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791.
Chantel D. Sloan Joann F. Gruber Kevin M. Mwenda Jason H. Moore Tracy Onega 《毒物与环境化学》2013,95(3):605-615
Indoor and outdoor air pollution is known to contribute to increased lung cancer incidence. This study is the first to address the contribution of home heating fuel and geographical course particulate matter (PM10) concentrations to lung cancer rates in New Hampshire, USA. First, Pearson correlation analysis and geographically weighted regression were used to investigate spatial relationships between outdoor PM10 and lung cancer rates. While the aforementioned analyses did not indicate a significant contribution of PM10 to lung cancer in the state, there was a trend towards a significant association in the northern and southwestern regions of the state. Second, case-control data were used to estimate the contributions of indoor pollution and secondhand smoke to the risk of lung cancer with adjustment for confounders. Increased risk was found among those who used wood or coal to heat their homes for more than 10 winters before the age of 18, with a significant increase in risk per winter. Resulting data suggest that further investigation of the relationship between heating-related air pollution levels and lung cancer risk is needed. 相似文献
792.
Mathias B. Forrester 《毒物与环境化学》2013,95(4):799-804
One of the most common types of microbial pesticides used is Bacillus thuringiensis. Although generally considered safe, exposures to B. thuringiensis pesticide do occur where management by healthcare providers is sought. The objective of this investigation was to describe B. thuringiensis pesticide exposures reported to Texas poison centers. Cases were all B. thuringiensis pesticide exposures reported to Texas poison centers during 2000–2010. The distribution of cases was determined for various demographic and clinical factors. Of 115 total cases, 64% occurred during May–July. The rate per 1,000,000 population was 14.3 in central Texas and 4.4 in the rest of the state. Of the patients, 56% were of an age 20 years or older and 55% were male. The exposure routes were 57% by ingestion, 30% by dermal contact, and 11% by inhalation. The patient was managed on site in 93% of the exposures and only one exposure was judged to be potentially serious. B. thuringiensis pesticide exposures reported to Texas poison centers were more frequently reported from the central region of the state. The majority of exposures occurred during April–July, involved adults and males, occurred by ingestion or dermal route, were managed on site and did not result in serious outcomes. 相似文献
793.
In this work, a new procedure for the enrichment of the trace amount of Cu2+, Ni2+, Co2+, Pb2+, Fe2+, and Zn2+ ions based on the utilization of multiwalled carbon nanotubes (MWCNT) modified with 2-(2-hydroxy-5-nitrophenyl)-4,5-diphenyl imidazole as chelating agent prior to their determination by flame atomic absorption spectrometry has been described. The influence of effective parameters including pH, amount of ligand and MWCNT, composition of eluent, and coexisting ions on recoveries of understudy metal ions was examined. At the optimum pH of 5.0, all metal ions were quantitatively sorbed onto the proposed solid phase and completely desorbed with 8?mL of 5.0?mol?L?1 HNO3. The detection limit of Cu2+, Co2+, Ni2+, Pb2+, Fe2+, and Zn2+ ions was 1.7, 2.4, 2.3, 2.9, 2.8, and 1.4?µg?L?1, while the preconcentration factor was 63 for Cu2+ and 94 for the other metal ions and relative standard deviations between 1.8 less than 3.0%. The proposed procedure was applied for the analysis of various samples. 相似文献
794.
795.
Neelam Dwivedi Sandeep Kumar Ashish S. Verma Ghanshyam D. Gupta K.K. Dutta 《毒物与环境化学》2013,95(9):1572-1580
Furfural is an industrial compound used as a process intermediate and as a solvent; it poses a potential inhalation hazard in occupational settings. This study was carried out to find furfural-induced immunotoxicity in Wistar rat following inhalative exposure. The weights of thymus and lymph node were found decreased, while the weights of the liver and the adrenal gland were significantly increased following furfural exposure. Delayed-type hypersensitivity response was found decreased in furfural vapors-exposed animals when compared to that of control animals. The phagocytic index of peritoneal and alveolar exudates showed significant decrease and was most prominent (90%) in 30 days-exposed groups. The number of anti-rat anti-sheep red blood cell immunoglobulin M plaque forming cells of spleen got decreased in furfural-exposed groups in comparison to control. Taken together, this study indicates that inhalation of furfural induces immunotoxic manifestations that could lead to severe immunological disorders. 相似文献
796.
Ram B. Jain 《毒物与环境化学》2013,95(3):516-529
The impact of secondhand smoke (SHS) on the levels of polycyclic aromatic hydrocarbons metabolites among the US children and adolescents was evaluated. The data from the National Health and Nutrition Examination Survey for 2003–2008 were analyzed by regression models. SHS at home for children was associated with statistically significantly higher unadjusted levels of 2-hydroxynapthalane, 2-, 3-, and 9-hydroxyfluorene, 1-, 2-, and 3-hydroxyphenanthrene, and 1-hydroxypyrene. Also, SHS at home for adolescents was associated with statistically significantly higher unadjusted levels of 2- and 9-hydroxyfluorene, 2- and 3-hydroxyphenanthrene, and 1-hydroxypyrene. Further, SHS exposure at home was associated with (1) higher adjusted levels of 9-hydroxyfluorene for 6–12 years old (p < 0.01) and (2) lower adjusted levels of 1-hydroxynaphthalene for 12–19 years old (p < 0.01). 相似文献
797.
The Sonbhadra district in the Singrauli area of Uttar Pradesh, India, has many coal mines and thermal power plants and is a critically polluted area. Many residents of this area reported adverse health conditions which may be linked to metal pollution, especially of mercury investigated here.In May 2012, samples of water (23), soil (7), blood, hair, and nails from persons showing adverse health conditions selected at random were collected and analyzed for total mercury by atomic absorption spectrometry.Twenty percent drinking water samples contained mercury from 3 to 26 μg L?1 (3–26 times the permissible limit). Soil samples had 0.5–10.1 mg kg?1 Hg.The average concentrations of mercury in human blood, hair, and nails were found to be 34 μg L?1, 7.4 mg kg?1, and 0.8 mg kg?1, respectively. Mercury concentrations in the blood of these persons were 45 and 28 μg L?1 on average in the case of men and women. This is much higher than the safe level of 5.8 μg L?1 set by the United States Environmental Protection Agency (USEPA).It was concluded that all residents of Sonbhadra sampled could be suffering from mercury toxicity as the area is polluted by Hg released from the coal-fired thermal power plants. 相似文献
798.
The aim of the present study was to evaluate the potential toxicity and general mechanisms involved in single walled carbon nanotubes (SWCNTs)-induced cytotoxicity using human embryonic kidney cell line (HEK293) cells. Carbon nanotubes (coded as CNT) used in this study were synthesized by the chemical vapor deposition method. To elucidate the possible mechanisms underlying SWCNT-induced cytotoxicity, cell viability, cell membrane damage (lactate dehydrogenase activity (LDH) assay), reduced glutathione (GSH), interleukin-8 (IL-8) and lipid peroxidation products levels were quantitatively assessed following SWCNT exposure for 48 hr using HEK293 cells. Exposure of cells to SWCNT at 3–300 μg/ml produced significant reduction in cell viability in a concentration-dependent manner. The IC50 value of SWCNT was found to be 87.58 μg/ml. Exposure of HEK cells to SWCNT at 10–100 μg/ml resulted in concentration-dependent cell membrane damage, increased production of IL-8, elevated levels of thiobarbituric acid reactive substances like malondialdehyde and decreased intracellular GSH levels. In summary, exposure to SWCNT resulted in a concentration-dependent cytotoxicity in cultured HEK293 cells that was associated with increased oxidative stress. 相似文献
799.
The results of a study of photocatalytic degradation of phenol using aqueous oxygenated TiO2 (anatase) suspensions in a batch Pyrex photoreactor are reported. The influence on the photodegradation rate of various parameters as pH, phenol and TiO2 content, oxygen partial pressure, anions present in the dispersions was investigated. A complete oxidation of phenol was observed. Intermediate compounds, catechol and quinone, were detected. It was observed that the photodegradation also proceeded with sunlight radiation. A mechanistic and kinetic model, which accounts for the results obtained, is given. Likely reasons for inactivity of the rutile modification for this reaction are also given. 相似文献
800.
Binding affinity of metanil yellow and its breakdown product p‐aminodiphenylamine to serum proteins has been studied employing chromatographic separation on Sephadex G‐200 and by paper and polyacrylamide gel electrophoresis. Metanil yellow has more affinity towards albumin than to globulins. The complexing is presumably through electrostatic forces. p‐Aminodiphenylamine on the other hand, preferably binds to globulin fractions of serum protein. However, a stable binding with BSA alone was also observed. The binding was quite stable and was accompanied by a shift in absorbance from 430 nm to 500 nm. Aspartic acid moiety of protein was found to be one of the units involved in the binding of p‐ADPA to proteins. 相似文献