不饱和季铵盐的合成及其聚合物在化工及环保领域的应用

按不饱和基团的类型对不饱和季铵盐进行了分类,并综述了其合成方法。介绍了其聚合物在含油污水处理、抗菌、纺织品、新材料等领域的应用。阐述了在不饱和季铵盐的开发及其聚合物的应用方面存在的问题。指出了今后的发展方向:应该加大科研投入,加快新型不饱和季铵盐的研发进程,特别是在主结构设计、纯度提高以及新型絮凝剂单体的多样性方面,以制备出多功能性的单体和聚合物。     

Emotional appeal in recruitment advertising and applicant attraction: Unpacking national cultural differences

We investigated the impact of the type of emotional appeal (ego‐focused vs. other‐focused) used in recruiting advertisements on applicant attraction to firms through two experimental studies across three countries (the United States, China, and Singapore). In Study 1, we made a traditional cultural comparison between the United States and China, whose dominant cultural values are characterized by individualism and collectivism, respectively. We found applicants in the United States were more strongly attracted to firms whose recruiting advertisements were based on an ego‐focused emotional appeal, while applicants in China were more attracted to firms that used ads with an other‐focused emotional appeal. Study 2 was conducted in bicultural Singapore. We primed bicultural applicants to be either the individualistic or collectivistic aspect of their cultural heritage. Applicants with individualist priming were attracted to recruiting advertisements with an ego‐focused emotional appeal, whereas applicants with collectivist priming were attracted to advertisements with an other‐focused emotional appeal. In addition, both studies revealed that a job applicant's regulatory focus (promotion vs. prevention) mediated the influence of national culture on the relationship between type of emotional appeal and applicant attraction to firms. Practical implications and suggestions for future research also are discussed. Copyright © 2016 John Wiley & Sons, Ltd.     

石油开采区域生态环境质量综合评价研究

石油开采在规模不断扩张的同时,也造成了大面积的采区环境污染,严重降低了生态环境质量.为探索石油开采区域生态环境质量综合评价的有效方法,通过对石油开采区域生态环境质量及综合评价现状的分析,精选指标构建了石油开采区域生态环境质量的综合评价指标体系,利用专家调查法确定了各评价指标的相对权值,并构建了石油开采区域生态环境质量模糊综合评价模型,选择胜利油田某采区进行了综合评价的应用研究,对模糊综合评价模型的有效性进行了验证.     

热荷载与风荷载作用下点式支承玻璃的破裂行为规律

在高层建筑火灾中,玻璃幕墙的破裂受到环境风和室内火灾的共同影响。研究了600 mm×600 mm×6mm的浮法玻璃幕墙在点支承安装方式下受到热辐射荷载和风荷载情况下的响应规律。分析了不同工况下玻璃表面的温度变化、风荷载的大小与玻璃破裂时间的关系、玻璃破裂与温差之间的关系、玻璃裂纹扩展及其与风速之间的关系。结果表明在玻璃两侧分别受到热辐射和风荷载共同作用时,风荷载的增加会加速玻璃的破裂。研究结果可为玻璃幕墙的工程应用提供技术支撑。     

Methane Emissions and Production Potentials of Forest Swamp Wetlands in the Eastern Great Xing’an Mountains, Northeast China

Measurements of methane flux at a few inundated sites in China have been extrapolated to obtain estimates on a national scale. To enable those national estimates to be refined and to compare flux from geographically separated sites comprising the same wetland types, we used a closed chamber method to measure methane flux in uninundated Betula platyphylla—and Larix gmelinii—dominated peatlands in the Northeast China. Our measurements were taken from both vegetated and bare soil surfaces, and we compared flux with environmental measures including vegetation biomass, soil temperature and soil characteristics. We found that methane flux was low, and that there were no significant differences between wetland types, indicating that environmental influences were dominant. We found that flux was positively correlated to temperature in the surface layers of the soil, the above-ground biomass of the shrub and herb layers, total soil carbon and total soil nitrogen; and we suggest that emissions may be due to anaerobic microcosms in the surface layers. The methane production potentials of the soils were low and similar between both sites but inconsistent with the differences between fluxes, and inconsistent with production potentials and fluxes reported from the same wetland types elsewhere, indicating that there were subtle environmental differences between wetlands classed as being of the same type. Differences between fluxes in vegetated chambers with bare soil chambers were insignificant, indicating that no methane emission through aerenchyma occurred at our sites. We concluded that wetland type was not an accurate predictor of methane flux.     

页岩气开发中压裂返排液的水质污染特征研究

页岩气压裂返排液成分复杂,为了解页岩气开采过程中压裂返排液的污染情况,对四川某页岩气典型井场不同时期的压裂返排液污染物组成进行了分析,采用超滤膜法测定溶解性有机物(DOM)相对分子质量分布特性,通过建立水质矩阵开展污染特性评价,并进行了综合生态毒性研究。结果表明,该区域不同时期压裂返排液中污染物特征相似,主要污染因子为总有机碳(TOC)和氯离子,并且生物毒性高、可生化性差。研究结果可为该区域压裂返排液处理技术的选择提供参考。     

Lateral velocity distribution in open channels with partially flexible submerged vegetation

Environmental Fluid Mechanics - This study implemented three analytical models to investigate the lateral distribution of depth-averaged streamwise velocity in a rectangular channel with lateral,...     

Two-phase modeling of sediment clouds

A sediment cloud release in stagnant ambient fluid occurs in many engineering applications. Examples include land reclamation and disposal of dredged materials. The detailed modeling of the distinct characteristics of both the solid and fluid phases of the sediment cloud is hitherto unavailable in the literature despite their importance in practice. In this paper, the two-phase mixing characteristics of the sediment cloud are investigated both experimentally and theoretically. Experiments were carried out to measure the transient depth penetration and the lateral spread of the sediment cloud and its entrained fluid using the laser induced fluorescence technique, with a range of particle sizes frequently encountered in the field (modeled at laboratory scale). A two-phase model of the sediment cloud that provides detailed predictions of the mixing characteristics of the individual phases is also proposed. The entrained fluid characteristics are solved by an integral model accounting for the buoyancy loss (due to particle separation) in each time step. The flow field induced by the sediment cloud is approximated by a Hill’s spherical vortex centered at the centroid and with the size of the entrained fluid. The particle equation of motion under the effect of the induced flow governs each computational particle. A random walk model using the hydrodynamic diffusion coefficient is used to account for the random fluctuation of particles in the dispersive regime. Overall, the model predictions of the two-phase mixing characteristics are in good agreement with the experimental data for a wide range of release conditions.     

Sustainability of a local government-instituted ecotourism development: Tayak adventure,nature and wildlife Park in Rizal,Laguna, Philippines

Environment, Development and Sustainability - Ecotourism development is a strategy of the Philippine Government. The existence of untapped natural resources and cultural/heritage assets has impeded...