INTEGRATING GEOGRAPHIC INFORMATION SYSTEMS AND MODFLOW FOR GROUND WATER RESOURCE ASSESSMENTS1

ABSTRACT: The Floridan Aquifer is the primary source of water in the coastal area of Santa Rosa County, Florida. In order to optimize well field design and analyze aquifer stress problems, the USGS MODFLOW code (McDonald and Harbaugh, 1988) is applied to develop a numerical computer model of the aquifer. The Geographical Information System (GIS) is the primary tool used in the development of the model grid, performance of the modeling procedure, and model analysis. The GIS is used in generating multiple grids in which to simulate both regional scale and local scale flow. The grid topology is recorded in geographic coordinates which facilitates geo-referencing and orientation of the grid to base maps and data coyerages. The GIS allows data transfer from various coverages to the nodes of the block centered grid where hydrogeologic information is stored as attributes to the grid coverage. From this grid coverage, pertinent information is queried within the GIS environment and used to generate the input files for the MODFLOW simulation. After MODFLOW execution, simulated heads and drawdown are imported into the grid coverage where residual error and recharge rates can be calculated. Contoured surfaces are then created for selected data sets including simulated heads, drawdown, residual error, and recharge rates. Model calibration is conducted utilizing the GIS to generate and process data sets associated with model simulations.     

Influence of groundwater conditions and co‐contaminants on sorption of perfluoroalkyl compounds on granular activated carbon

Per and polyfluoroalkyl substances (PFAS) are emerging and persistent organic pollutants that have been detected in many environmental media, humans, and wildlife. A common method to effectively remove PFAS from water is adsorption by activated carbon. Preliminary sorption experiments were conducted using five characterized Calgon Corporation coal‐based granular activated carbon (GAC; F100, F200, F816, F300, and F400), one coconut‐based GAC (CBC‐OLC 12 × 30), and one Jacobi Corporation coal‐based GAC (Omni‐G 12 × 40). Sorption of four representative PFAS onto each GAC was measured to select the most favorable carbon sources. F400 and CBC were chosen based on their performance in preliminary PFAS sorption experiments and contrasting properties. Freundlich and Langmuir isotherm models were developed for perfluorooctanoic acid (PFOA) and perfluorooctanoic sulfonate (PFOS) at an initial concentration of 1 mg/L. Sorption capacities were determined for PFOA and PFOS individually and in the mixture. Individual compounds showed higher sorption than when present in the mixture for both PFOA and PFOS. PFOS showed higher sorption than PFOA both individually and in the mixture and F400 showed higher sorption capacity than CBC. The presence of co‐contaminants (kerosene, trichloroethylene, and ethanol), and variations in groundwater conditions (pH, presence of anions, naturally occurring organic matter, and iron oxides) demonstrated limited impact on the sorption of PFAS onto GAC under the experimental conditions tested.     

Analysis of Sediment Retention in Western Riverine Wetlands: The Yampa River Watershed,Colorado, USA

We quantified annual sediment deposition, bank erosion, and sediment budgets in nine riverine wetlands that represented a watershed continuum for 1 year in the unregulated Yampa River drainage basin in Colorado. One site was studied for 2 years to compare responses to peak flow variability. Annual mean sediment deposition ranged from 0.01 kg/m² along a first-order subalpine stream to 21.8 kg/m² at a sixth-order alluvial forest. Annual mean riverbank erosion ranged from 3 kg/m-of-bank at the first-order site to 1000 kg/m at the 6^th-order site. Total sediment budgets were nearly balanced at six sites, while net export from bank erosion occurred at three sites. Both total sediment deposition (R² = 0.86, p < 0.01) and bank erosion (R² = 0.77, p < 0.01) were strongly related to bankfull height, and channel sinuosity and valley confinement helped to explain additional variability among sites. The texture and organic fraction of eroded and deposited sediment were relatively similar in most sites and varied among sites by watershed position. Our results indicate that bank erosion generally balances sediment deposition in riverine wetlands, and we found no distinct zones of sediment retention versus export on a watershed continuum. Zones of apparent disequilibrium can occur in unregulated rivers due to factors such as incised channels, beaver activity, and cattle grazing. A primary function of many western riverine wetlands is sediment exchange, not retention, which may operate by transforming materials and compounds in temporary sediment pools on floodplains. These results are considered in the context of the Hydrogeomorphic approach being implemented by the U.S. government for wetland resource management.     

Understanding Fish Behavior,Distribution, and Survival in Thermal Effluents Using Fixed Telemetry Arrays: A Case Study of Smallmouth Bass in a Discharge Canal During Winter

Advances in telemetry have facilitated the continuous monitoring of fish position and movement. At present, there are few examples where this approach has been applied to environmental monitoring or assessment. Here we 1) present a case study that used a fixed antenna array and continuously scanning coded receiving system to monitor the movement of radio-tagged smallmouth bass (Micropterus dolomieu) in a thermal discharge canal on Lake Erie during the winter of 1998/1999, and 2) evaluate the use of fixed telemetry arrays for environmental monitoring. Although the number of radiotagged bass in the canal decreased gradually over time, fish spent the majority of the winter in the canal. When in the canal, bass selected areas upstream of the tempering pumps where water was the warmest. This region was also high in habitat complexity, had adequate velocity refuges, and abundant forage. Despite residing in the thermal effluent throughout the winter, none of the fish monitored were observed to participate in reproductive activities in the canal in the Spring. Interestingly, during a biofouling chlorination pulse in May, 50% of radiotagged fish still residing in the canal left and did not return during the monitoring period. Utility infrastructure accessible to fish, including thermal effluents, should be considered as fish habitat and managed accordingly to minimize mortality and sublethal effects on resident and transient fish. Fixed telemetry arrays that permit the continuous monitoring of fish behavior as described in this paper are widely applicable to many issues in environmental management, monitoring, and conservation.     

REVIVING URBAN STREAMS: LAND USE,HYDROLOGY, BIOLOGY,AND HUMAN BEHAVIOR1

ABSTRACT: Successful stream rehabilitation requires a shift from narrow analysis and management to integrated understanding of the links between human actions and changing river health. At study sites in the Puget Sound lowlands of western Washington State, landscape, hydrological, and biological conditions were evaluated for streams flowing through watersheds with varying levels of urban development. At all spatial scales, stream biological condition measured by the benthic index of biological integrity (B‐IBI) declined as impervious area increased. Impervious area alone, however, is a flawed surrogate of river health. Hydrologic metrics that reflect chronic altered streamflows, for example, provide a direct mechanistic link between the changes associated with urban development and declines in stream biological condition. These measures provide a more sensitive understanding of stream basin response to urban development than do treatment of each increment of impervious area equally. Land use in residential backyards adjacent to streams also heavily influences stream condition. Successful stream rehabilitation thus requires coordinated diagnosis of the causes of degradation and integrative management to treat the range of ecological stressors within each urban area, and it depends on remedies appropriate at scales from backyards to regional storm water systems.     

Muscle tetanus and loading condition effects on the elastic and viscous characteristics of the thorax

Thoracic deformation under an applied load is an established indicator of injury risk, but the force required to achieve an injurious level of deformation currently is not understood adequately. This article evaluates how two potentially important factors, loading condition and muscle tensing, affect the structural response of the dynamically loaded thorax. Structural models of two human cadaver thoraxes and two porcine thoraxes were used to quantify the effects. The human cadavers, which represent anthropometric extremes, were subjected to anterior loading from (1) a 5.1-cm-wide belt oriented diagonally (i.e., seatbelt-like loading), (2) a 15.2-cm-diameter rigid hub, and (3) a 20.3-cm-wide belt oriented laterally (i.e., a distributed load). A structural model having the mathematical formulation of a quasilinear viscoelastic material model was used to model the elastic and viscous response, with ramp-hold tests used to determine the model coefficients. The effect of thoracic musculature was assessed using similar ramp-hold tests on the porcine subjects, each with and without forced muscle contraction. Even maximally contracted thoracic musculature is shown to have a minimal effect on the response, with similar elastic and viscous characteristics exhibited by each subject regardless of muscle tone. The elastic response is shown to be approximately a factor of three stiffer for diagonal belt loading and for this distributed loading condition than for the hub loading, indicating that the response is influenced most by the particular anatomical structures that are engaged and, secondarily, by the area of load application. Specifically, shoulder involvement is shown to have a strong influence. The force relaxation is found to be pronounced, but insensitive to the loading condition, with long-time force relaxation coefficients (G( infinity )) in the range of 0.1 to 0.3. The findings of this study provide restraint-specific guidelines for the force-deflection characteristics of both physical and computational thoracic models.     

Differences in relative risks for fatal occupational highway transportation accidents

Problem and Method: This study examined the trends in the relative risks for being involved in fatal occupational highway transportation accidents based upon the age and gender of the victim. Results: Significant differences in relative risks were identified based upon age; however, there were no significant differences in relative risks based upon gender. The trend analysis of relative risks for all motor-vehicle accidents based upon age showed that males exhibited a significant cubic trend while females exhibited a significant linear trend. The trend analysis of relative risks for fatal motor-vehicle accidents specifically involving vehicle operators based upon age yielded a significant quadratic trend for males and no significant trends for females. Examining the relative risks for fatalities involving only motor-vehicle operators controlled, to a certain extent, the differences in job exposure to motor-vehicle accidents based upon age. Impact: Prevention measures are identified as most crucial for older male workers in the transportation and agriculture industries.     

Aquatic ecological risks due to cyanide releases from biomass burning

Aquatic toxicity due to the creation and mobilization of chemical constituents by fire has been little studied, despite reports of post-fire fish kills attributed to unspecified pyrogenic toxicants. We examined releases of cyanides from biomass burning and their effect on surface runoff water. In laboratory test burns, available cyanide concentrations in leachate from residual ash were much higher than in leachate from partially burned and unburned fuel and were similar to or higher than the 96-h median lethal concentration (LC50) for rainbow trout (45 microg/l). Free cyanide concentrations in stormwater runoff collected after a wildfire in North Carolina averaged 49 microg/l, again similar to the rainbow trout LC50 and an order of magnitude higher than in samples from an adjacent unburned area. Pyrogenic cyanide inputs, together with other fire-related stressors, may contribute to post-fire fish mortalities, particularly those affecting salmonids.     

ELEVATED ATMOSPHERIC CO2 INCREASES WATER AVAILABILITY IN A WATER-LIMITED GRASSLAND ECOSYSTEM1

ABSTRACT: Californian annual grassland on sandstone (moderately fertile) and serpentine (very infertile) soils at the Jasper Ridge Biological Preserve, Stanford, California, were exposed to ambient or elevated (ambient + 36 Pa CO₂) atmospheric CO₂ in open-top chambers since December 1991. We measured ecosystem evapotranspiration with open gas-exchange systems, and soil moisture with time-domain reflectometry (TDR) over 0–15 cm (serpentine) and 0–30 cm (sandstone) depths, at times of peak above ground physiological activity. Evapotranspiration decreased by 12 to 63 percent under elevated CO₂ in three consecutive years in the sandstone ecosystem (p = 0.053, p = 0.162, p = 0.082 in 1992, 1993, and 1994, respectively). In correspondence with decreased evapotranspiration, late-season soil moisture reserves in the sandstone were extended temporally by 10 ± 3 days in 1993 and by 28 ± 11 days in 1994. The effect of elevated CO₂ on soil moisture was greater in the drier spring of 1994 (419 mm annual rainfall) than in 1993 (905 mm annual rainfall). In the serpentine ecosystem, evapotranspiration and soil moisture reserves were not clearly affected by elevated CO₂. Soil water may be conserved in drought-affected ecosystems exposed to elevated CO₂, but the amount of conservation appears to depend on the relative importance of transpiration and soil evaporation in controlling water flux.     

Assessing potential bioavailability of metals in sediments: A proposed approach

Due to anthropogenic inputs, elevated concentrations of metals frequently occur in aquatic sediments. In order to make defensible estimates of the potential risk of metals in sediments and/or develop sediment quality criteria for metals, it is essential to identify that fraction of the total metal in the sediments that is bioavailable. Studies with a variety of benthic invertebrates indicate that interstitial (pore) water concentrations of metals correspond very well with the bioavailability of metals in test sediments. Many factors may influence pore water concentrations of metals; however, in anaerobic sediments a key phase controlling partitioning of several cationic metals (cadmium, nickel, lead, zinc, copper) into pore water is acid volatile sulfide (AVS). In this paper, we present an overview of the technical basis for predicting bioavailability of cationic metals to benthic organisms based on pore water metal concentrations and metal-AVS relationships. Included are discussions of the advantages and limitations of metal bioavailability predictions based on these parameters, relative both to site-specific assessments and the development of sediment quality criteria.