also clear that algal ponds with high inoculum size might be more suitable to be installed as a secondary rather than a tertiary treatment process. 相似文献
It is obvious that the application of solid waste compost improves the soil fertility. These wastes, however, may also have some negative effects on the agricultural environment due to their metal content. This research aimed at evaluating the influence of Tunisian municipal solid waste compost and farmyard manure on some chemical properties and the distribution of heavy metals in a calcareous Tunisian soil (clayey–loamy soil). A field plot experiment, without vegetation, was installed since 1999 at the experimental farm of the Agronomic National Institute of Tunis (INAT) in the region of Mornag (20 km south of Tunis, Tunisia). During 5 years, the field received yearly the following treatments: 0, 40, 80 and 120 t/ha of municipal solid waste compost and 0, 40 and 120 t/ha of manure. The fractionation of heavy metals in the soil was evaluated after 5 years using a sequential extraction procedure. The application of the two amendments was found to increase the content of organic matter, the total nitrogen content and the electrical conductivity, whereas it slightly decreased the soil pH. The addition of manure did not have a significant effect on the accumulation of heavy metals in the soil, whereas compost application increased the total concentration of heavy metals in the soil. The distribution of heavy metals between the different fractions in untreated and treated soils showed the residual fraction to be dominant, followed by the fraction bound to Fe and Mn oxides. The amount of Cu bound to the organic fraction increased with the application rate, which is probably caused by the formation of organic complexes. For the other metals, the increase of the association with organic matter is very limited. The application of compost moreover increases the amount of Zn associated with Fe and Mn oxides. The “Mobility Factor (MF)” was quite low and did not change after the 5-year application of the two organic amendments. It always remained lower than 10%, although for Cd it amounted to 17%. 相似文献
Small- and medium-sized enterprises (SMEs) form the core of societal and economic development. However, most people query on the implementation and performance of environmental management. In this paper, the manufacturing SMEs in Northern China with different pollution levels are studied to explore the main forces (e.g., government, society, market, and enterprise itself) driving SMEs for promoting environmental management. It focuses on the correlation between environmental management and economic performance for SMEs at different pollution levels. The results show that SMEs of different pollution levels have significant differences in the relationship of driving forces and performance. First, for SMEs with high-pollution levels, social and market driving forces and government incentives are revealed having a significant effect on their environmental performance. Driving forces from within the enterprise itself and the market provide a positive effect on the economic performance, while social forces have a negative effect. Second, for SMEs with light pollution, social and market driving forces, and government assistance play a supporting role on corporate environmental performance improvement. It is also found that the driving force of the enterprise itself does not have a significant effect on the environmental performance for SMEs with different pollution levels. In addition, the environmental performance and economic performance for SMEs with high or light-pollution levels are positively correlated. Further, it shows that the environmental performance is moderately correlated with financial indices, but not significantly with the non-financial indices. 相似文献
The interaction between zinc and cadmium was investigated in tomato plants (Solanum lycopersicum). Ten-day-old seedlings were treated with 10 μmol/L CDC12 associated to different concentrations of ZnC12 (10, 50, 100, and 150 μmol/L). Zn supply clearly reduced Cd accumulation in leaves and simultaneously increased Zn concentration. Cd induced oxidative stress in leaves as indicated by an increase in thiobarbituric acid-reactive substances (TBARS) level and chlorophyll breakdown. Furthermore, compared with control, Cdtreate plants had significantly higher activities of superoxide dismutase (SOD, EC 1.15.1.1), whereas, catalase (CAT, EC 1.111.1.6),ascorbate peroxidase (APX, EC 1.11.1.11), and glutathione reductase (GR, EC 1.6.4.2) activities were significantly suppressed by Cd addition. Zn supplementation, at low level, restored and enhanced the functional activity of these enzymes (SOD, CAT, APX and GR) as compared to Cd-alone-treated plants. The beneficial effect of adequate Zn level on Cd toxicity was confirmed by a significant decrease in TBARS level and restoration of chlorophyll content. However, when Zn was added at high level in combination with Cd there was an accumulation of oxidative stress, which was higher than that for Cd or excess Zn alone treatments. These results suggested that higher Zn concentrations and Cd are synergistic in their effect on plant growth parameters and oxidative stress. 相似文献
This paper applies vulnerability assessment methodology to assess the comparative vulnerability of different tourism supply types by region in Hungary. The steps of the methodology include (1) definition of tourism supply typology, (2) identifying exposure indicators, (3) identifying sensitivity indicators, (4) identification of adaptive capacity indicators and (5) developing a vulnerability map. It is clear that climate change has potential negative effects on tourism in Hungary, but the spatial distribution, as well as the sub-sectoral (by tourism supply types) differences of these impacts is almost unknown. Most research papers dealing with the vulnerability of tourism mainly focus on a specific tourism type, whereas this article aims to address all of them from a regional point of view. The key results presented in this paper include the vulnerability map of the country showing the relative vulnerability of different tourism supply types and detailed analysis investigating the possible causes and driving factors. We have categorized tourism regions based on the five most vulnerable tourism supply types. The most significant of them all turned out to be outdoor event-based tourism, being the most vulnerable in the two southern regions, since the expected impacts of climate change are foreseen to be the most significant in these areas. 相似文献
The insecticide 14C-chlorpyrifos was found mineralized in a Tunisian soil with repeated exposure to it. From this soil, a bacterial strain was isolated that was able to grow in a minimal salt medium (MSM) supplemented with 25 mg L?1 of chlorpyrifos. It was characterized as Serratia rubidaea strain ABS 10 using morphological and biochemical analyses, as well as 16S rRNA sequencing. In a liquid culture, the S. rubidaea strain ABS 10 was able to dissipate chlorpyrifos almost entirely within 48 h of incubation. Although the S. rubidaea strain ABS 10 was able to grow in an MSM supplemented with chlorpyrifos and dissipate it in a liquid culture, it was not able to mineralize 14C-chlorpyrifos. Therefore, it can be concluded that the dissipation capability of this bacteria might be attributed to its capacity to adsorb CHL. It can also be ascribed to other reasons such as the formation of biogenic non-extractable residues. In both non-sterile and sterile soil inoculated with S. rubidaea strain ABS 10, chlorpyrifos was more rapidly dissipated than in controls with DT50 of 1.38 and 1.05 days, respectively.