Evaluation of PFAS treatment technology: Alkaline ozonation

A bench‐scale treatability study was performed to evaluate the effectiveness of alkaline ozonation on removing per‐ and polyfluoroalkyl substances (PFAS) present in groundwater at a former industrial site in Michigan. The study involved testing the PFAS‐impacted groundwater under alkaline ozonating conditions under a range of experimental conditions, including modifying pH, hydrogen peroxide‐to‐ozone molar ratio doses, length of ozonation pretreatment times, and sampling techniques. PFAS‐spiked samples were used to determine if inorganic ions such as fluoride (F^?), sulfate (SO₄^2?), formate (HCOO^?), acetate (CH₃COO^?), and trifluoroacetate (CF₃COO^?) were generated or if there were decreases in total organic fluorine resulting from PFAS treatment. The results from all tests indicate that decreases in PFAS concentrations were due to a combination of removal and destructive mechanisms with enhanced removal under acidic pH ozonation pretreatment conditions. Short‐chain PFAS concentrations increased during the experiments followed by an overall decrease in concentration under continuous alkaline ozonation conditions. Reductions in concentrations in perfluorooctane sulfonic acid of 75–97% were observed. Reductions in concentrations were also observed in other PFAS such as 6:2 FTS, PFHxS, PFOA, and PFNA. To our best knowledge, this is the first time that alkaline ozonation has been performed on PFAS‐impacted water while monitoring a larger suite of PFAS analytes in addition to destruction byproducts. Treatment of PFAS under the conditions discussed in this paper suggests that alkaline ozonation may be a viable remediation option for PFAS‐impacted waters.     

A new index for measuring perpendicularity of animal movements in relation to patch boundaries

We introduce a new index for measuring perpendicularity of animal movements with respect to a boundary (e.g., a habitat patch edge), and provide a computer algorithm for its calculation. Our index, η, improves on an approach that measures perpendicularity with respect to a fixed boundary direction. This is because η accounts for moment-to-moment trajectories relative to nearest-neighbor boundary attributes at the scale of an animal's movement. Our algorithm prp calculates η efficiently and accurately with both synthetic data and large telemetry datasets. In addition, we have included routines in prp which account for scenarios inherently problematic to perpendicularity estimators.     

PRIESTLEY‐TAYLOR ALPHA COEFFICIENT: VARIABILITY AND RELATIONSHIP TO NDVI IN ARCTIC TUNDRA LANDSCAPES1

ABSTRACT: Average daily values of the Priestley‐Taylor coefficient (a) were calculated for two eddy covariance (flux) tower sites with contrasting vegetation, soil moisture, and temperature characteristics on the North Slope of Alaska over the 1994 and 1995 growing seasons. Because variations in a have been shown to be associated with changes in vegetation, soil moisture, and meteorological conditions in Arctic ecosystems, we hypothesized that a values would be significantly different between sites. Since variations in the normalized difference vegetation index (NDVI) follow patterns of vegetation community composition and state that are largely controlled by moisture and temperature gradients on the North Slope of Alaska, we hypothesized that temporal variations in a respond to these same conditions and thus co‐vary with NDVI. Significant differences in a values were found between the two sites in 1994 under average precipitation conditions. However, in 1995, when precipitation conditions were above average, no significant difference was found. Overall, the variations in a over the two growing seasons showed little relationship to the seasonal progression of the regional NDVI. The only significant relationship was found at the drier, upland study site.     

Incomplete mixing in a small, urban stream

Conservative solute tracer experiments were conducted in Indian Creek, a small urban stream located in Philadelphia, Pennsylvania, USA. Estimated flow rates were between 46 Ls(-1) and 81 Ls(-1), average stream width was 5.5m and average stream depth was 0.2m. Given these dimensions, most researchers would think it reasonable to assume that the stream is completely mixed vertically and horizontally. However, we found that the stream was not vertically completely mixed in a 1.0m deep, 30 m long pool. The limited mixing was demonstrated by the vertical stratification of a tracer cloud which was completely mixed both laterally and vertically across the stream prior to entering the pool. We suggest that the cause of limited mixing is due to a balance between groundwater inflow and transverse dispersion at the cross-section. We show that the unsupported assumption of complete mixing may result in a wide range, and thus increased uncertainty, of the values of stream flow and longitudinal dispersion coefficient estimated from these data. We conclude that the assumption of complete mixing and one-dimensional modeling must be checked against actual field conditions, even in small streams.     

Policy networks,stakeholder interactions and climate adaptation in the region of South East Queensland,Australia

The strategic use of science in regional policy-making forums often assumes collaborative interactions between stakeholders. However, other types of stakeholder interactions are possible. This paper uses the ecology of games to frame an investigation into stakeholder participation in the policy networks for regional climate change planning for South East Queensland, Australia. We tracked organisational participation in policy forums between 2008 and 2012. We then used a novel bipartite network theoretical approach to identify participation by different types of organisations across shared multiple forums, which we argue prefaces: cooperation, collaboration, support or advocacy. Network analysis was then combined with semi-structured interviews to access how scientific information was utilised across the regional network. Our results suggest that stakeholder interactions were predominately used to advocate for organisational agendas. Advocacy artificially narrows the scope of possible policy options and represents a biased, selective use of information. While advocacy is an important part of policy process, as a counter balance, explicit efforts are needed to recurrently expand the scope of policy options.     

Four Decades of Plant Community Change in the Alpine Tundra of Southwest Yukon,Canada

Repeat measurements from long-term plots provide precise data for studying plant community change. In 2010, we visited a remote location in Yukon, Canada, where a detailed survey of alpine tundra communities was conducted in 1968. Plant community composition was resurveyed on the same four slopes using the same methods as the original study. Species richness and diversity increased significantly over the 42 years and non-metric multidimensional scaling indicated that community composition had also changed significantly. However, the direction and magnitude of change varied with aspect. Dominant species were not replaced or eliminated but, instead, declined in relative importance. Fine-scale changes in vegetation were evident from repeat photography and dendro-ecological analysis of erect shrubs, supporting the community-level analysis. The period of study corresponds to a mean annual temperature increase of 2°C, suggesting that climate warming has influenced these changes.     

Is adaptive co-management ethical?

‘Good’ governance and adaptive co-management hold broad appeal due to their positive connotations and ‘noble ethical claims’. This paper poses a fundamental question: is adaptive co-management ethical? In pursuing an answer to this question, the concept of adaptive co-management is succinctly summarized and three ethical perspectives (deontology, teleology and existentialism) are explored. The case of adaptive co-management in Cambodia is described and subsequently considered through the lens of ethical triangulation. The case illuminates important ethical considerations and directs attention towards the need for meditative thinking which increases the value of tradition, ecology, and culture. Giving ethics a central position makes clear the potential for adaptive co-management to be an agent for governance, which is good, right and authentic as well as an arena to embrace uncertainty.     

Effect of biodegradation on the consolidation properties of a dewatered municipal sewage sludge

The effect of biodegradation on the consolidation characteristics of an anaerobically digested, dewatered municipal sewage sludge was studied. Maintained-load oedometer consolidation tests that included measurement of the pore fluid pressure response were conducted on moderately degraded sludge material and saturated bulk samples that had been stored under static conditions and allowed to anaerobically biodegrade further (simulating what would happen in an actual sewage sludge monofill or lagoon condition). Strongly degraded sludge material was produced after a storage period of 13 years at ambient temperatures of 5-15 degrees C, with the total volatile solids reducing from initially 70% to 55%. The sludge materials were highly compressible, although impermeable for practical purposes. Primary consolidation generally occurred very slowly, which was attributed to the microstructure of the solid phase, the composition and viscosity of the pore fluid, ongoing biodegradation and the high organic contents. The coefficient of primary consolidation values decreased from initially about 0.35m2/yr to 0.003-0.03m2/yr with increasing effective stress (sigmav'=3-100kPa). Initially, the strongly degraded sludge material was slightly more permeable, although both the moderately and strongly degraded materials became impermeable for practical purposes (k=10(-9)-10(-12)m/s) below about 650% and 450% water contents, respectively. Secondary compression became more dominant with increasing effective stress with a mean secondary compression index (Calphae) value of 0.9 measured for both the moderately and strongly degraded materials.