Community perceptions of scuba dive tourism development in Bien Unido,Bohol Island,Philippines

The Coastal Conservation and Education Foundation (CCEF), a Philippine environmental organization, in collaboration with Region 7 municipality leaders from Cebu, Leyte, and Bohol, as well as various financial donors, is striving to improve the marine resource management of the Outer Danajon Bank in the Philippines. One of the goals is to develop scuba dive tourism along the Outer Bank, beginning with the municipality of Bien Unido on Bohol Island. Despite previous efforts to attract investors and tourists by the Bien Unido mayor, dive tourism is currently absent from the municipality. During the summer of 2011, the mayor, the CCEF, and a private real estate developer, agreed to invest in infrastructure and livelihood training in Bien Unido for the purpose of developing a scuba dive tourism industry. This study analyzes current community viewpoints on the development of dive tourism in Bien Unido and four selected dive tourist cites. The study consists of thirty-four qualitative interviews conducted in Bien Unido and four other dive tourist sites as well as 1117 quantitative surveys conducted with community members throughout the central portion of the Philippines (Region 7). This study complements the Danajon Bank Marine Park Project of the CCEF and makes recommendations to improve the management of the Danajon Bank Double Barrier coral reef with protected areas and alternative livelihood projects linked to tourism development. The interviews served to define tourism and to document the specific needs of each barangay, or community, for tourism development. The qualitative survey revealed generally positive attitudes regarding scuba dive tourism development. Nintey-one percent of respondents believe tourism will help the barangay and most would participate in selling food/drink or being a recreational tour guide for tourists. Interview and survey respondents expectations that economic benefits will outweigh any social or environmental challenges, primarily alternative livelihoods and increased revenue for the municipality. Overall, Bien Unido and Region 7 community members will likely welcome visitors to their communities due to the expected benefits regardless of other negative environmental and social externalities such as increases in resource pressures and losses of tradition. Four additional municipalities were selected as “tourism developed sites” to further explore the negative and positive impacts of dive tourism, as perceived by the barangay captains or council, over a range of five to thirty years. These findings revealed challenges that were not mentioned in Bien Unido interviews or in the Region 7 qualitative surveys including changes in the price of living, increases in drug trafficking and sex trade, and private investors controlling community decisions.

“As long as tourists like to come, then we want them all. If they will come, we will welcome them all.” Bien Unido interviewee, July 19, 2011

     

Characterization and application of the enzyme peroxidase to the degradation of the mycotoxin DON

Deoxynivalenol (DON), one of the main mycotoxins found in food matrices, has high level of toxicity. This study aimed to characterize the peroxidase enzyme extracted from rice bran to be applied to the biodegradation of DON in order to evaluate the potential peroxidase (PO) from rice bran (RB) has to degrade DON in optimal conditions. Purification and recovery factors of PO extracted from RB and purified by three-phase partitioning were 5.7% and 50%, respectively. PO had the highest level of activity in the phosphate buffer 5 mM pH 5.5 in both crude and purified forms, whose reaction temperatures were 25°C and 10°C. At the end of production, purification and characterization steps, specific activities of the bran were 115.79 U mg^?1 and 4363 U g^?1. Reduction in the mycotoxin DON in optimal conditions determined for PO from RB was 20.3%, a promising result when the aim is to adequate mycotoxicological levels to foods.     

How certain can we really be that our boss is trustworthy,and does it matter? A metacognitive perspective on employee evaluations of supervisor trustworthiness

This research helps to integrate the metacognitive concept of evaluation certainty into the trust literature by demonstrating that certainty can amplify the effects of trustworthiness evaluations and stabilize trustworthiness evaluations over time. Across an experimental study (Study 1) and a multiwave survey of employees (Study 2), we show that trustworthiness evaluations exert a stronger influence on individuals' trust at higher levels of certainty and that trust transmits the multiplicative effects of trustworthiness evaluations and certainty on key indicators of employee risk-taking including reliance and disclosure behavior. Further, in Study 2, we show that certainty can help predict change in trustworthiness evaluations over time. Finally, in a two-wave field survey (Study 3), we examine factors that influence evaluation certainty and show that relational transparency and leader prototypicality (LP) have interactive effects on employees' certainty such that the influence of relational transparency on certainty will be more positive at higher levels of LP. Theoretical and practical implications are discussed.     

Toxicity assessment of 2,4-D and MCPA herbicides in primary culture of fish hepatic cells

In this study, we used primary cultures of fish hepatic cells as a tool for evaluating the effects of environmental contamination. Primary hepatic cell cultures derived from the subtropical fish Metynnis roosevelti were exposed to different concentrations (0.275, 2.75 and 27.5 μg L^?1) of the herbicides 2,4-dichlorophenoxyacetic acid (2,4-D) and 4-chloro-2-methylphenoxyacetic acid (MCPA). Cellular respiratory activity was evaluated by polarography using three substrates: 0.5 M glucose, 0.5 M succinate and 0.5 M α-ketoglutarate. Significant changes were observed in cellular oxygen consumption with 0.5 M α-ketoglutarate. Even at low concentrations, 2,4-D and MCPA were potent uncouplers of oxidative phosphorylation. Primary cultures of M. roosevelti liver cells may provide a useful tool for the evaluation of environmental contaminant effects. A review of regulations regarding permitted concentrations of these herbicides is needed.     

Effect of coumaphos on cholinesterase activity,hematology, and biochemical blood parameters of bovines in tropical regions of Mexico

To assess the effect of coumaphos [O-(3-chloro-4-methyl-2-oxo-2H-1-benzopyran-7-yl) O,O-diethyl phosphorothioate] exposure on physiological responses during bovine production, acetylcolinesterase (AChE) and butyrylcholinesterase (BuChE) activities were measured in whole blood, erythrocytes, and plasma of healthy male steers (Bos Taurus x Bos indicus) sprayed with coumaphos at a non-lethal dose of 1 mg kg^{? 1} body weight per day once every 14 (in vivo group) or 21 days (southern and central groups). Coumaphos topically administered at 1 mg/kg body weight per day to cattle under normal management practices in tropical areas produced a significant inhibition in erythrocyte (RBC) AChE and BuAChE activities when compared to baseline levels. RBC-AChE activity for the in vivo group decreased 71.3% (P < 0.05) and BuChE activity 59.1% (P < 0.05); RBC-AChE activity decreased 55.1% (P < 0.05) (southern group) and 43.4% (P < 0.05) (central group). Compared to the control specimens, steers from in vivo, southern, and central groups after 150 days of exposure had lower (P < 0.05) leukocyte count, absolute lymphocyte, erythrocyte, and platelet counts. Decreases in RBC-AChE activities correlated with decreased lymphocyte (r = 1.000, p = 0.01), erythrocyte (r = 1.000, p = 0.003), and platelet counts (r = 0.841, p = 0.036). Significantly increased BUN levels (P < 0.05) correlated with the decrease in RBC-AChE activities (r = ? 0.997, p = 0.047) and with the decrease in absolute red blood cell (r = ? 0.883, p = 0.020) and lymphocyte (r = ? 0.825, p = 0.043) counts; increased (P < 0.05) total plasma protein levels correlated with the decrease in RBC-AChE activities (r = ?0.998, p = 0.043), absolute red blood cell (r = ? 0.998, p = 0.040), lymphocyte (r = ? 0.893, p = 0.017), and platelet (r = -0.855, p = 0.030) counts. The physiological responses correlated with the erythrocyte acetylcholinesterase inhibition could be considered as early indicators or warning responses of bovine exposures to organophosphorus pesticides (OPs).     

Combined use of a transformed red mud reactive barrier and electrokinetics for remediation of Cr/As contaminated soil

A reactive barrier (RB) of transformed red mud (TRM), a by-product of the refinement of bauxite in alumina production, was placed adjacent to the anode of an electrokinetic (EK) system with the aim of enhancing removal of chromium or arsenic, added singly to a low permeability clayey soil, and favouring entrapment. The innovative study focused on evaluation of the synergic interaction between the EK system and the RB, and of the efficiency when compared to traditional EK remediation (control tests). The results obtained underlined the successful outcome of treatment of the Cr(VI)-contaminated soil. In presence of the TRM RB, 19.4% wt. of total Cr content was detected in the anolyte and 20.6% wt. trapped in the anodic RB after 6 d, versus 6.6% wt. in the anolyte and 8.8% wt. in the soil adjacent to the anode following the control run without RB. On increasing duration of treatment up to 12 d, 60.8% wt. of total initial Cr was found in the anolyte and 25.5% wt. trapped in the RB, versus 9.1% wt. and 5.3% wt., respectively, after a control run of the same duration. Finally, on increasing the mass of TRM in the RB, 60.6% wt. of initial Cr content was found to have accumulated in the RB, with Cr being completely absent from the anodic chamber. Conversely, combined treatment was much less effective on As contaminated soil, at least under the operative conditions applied. Low initial As concentration and interference with iron oxides in the soil were likely the reasons underlying low efficiency while attempting As decontamination.     

The views of experts and residents on social vulnerability to flash floods in an Alpine region of Italy

This paper reports on research work performed for Floodsite a European Community-funded project on the social aspects of vulnerability in the Adige/Sarca river basin of the Trentino-Alto Adige region, Italy. It identifies some limitations to the use of a fixed set of indicators, which fail to account for either local peculiarities or the intangible aspects that contribute to the shaping of social vulnerability. The authors employed a number of methods to investigate the opinions of professionals and residents on risk and safety, distinguishing between the individual and the institutional components of social vulnerability. Adopting a systemic perspective, they explored the interactions between these two elements, showing how they may give rise to unexpected phenomena. The 'safety paradox' and the 'efficiency paradox' are discussed, emerging when increased protection provided by structural devices and dedicated institutions translates into a lack of awareness and agency on the part of residents.     

Comparisons of EPA Rollback,Empirical/Kinetic,and Physicochemical Oxidant Prediction Relationships in the San Francisco Bay Area

This paper describes, compares and evaluates selected Oxidant Prediction Relationships {OPRs) in terms of projections of hydrocarbon emission reductions required for attainment of the former 0.08 ppm standard and the new 0.12 ppm standard in the San Francisco Bay Area in 1985. The OPRs analyzed are the LIRAQ physicochemical model, EPA’s Empirical Kinetic Modeling Approach (EKMA), linear and Appendix J rollback, and an empirical OPR based on local observations.

LIRAQ simulations indicated that to achieve the 0.12 ppm ozone standard, 1985 hydrocarbon emissions must be reduced by 27% from projected levels. The equivalent reductions derived from simple linear rollback, linear rollback with 0.04 ppm background, and the local empirical OPR were 32%, 45% and 37%, respectively. The LIRAQ simulations also showed that reduction of both hydrocarbon and NO_x emissions is less effective than reduction of hydrocarbons only. The attempt to apply EKMA failed because the Bay Area’s low hydrocarbon/NO_x ratios and observed ozone levels are not consistent with the standard EKMA isopleth curves.

For planning, proper OPR selection is important because the wide range in the projections of various OPRs translates into a correspondingly wide range in control costs. Physicochemical OPRs are preferred because they are verifiable; they account for complex topography, meteorology, and source distributions; and because they can treat a variety of control strategies. In the future, the uncertainties associated with the projections can be resolved by assessing trends in air quality on a regular basis and by upgrading and reapplying the prediction methodologies as new information becomes available.     

Studies on degradation of glyphosate by several oxidative chemical processes: Ozonation,photolysis and heterogeneous photocatalysis

Several different Advanced Oxidation Processes (AOPs) including ozonation at pH 6.5 and 10, photolysis and heterogeneous photocatalysis using TiO₂ as semiconductor and dissolved oxygen as electron acceptor were applied to study the degradation of glyphosate (N-phosphonomethyl glycine) in water. The degree of glyphosate degradation, the reactions kinetic and the formation of the major metabolite, aminomethyl phosphonic acid (AMPA), were evaluated. Ozonation at pH 10 resulted in the maximum mineralization of glyphosate. It was observed that under the experimental conditions used in this study the degradation of glyphosate followed the first-order kinetics. The half-life obtained for glyphosate degradation in the O₃/pH 10 process was 1.8 minutes.