全文获取类型
收费全文 | 394篇 |
免费 | 6篇 |
国内免费 | 4篇 |
专业分类
安全科学 | 10篇 |
废物处理 | 19篇 |
环保管理 | 34篇 |
综合类 | 99篇 |
基础理论 | 68篇 |
环境理论 | 1篇 |
污染及防治 | 120篇 |
评价与监测 | 28篇 |
社会与环境 | 22篇 |
灾害及防治 | 3篇 |
出版年
2023年 | 7篇 |
2022年 | 15篇 |
2021年 | 12篇 |
2020年 | 6篇 |
2019年 | 9篇 |
2018年 | 13篇 |
2017年 | 17篇 |
2016年 | 21篇 |
2015年 | 12篇 |
2014年 | 17篇 |
2013年 | 23篇 |
2012年 | 34篇 |
2011年 | 21篇 |
2010年 | 10篇 |
2009年 | 20篇 |
2008年 | 19篇 |
2007年 | 19篇 |
2006年 | 14篇 |
2005年 | 12篇 |
2004年 | 10篇 |
2003年 | 13篇 |
2002年 | 10篇 |
2001年 | 6篇 |
2000年 | 2篇 |
1998年 | 2篇 |
1997年 | 6篇 |
1995年 | 2篇 |
1994年 | 5篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1964年 | 2篇 |
1961年 | 1篇 |
1959年 | 2篇 |
1957年 | 2篇 |
1956年 | 1篇 |
1954年 | 1篇 |
1948年 | 1篇 |
1932年 | 1篇 |
1931年 | 1篇 |
1925年 | 2篇 |
1924年 | 2篇 |
1923年 | 2篇 |
1921年 | 3篇 |
1920年 | 1篇 |
1919年 | 1篇 |
1918年 | 2篇 |
1917年 | 1篇 |
1914年 | 1篇 |
排序方式: 共有404条查询结果,搜索用时 15 毫秒
151.
Brito Pedro Elias Marcos Silva-Neto Carlos Sujii Edison Silva Daniela Gonçalves Bruno Franceschinelli Edivani 《Environmental science and pollution research international》2020,27(31):38654-38661
Environmental Science and Pollution Research - The presence of Brazilian native bees can improve tomato production by increasing pollination effectiveness. However, the extensive use of pesticides... 相似文献
152.
Ronan Cariou Philippe Marchand Aline Brosseaud El Mostafa Qannari Bruno Le Bizec 《Environmental pollution (Barking, Essex : 1987)》2010,158(3):941-4047
Current European Union regulation regarding polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans (PCDD/Fs) and dioxin-like polychlorinated biphenyls (dl-PCBs) in food and feed is based on Toxic Equivalent Quotient (TEQ) concept. For confirmatory purpose, the isotope-dilution method associated to a measurement by gas chromatography coupled with high resolution mass spectrometry is usually the method of choice for precisely measuring the 29 target congeners in three separated fractions. Time and cost related to these analyses are very significant. Various kinds of screening concepts can be considered. In the present study, we elaborated and validated a prediction model for the 2005 World Health Organization TEQ in fish, based on the measurement of 4 PCDD/F and 2 non-ortho dl-PCB congeners, potentially analyzable in a single extracted fraction by gas chromatography coupled with mass spectrometry. Large independent datasets have been used for model elaboration (n = 108) and validation (n = 363, n = 357 and n = 6). 相似文献
153.
This work focuses on the influence of humic acids (HAs) on the fate of carbon nanotubes (CNTs) in aqueous media. This influence was demonstrated by mixing CNT powder with HAs in aqueous solution in varying concentrations. The aqueous media containing HAs and CNTs were size-characterized by asymmetrical flow field-flow fractionation (AsFlFFF) coupled with multi-angle light scattering (MALS). This coupling yielded information concerning the size distribution of single- and multi-walled CNTs (SWCNTs and MWCNTs) and HAs under different physico-chemical conditions that can occur in environmental water. HAs can disperse individual CNTs in aqueous media. However, the difference in the physical structure between SWCNTs and MWCNTs leads to significant differences in the quantity of HA that can adsorb onto the nanotube surface and in the stability of the CNT/HA complex. Compared with MWCNTs, SWCNTs suspended in HAs are less affected by changing ionic strength with respect to stability and the amount suspended. 相似文献
154.
Ramos AS Gonçalves F Antunes SC Nunes B 《Journal of environmental science and health. Part. B》2012,47(6):512-519
This study characterizes the cholinesterasic forms present in the bivalve Corbicula fluminea, through the analysis of differential affinity towards various substrates and inhibitors. This approach also permitted the validation of cholinesterase inhibition in the mentioned species for monitoring purposes by evaluating the inhibitory activity of a detergent (SDS) and a pesticide (chlorfenvinphos), both in vitro and in vivo. The cholinesterasic form present in the tissues of C. fluminea showed intermediate properties in terms of its relation with substrates and inhibitors. Furthermore, it was not inhibited by the detergent SDS under any of the test conditions, but was clearly inhibited by the selected organophosphate. The data show clearly that the main cholinesterasic form in C. fluminea is responsive to the organophosphate chlorfenvinphos, thus supporting the use of this biomarker for the environmental monitoring of specific contaminants such as anticholinesterasic pesticides. Despite not being commonly attained in the wild, the levels of chlorfenvinphos required to elicit a significant ChE inhibition were only one order of magnitude above actual values of aquatic contamination by this pesticide. 相似文献
155.
The history of the establishment and management philosophies of the mainland Portuguese Protected Areas was reconstructed
through the use of written records and oral history interviews. The objectives were to review the main philosophies in the
creation and management of these areas, to assess the influence of international PA models, to compare the Portuguese case
with other European and international literature concerning PAs and to discuss the value of the oral history in this research.
As main results, it was found that the initial management model of “Wilderness (or Yellowstone)” was replaced by the “new
paradigm” of PAs when the democracy was re-established. Changes in the management philosophies within this “new paradigm”
were also identified, which resulted in the transition of a “Landscape” to a “Nature conservation” model. After the establishment
of the Natura 2000 network, the “Biodiversity conservation” model prevailed. It was also found that the initiative for the
establishment of most PAs came from the government, although there were few cases of creation due to the action of NGOs and
municipalities. Finally, oral history interviews enabled the addition of information to the literature review, but also provided
more insight and detail to this history. 相似文献
156.
Medeiros Vinci R Jacxsens L Van Loco J Matsiko E Lachat C de Schaetzen T Canfyn M Van Overmeire I Kolsteren P De Meulenaer B 《Chemosphere》2012,88(8):1001-1007
Benzene is a volatile organic compound known to be carcinogenic to humans (Group 1) and may be present in food. In the present study, 455 food samples from the Belgian market were analyzed for benzene contents and some possible sources of its occurrence in the foodstuffs were evaluated. Benzene was found above the level of detection in 58% of analyzed samples with the highest contents found in processed foods such as smoked and canned fish, and foods which contained these as ingredients (up to 76.21 μg kg−1). Unprocessed foods such as raw meat, fish, and eggs contained much lower concentrations of benzene. Using the benzene concentrations in food, a quantitative dietary exposure assessment of benzene intake was conducted on a national representative sample of the Belgian population over 15 years of age. The mean benzene intake for all foods was 0.020 μg kg bw d−1 according to a probabilistic analysis. These values are below the minimum risk level for oral chronic exposure to benzene (0.5 μg kg bw d−1). 相似文献
157.
Ana S. Ramos Fernando Gonçalves Sara C. Antunes Bruno Nunes 《Journal of environmental science and health. Part. B》2013,48(6):512-519
This study characterizes the cholinesterasic forms present in the bivalve Corbicula fluminea, through the analysis of differential affinity towards various substrates and inhibitors. This approach also permitted the validation of cholinesterase inhibition in the mentioned species for monitoring purposes by evaluating the inhibitory activity of a detergent (SDS) and a pesticide (chlorfenvinphos), both in vitro and in vivo. The cholinesterasic form present in the tissues of C. fluminea showed intermediate properties in terms of its relation with substrates and inhibitors. Furthermore, it was not inhibited by the detergent SDS under any of the test conditions, but was clearly inhibited by the selected organophosphate. The data show clearly that the main cholinesterasic form in C. fluminea is responsive to the organophosphate chlorfenvinphos, thus supporting the use of this biomarker for the environmental monitoring of specific contaminants such as anticholinesterasic pesticides. Despite not being commonly attained in the wild, the levels of chlorfenvinphos required to elicit a significant ChE inhibition were only one order of magnitude above actual values of aquatic contamination by this pesticide. 相似文献
158.
Mathieu Cladière Johnny Gasperi Catherine Lorgeoux Céline Bonhomme Vincent Rocher Bruno Tassin 《Environmental science and pollution research international》2013,20(5):2973-2983
This study evaluates the influence of a heavily urbanized area (Paris Metropolitan area), on receiving water contamination by both bisphenol A (BPA) and alkylphenol ethoxylate (APE) biodegradation product. The study began by investigating concentrations within urban sources. In addition to the more commonly studied wastewater treatment plant effluent, wet weather urban sources (including combined sewer overflows, urban runoff, and total atmospheric fallout) were considered. The initial results highlight a significant contamination of all urban sources (from a few nanograms per liter in atmospheric fallout to several micrograms per liter in the other sources) with clearly distinguishable distribution patterns. Secondly, concentration changes along the Seine River from upstream of the Paris Metropolitan area to downstream were investigated. While the concentrations of BPA and nonylphenoxy acetic acid (NP1EC) increase substantially due to urban sources, the 4-nonylphenol concentrations remain homogeneous along the Seine. These results suggest a broad dissemination of 4-nonylphenol at the scale of the Seine River basin. Moreover, the relationship between pollutant concentrations and Seine River flow was assessed both upstream and downstream of the Paris conurbation. Consequently, a sharp decrease in dissolved NP1EC concentrations relative to Seine River flow underscores the influence of single-point urban pollution on Seine River contamination. Conversely, dissolved 4-nonylphenol concentrations serve to reinforce the hypothesis of its widespread presence at the Seine River basin scale. 相似文献
159.
Rawaa Ammar Antoine G. El Samrani Véronique Kazpard Joseph Bassil Bruno Lartiges Zeinab Saad Lei Chou 《Environmental science and pollution research international》2013,20(12):9014-9025
One of the most important sources of solid waste in the Mediterranean Basin ecosystem originated from the phosphate fertilizer industries, which discharge phosphogypsum (PG) directly into aquatic environments or are stacked on stockpiles. The present study investigates metal release from PG under the influence of variable pH, increasing PG mass content, and complexing organic matter ligands. Major ions from PG leachates, grain size and charge, main functional groups along with metal leachability (Pb, Cd, Cr, Cu, and Zn) were determined using ion chromatography, laser diffraction, zetameter, Fourier transform infrared spectroscopy, and atomic absorption spectroscopy, respectively. The complete dissolution of PG recorded is at 2 g/L. Saturation and supersaturation with respect to PG may occur at concentrations of 3 and 4 g/L, respectively, revealing a clustering phenomenon leading to heavy metal encapsulation within the aggregates. Organic ligands such as citrate may trigger the cationic exchange within the PG suspension leading to ion release. As these factors are considered as specific process involving the release of contaminants from PG during storage under natural conditions, this study could set the foundations for PG remediation in aquatic environment. Organic ligands under controlled pH conditions could be utilized in treating fertilizer industrial wastes by taking into consideration the particularity of the receiving area, thus decreasing metal hazardous impact on natural media. 相似文献
160.
Margarida Nunes Anaïs Vernisseau Philippe Marchand Bruno Le Bizec Fernando Ramos Miguel A. Pardal 《Environmental science and pollution research international》2014,21(15):9396-9407
Superficial sediments collected from seven estuarine systems located along the Portuguese coast were analyzed for 7 polychlorinated dibenzo-p-dioxins (PCDDs), 10 polychlorinated dibenzofurans (PCDFs), and 12 dioxin-like polychlorinated biphenyls (dl-PCBs). Total PCDD/F concentration ranged from 4.6 to 464 pg g?1 dry weight (dw), while that of dl-PCBs varied from 26.6 to 8,693 pg g?1 dw. In general, the highest PCDD/F and dl-PCB concentrations were associated with densely populated and industrially impacted areas. Additionally, PCDD/F revealed a predominance of octachlorodibenzodioxin (OCDD) to total PCDD/Fs, while PCB 118 was the major contributor to total dl-PCBs. This study provided a global perspective of the contamination status of Portuguese estuaries by dioxin-like compounds and allowed a comparison between the investigated systems and other systems worldwide. PCDD/F and dl-PCB levels found in the collected sediments were lower than those of highly impacted areas from different parts of the globe. Nevertheless, comparison with guidelines and quality standards from other countries indicated that some Portuguese estuarine areas with a high industrialization level present PCDD/F and dl-PCB concentrations in superficial sediment that may constitute a risk to aquatic organisms. 相似文献