碳纳米管电极原位产生过氧化氢及其对亚甲基蓝脱色效果

将碳纳米管固定化制成多孔疏水性导电薄膜构建电化学阴极还原体系,实现过氧化氢在阴极的原位产生。电极特性研究表明,电极在较宽的电压范围内均具有较好的活性。考察了阴极电位、电极成分、氧气流量和电解质浓度对过氧化氢原位产生的影响,在优化条件下经过120min后过氧化氢达到66．17mg／L,并探讨过氧化氢原位产生的机理。在此基础上考察原位过氧化氢氧化工艺下对亚甲基蓝的脱色效果,并分析其脱色机理。     

Increasing tree cover while losing diverse natural forests in tropical Hainan,China

To protect biodiversity and improve environmental conditions, China has invested billions of dollars in reforestation and payments for ecosystem service programs. Here, we examine the Sloping Land Conversion Program, the largest such program in the world and found that after 13 years of implementation at our study site, it has had negative impacts on natural tropical forests. GIS and remote sensing techniques revealed that both natural forests and natural shrub and grasslands were replaced by non-native monocultural plantations on Hainan Island, China, a key tropical biodiversity hotspot. Under current Chinese policy, these plantations are classified simply as “forests”, with the assumption that they are equivalent to natural forests. This lack of a distinction in forest quality has led to substantial deforestation and plantation expansion, including encroachment into protected areas on Hainan. Additional social and economic drivers of these changes were identified by examining the participants in this program and their actions. Without a new ecologically based definition of forests and new goals for reforestation, such programs designed to improve ecosystem services, and forest quality may actually threaten remaining natural forests and other vegetation types in Hainan and in other areas of mainland China.     

A novel pretreatment approach for fast determination of organochlorine pesticides in biotic samples

Recent studies have focused on enantiomeric behaviors of chiral organochlorine pesticides (OCPs) in biotic matrix because they provide insights into the biotransformation processes of chiral OCPs. In the present paper, a double in-line column chromatographic method was developed to effectively remove the lipid impurity in different biotic samples for clean-up of OCPs. After an initial Soxhlet extraction of OCPs from the biotic samples by a mixture of acetone and dichloromethane (DCM), dimethyl sulfoxide (DMSO) was directly added to the extract, and low boiling point solvents (acetone and DCM) were then evaporated. OCPs remained in DMSO were eluted via column 1 filled with silicon gel, and subsequently passed through column 2 packed with 15% deactivated florisil. This novel method was characterized by significant time and solvent savings. The recovery rates of α -HCH (hexachlorocyclohexane), β -HCH, γ -HCH and δ -HCH were 78.5 ± 3.1%, 72.4 ± 7.7%, 72 ± 4.0% and 70.0 ± 8.7%, respectively, and 92.5 ± 3.8%, 79.7 ± 6.7% and 83.4 ± 6.5% for 1,1-dichloro-2-(2-chlorophenyl)-2-(4- chlorophenyl) ethylene (o,p′-DDE), 1,1-dichloro-2-(2-chlorophenyl)-2-(4-chloro phenyl)ethane (o,p′-DDD) and 1,1,1-trichloro-2-(2-chlorophenyl)-2-(4-chlorophenyl) ethane (o,p′-DDT), separately. In addition, the separation efficiencies of the target compounds by both achiral and chiral gas chromatographic columns were satisfactory using the established method. Therefore, the double in-line column chromatography was a useful alternative method for pretreatment of OCPs in different biotic samples.     

Using variances in hydrocarbon concentration and carbon stable isotope to determine the important influence of irrigated water on petroleum accumulation in surface soil

Hunpu is a wastewater-irrigated area southwest of Shenyang. To evaluate petroleum contamination and identify its sources at the area, the aliphatic hydrocarbons and compound-specific carbon stable isotopes of n-alkanes in the soil, irrigation water, and atmospheric deposition were analyzed. The analyses of hydrocarbon concentrations and geochemical characteristics reveal that the water is moderately contaminated by degraded heavy oil. According to the isotope analysis, inputs of modern C3 plants and degraded petroleum are present in the water, air, and soil. The similarities and dissimilarities among the water, air, and soil samples were determined by concentration, isotope, and multivariate statistical analyses. Hydrocarbons from various sources, as well as the water/atmospheric deposition samples, are more effectively differentiated through principal component analysis of carbon stable isotope ratios (δ¹³C) relative to hydrocarbon concentrations. Redundancy analysis indicates that 57.1 % of the variance in the δ¹³C of the soil can be explained by the δ¹³C of both the water and air, and 35.5 % of the variance in the hydrocarbon concentrations of the soil can be explained by hydrocarbon concentrations of both the water and the air. The δ¹³C in the atmospheric deposition accounts for 28.2 % of the δ¹³C variance in the soil, which is considerably higher than the variance in hydrocarbon concentrations of the soil explained by hydrocarbon concentrations of the atmospheric deposition (7.7 %). In contrast to δ¹³C analysis, the analysis of hydrocarbon concentrations underestimates the effect of petroleum contamination in the irrigated water and air on the surface soil. Overall, the irrigated water exerts a larger effect on the surface soil than does the atmospheric deposition.     

“混凝气浮-膜生物反应器”处理林化废水工程运行调试研究

本文中根据林化废水特征确定使用"混凝气浮-膜生物反应处理器"的工艺进行处理。工程中硫酸铝的投加量为40mg/L,PAM的投加量为3mg/L,在废水pH值为7～8时进水COD、SS、OIL为279mg/L、20mg/L、26mg/L,进行混凝气浮后,出水的COD、SS、OIL浓度依次为135mg/L、9.6mg/L、9.5mg/L,去除率分别达到了52%、50%、64%。膜生物反应系统的调试,以污泥接种的方式进行污泥培养驯化。初期以面粉作为营养源清水培养污泥,按照7天左右的周期按每次30m3/d的污水进水量逐渐增加污水的比例,直到完全进水,调试驯化期污泥浓度控制在2500～3000mg/L。正常运转中污泥浓度可达到5000mg/L左右,出水水质COD、SS、OIL浓度分别达到30mg/L、6mg/L、3mg/L,符合处理目标要求。     

载Ni-Cu-K活性炭催化氧化法处理染料废水活性红X-3B

以载Ni活性炭为催化剂 ,用空气氧化模拟染料废水活性红X 3B。实验结果表明 ,负载在活性炭上的金属离子起到催化氧化的作用。活性炭对活性红X 3B的COD和色度的去除率能达到 98 74 %以上 ,较不加金属的活性炭去除率提高 30 % ,用活性炭处理浓度为 0 4g/L的模拟废水活性红X 3B ,投加量为 5g/L时 ,催化氧化效果最明显 ,催化氧化作用对色度的去除率达 2 5 33%。     

Co-pyrolysis of sewage sludge and biomass for stabilizing heavy metals and reducing biochar toxicity: A review

The huge amounts of sewage sludge produced by municipal wastewater treatment plants induce major environmental and economical issues, calling for advanced disposal methods. Traditional methods for sewage sludge disposal increase greenhouse gas emissions and pollution. Moreover, biochar created from sewage sludge often cannot be used directly in soil applications due to elevated levels of heavy metals and other toxic compounds, which alter soil biota and earthworms. This has limited the application of sewage sludge-derived biochar as a fertilizer. Here, we review biomass and sewage sludge co-pyrolysis with a focus on the stabilization of heavy metals and toxicity reduction of the sludge-derived biochar. We observed that co-pyrolyzing sewage sludge with biomass materials reduced heavy metal concentrations and decreased the environmental risk of sludge-derived biochar by up to 93%. Biochar produced from sewage sludge and biomass co-pyrolysis could enhance the reproduction stimulation of soil biota by 20‒98%. Heavy metals immobilization and transformation are controlled by the co-feed material mixing ratio, pyrolysis temperature, and pyrolysis atmosphere.

     

The progress and challenges in sustainable forestry development in China

Forestry development in China has undergone a series of reforms over the past six decades. This article examines temporal changes in forest resources and policies, the current status of forestry, and future challenges toward sustainable forest management in China. Excessive logging in the 1950s to 1980s badly damaged the nation’s forests, but the adoption of enlightened forest policies in the late 1990s has led to increases in China’s total forest area and growing stock. Forest degradation was ecologically and economically costly, and rehabilitation processes have become increasingly more expensive. The low quality and young age of forest resources, loss of natural forests, and more difficulties in afforestation and reforestation pose severe challenges for China’s sustainable forestry. It is critically important for China to enhance forest productivity through intensive management, strengthen enforcement, and educational programs for protecting and restoring natural forests, narrow the gap between domestic timber supply and rapidly expanding consumption, improve coordinating networks for management, finance, and technology transfer, and accelerate efforts to clarify and stabilize tenure arrangements for non-state forests. China’s experience and lessons in forestry may be helpful for other developing countries that are seeking to achieve the goal of sustainable forest management.     

汶川8.0级地震都江堰市天然气系统震害分析及救灾过程

四川都江堰市地处龙门山主山前边界大断裂上,在汶川8.0级地震烈度分布图中属于Ⅸ度区,是地震受灾最严重的城市之一。作为城市生命线的天然气供应链在本次地震中遭遇了一定的破坏。通过对都江堰市天然气系统的基本构成、震害情况以及应急救灾过程等的调查与整理,对都江堰燃气系统中门站、CNG加气站、中压配气管网及低压配气支管各组成部分在地震中的震害情况进行了分析,对震后的应急处置措施、供气恢复策略及灾后重建工作进行了综述,总结了汶川地震中都江堰天然气系统的应灾经验及救灾环节中的不足之处,并就如何提高燃气系统的抗震应灾能力提出建议。     

针-板放电等离子体反应器结构参数对甲基橙脱色反应速率常数的影响

采用针-板放电等离子体反应器处理模拟甲基橙(MO)废水,研究了反应器结构参数对MO脱色反应速率常数的影响.实验得出最佳反应器结构参数:阳极为5根不锈钢针并联,针间距为17 mm,针电极长度为2 mm,电极间距为10 mm,O2流量为0.18 m3/h,阴极丝网目数为20目,在阳极上部设置5层间距为15 mm的不锈钢丝介...