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61.
We investigated the influence of elevated CO2 and O3 on soil N cycling within the soybean growing season and across soil environments (i.e., rhizosphere and bulk soil) at the Soybean Free Air Concentration Enrichment (SoyFACE) experiment in Illinois, USA. Elevated O3 decreased soil mineral N likely through a reduction in plant material input and increased denitrification, which was evidenced by the greater abundance of the denitrifier gene nosZ. Elevated CO2 did not alter the parameters evaluated and both elevated CO2 and O3 showed no interactive effects on nitrifier and denitrifier abundance, nor on total and mineral N concentrations. These results indicate that elevated CO2 may have limited effects on N transformations in soybean agroecosystems. However, elevated O3 can lead to a decrease in soil N availability in both bulk and rhizosphere soils, and this likely also affects ecosystem productivity by reducing the mineralization rates of plant-derived residues.  相似文献   
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Minimising the cost of repeatedly estimating C (C) stocks is crucial to the financial viability of projects that seek to sell C credits. Depending on the price of C, this may imply less or more sampling effort than would be applied for science objectives. In systems with heterogeneous C pools, such as savannas, this translates into a variable-effort sampling strategy that maximises the marginal additional C that can be claimed per incremental unit of effort expended. Analysis of a savanna in north-eastern South Africa indicates relatively modest returns per hectare due to the small C quantities and low sequestration rates. Under these conditions, areas in excess of 1,000 ha and infrequent sampling frequencies of 5–10 years are required to make such projects financially viable. For such projects the sample variance, number of samples, cost per sample and establishment costs have negligible impacts on financial viability. It was also found that the soil-C pool contributes up to three times the net returns of the aboveground C pool and provides a strong argument to monitor soil C for certification and market trading. The financial viability estimates, however, do not include the management or opportunity costs incurred in changing the land use. The economies of scale identified in this study combined with the massive area covered by savannas indicate that these additional costs can be covered. Further research is recommended to quantify these costs and interrogate the feasibility of large scale (in excess of 10,000 ha) C-sink projects in savanna systems.  相似文献   
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The concentration of CO2 in air near the ground needs to be predicted to assess environmental and health risks from leaking underground storage. There is an exact solution to the advection–diffusion equation describing trace gases carried by wind when the wind profile is modeled with a power-law dependence on height. The analytical solution is compared with a numerical simulation of the coupled air–ground system with a source of CO2 underground at the water table. The two methods produce similar results far from the boundaries, but the boundary conditions have a strong effect; the simulation imposes boundary conditions at the edge of a finite domain while the analytic solution imposes them at infinity. The reverse seepage from air to ground is shown in the simulation to be very small, and the large difference between time scales suggests that air and ground can be modeled separately, with gas emissions from the ground model used as inputs to the air model.  相似文献   
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Incident reporting systems are playing an increasingly important role in the development and maintenance of safety-critical applications. The perceived success of the FAA's Aviation Safety Reporting System (ASRS) and the FDA's MedWatch has led to the establishment of similar national and international schemes. These enable individuals and groups to report their safety concerns in a confidential or anonymous manner. Unfortunately, many of these systems are becoming victims of their own success. The ASRS and MedWatch have both now received over 500,000 submissions. In consequence, the administrators of incident reporting systems increasingly rely upon software tools to support the administration of their systems. In the past, these systems have relied upon ad hoc applications of conventional database technology. However, there are several reasons why this technology is inadequate for many large-scale reporting schemes. In particular, the problems of query formation often result in poor precision and recall. This, in turn, has profound implications for safety-critical applications. Users may fail to identify similar incidents within national or international collections. These ad hoc approaches also neglect the opportunities provided by recent developments in computer assisted interviewing and in the monitoring of retrieval activities to build models of user behavior. These techniques offer a number of potential benefits. For instance, it is possible to automatically detect potential biases in the way that investigators analyze particular incidents.  相似文献   
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Rational, cost-effective provision of mission-critical environmental management information remains elusive for almost all large enterprises. Even among the best performing companies—best performing from the perspectives of profitability, quality and/or environmental stewardship—environmental management information systems (EMIS) are usually comprised of dozens to hundreds of individual, isolated applications that require costly data capture, training, and maintenance. This article, the first of two, will discuss ways to coordinate information infrastructures with strategic goals and business processes.  相似文献   
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