GEOCHEMICAL INTERPRETATIONS OF GROUNDWATER FLOW SYSTEMS1

ABSTRACT. Interest in the geochemistry of groundwater is increasing owing to the great number of current projects involving underground liquid waste storage, artificial recharge of potable water, accidental contamination of groundwater bodies, sanitary landfills, and pollution monitoring. Geochemical techniques used to facilitate the understanding of a groundwater system range from extremely simple to those requiring sophisticated theories, equipment, and procedures. An interpretation of the simple trilinear diagram for samples collected from the Yucatan Peninsula of Mexico provided evidence that the fresh-water body was only a few tens of meters thick and was underlain everywhere by an extensive body of salt water. A geochemical technique that has been used effectively to identify the source of salt water in coastal aquifers is measurement of the carbon-14 concentrations. Carbon-14 has been used in a regional carbonate aquifer to determine the velocity of groundwater movement, rates of chemical reactions, and distribution of hydraulic conductivity. The application of principles of irreversible thermodynamics to groundwater systems provides a basis for constructing models which permit prediction, over both time and space, of changes in head distribution and chemical character of the water resulting from imposed stresses on the system. In essence, proper application of irreversible thermodynamics combines the potential theory of Hubbert with principles of reversible chemical thermodynamics, such as solution of carbonate minerals, to describe and explain controlling chemical reactions and processes of groundwater systems.     

AN INSULATED EVAPORIMETER1

Evaporation was measured from a circular evaporation pan, 18 inches in diameter and 8 inches deep. The pan was insulated on the sides and bottom using 2 inches of freon-blown polyurethane foam. A U.S. Weather Bureau Class A evaporation pan was used to obtain reference evaporation measurements. Water evaporation from the Class A pan and the insulated pan were highly correlated. Using a water-methanol mixture, the insulated pan may be operated at temperatures below 32 F; the equivalent liquid water evaporation may be determined using a regression equation.     

Evaluating public participation in environmental decision-making: EPA's superfund community involvement program

This article discusses an 8-year, ongoing project that evaluates the Environmental Protection Agency's Superfund community involvement program. The project originated as a response to the Government Performance and Results Act, which requires federal agencies to articulate program goals, and evaluate and report their progress in meeting those goals. The evaluation project assesses how effective the Superfund community involvement program is in promoting public participation in decisions about how to clean up hazardous wastes at Superfund sites. We do three things in the article: (1) share our experience with evaluating an Agency public participation program, including lessons learned about methods of evaluation; (2) report evaluation results; and (3) address a number of issues pertaining to the evaluation of public participation in environmental decision-making. Our goal is to encourage more environmental managers to incorporate evaluation into their public participation programs as a tool for improving them. We found that written mail surveys were an effective and economical tool for obtaining feedback on EPA's community involvement program at Superfund sites. The evaluation focused on four criteria: citizen satisfaction with EPA information about the Superfund site, citizen understanding of environmental and human health risks associated with the site, citizen satisfaction with opportunities provided by EPA for community input, and citizen satisfaction with EPA's response to community input. While the evaluation results were mixed, in general, community members who were most informed about and involved in the cleanup process at Superfund sites generally were also the most satisfied with the community involvement process, and the job that EPA was doing cleaning up the site. We conclude that systematic evaluation provides meaningful and useful information that agencies can use to improve their public participation programs. However, there need to be institutionalized processes that ensure evaluation results are used to develop and implement strategies for improvement.     

Molecular-level investigation of monoaromatic compound sorption to suspended soil particles by deuterium nuclear magnetic resonance

Molecular-level sorption behavior of monoaromatic compounds in suspensions of water-dispersable clay components was studied by measuring 2H nuclear magnetic resonance (NMR) spin-spin relaxation times (T2). In general, decreased T2 values indicate stronger solute-sorbent interactions and increased sorption of the solute. A decreasing trend for T2 values in the order benzene > fluorobenzene > toluene (-C6D5 moiety) was observed, which was probably caused by the hydrophobic effect. The T2 values for benzene and the -C6D5 moiety of toluene increased with increasing pH, whereas the trend with pH was much weaker and less consistent for fluorobenzene and the methyl group of toluene. Conversely, no clear relationship was found between T2 values and pH for dichloromethane. These contrasting results cannot be explained by the pH-dependent self-assembly and hydrophobicity of humics. Instead, directed specific forces, including hydrogen bonding, cation-pi interactions, and aromatic-aromatic interactions, are proposed between the benzene ring of monoaromatic solutes and soil organic matter (SOM). Substituents of benzene affect these interactions by varying the pi electron density. When the soil fraction was treated with NaOH to remove humic and fulvic acids, T2 values for the different monoaromatic solutes were surprisingly lower compared with those for the untreated soil fraction. This result is probably caused by the increased ratio of solutes adsorbed to "hard" or "glassy" SOM components, which leads to less mobile sorbed solute molecules, after removing NaOH-extractable humics that contain more "soft" or "rubbery" SOM components.     

Indicators Assessment for Habitat Conservation Plan of Yolo County, California, USA

/ Whereas habitat conservation plans (HCPs) have been intended to provide comprehensive environmental mitigation for multiple species, they often narrow in focus to one species and either one mitigation site or unspecified sites. We developed an indicators framework from which to rate land units for their ecological integrity, collateral values (nonbiological qualities that can improve conservation), and restoration and conservation opportunities. The ratings of land units were guided by the tenets of conservation biology and principles of landscape and ecosystem ecology, and they were made using existing physical and floral information managed on a GIS. As an example of how the indicators approach can be used for HCPs, the 29 legally rare species targeted by the Yolo County HCP were each associated with vegetation complexes and agricultural crops, the maps of which were used for rating some of the landscape indices. The ratings were mapped so that mitigation can be directed to the places on the landscape where the legally rare species should benefit most from conservation practices. The most highly rated land units for conservation opportunity occurred along streams and sloughs, especially where they emerged from the foothills and entered the Central Valley and where the two largest creeks intersected the Sacramento River flood basin. We recommend that priority be given to mitigation or conservation at the most highly rated land units. The indices were easy to measure and can be used with other tools to monitor the mitigation success. The indicators framework can be applied to other large-area planning efforts with some modifications.KEY WORDS: Ecosystem; Indicators; Landscape; Mitigation; Planning; Yolo County; California     

Channel change,sediment transport,and fish habitat in a coastal stream: Effects of an extreme event

A study on sediment transport and channel change was conducted on Zayante Creek and the lower San Lorenzo River in Santa Cruz County, California. A rainstorm with a recurrence interval locally in excess of 150 years occurred during the study year, 1982 WY. Stream surveys indicated that significant aggradation occurred during and after the peak flood. Upper study reaches were substantially recovered after high flows of early April, but the lower study reaches still had significant filling of pools and burial of riffles by sand. Increases in width-depth ratio were minor and localized in upper reaches, but were significant in lower reaches. Large inputs of sand, primarily from landsliding, altered the sediment transport regime. A higher proportion of the bedload is now transported by lower flows than before the January event. Roads and sand quarries contributed significantly to sediment input to the stream. A proposed dam may alter the sediment transport regime of Zayante Creek. Mitigating the effects of this dam on downstream fish habitat may require occasional bankfull discharges.     

Timing of hurricane emergency actions

Emergency actions to prepare for hurricanes often require more time than is available from official public warnings. This means that the preparedness official must decide not onlywhat to do butwhen to do it. The action decision system, described here, developed for use in the State of Florida, reformats the hurricane track forecast, a 72-h projection, prepared at the National Hurricane Center in Miami, to specify the probability of a strike at each of 12 vulnerable coastal communities, and then normalizes the value in terms of a composite of probabilities computed for historic hurricanes that struck the respective communities. The normalization, a ratio of the two probability values, current and historic, expressed as a percentage is defined as the level of risk. When this level reaches or exceeds 100% the risk level is defined as critical and the system recommends that emergency actions to prepare begin immediately.The system is founded upon individual hurricane climatologies and decision procedures that are tailored for use at each community. The action recommendations generated by the risk analyses with a 93% level of confidence relieve the preparedness official of the need to make meteorological decisions in timing evacuations and other critical measures, even when these must begin before official hurricane warnings are received.The work that provided the basis for this publication was supported by funding under a Cooperative Agreement with the Federal Emergency Management Agency. The substance and findings of the work are dedicated to the public. The authors are solely responsible for the accuracy of the statements and interpretations contained in the publication. Such interpretations do not necessarily reflect the views of the government.     

WATERSHED PLANNING FOR ACID MINE DRAINAGE ABATEMENT1

Acid drainage from abandoned mines is a widespread problem in old mining regions. Agencies seeking to abate it face the prospect of dealing with hundreds of potential abatement projects, stretching decades into the future. A systematic regional analysis is necessary to establish locations, objectives, priorities, and phasing of such projects. The U.S. Bureau of Mines developed a novel procedure for abatement planning in the 420 square mile Blacklick Creek Watershed in Pennsylvania. The plan sought to direct abatement projects toward pollution sources where degradation was worst and adverse effects greatest. It established abatement priorities by comparing the “supply” of sources to be reclaimed (the degrees of old mines' water quality degradation) with the “demand” for abatement to be done (the natural and cultural values represented by the region's demography, land use and other non-mining characteristics). Matrices were used to define the relationships among mining and non-mining factors; maps were developed to show the geographic distribution of the conclusions. The locations, priorities, and phasing of abatement objectives shown on the maps should provide guidance for any abatement effort, no matter what type of technology is applied to achieve the objectives. Over the many years in which abatement projects are to be performed in the Watershed, the plan can be used to define, coordinate, and establish priorities for the projects in a manner that can result in maximum abatement benefits from the application of limited funds.     

WATER CONSERVATION METHODS IN URBAN LANDSCAPE IRRIGATION: AN EXPLORATORY OVERVIEW1

ABSTRACT: The increasing use of irrigation for urban landscapes is causing new demands for efficient watering systems. Conservation techniques for irrigated agricultural fields cannot be applied to urban landscapes without amendment. This paper attempts to review methods of urban landscape water conservation in the context of the diversity and complexity of urban landscapes and the demands upon them for quality of the urban environment. A development's initial site layout and planting design fundamentally determine how much irrigation water will be required; the complexity and creativity inherent in urban design open a number of specific possibilities for reducing water demand. Irrigation hardware is then designed to deliver the required volume of water to the specified landscape efficiently by implementing a number of physical and operational principles. Maintenance of the finished development involves monitoring results and making adjustments as the plantings grow and develop. The potential for conserving urban irrigation water is large. Effective conservation need not compromise other qualities of the urban environment such as aesthetics, screening, or shade. Urban design can address both the kinds of landscapes people need, and minimal consumption of irrigation water.