钙钛矿型催化剂催化湿式氧化处理煤气化废水纳滤浓缩液

采用溶胶-凝胶法制备了Mn掺杂钙钛矿型催化剂LaFexMn1-xO3,并以其为催化剂催化湿式双氧水氧化处理煤气化废水纳滤浓缩液。采用XRD,SEM,FTIR技术对催化剂进行了表征。表征结果显示：制备的催化剂均具有标准的钙钛矿型结构,其中,LaFe0.9Mn0.1O3的结构稳定,比表面积大。实验结果表明：制备的催化剂中LaFe0.9Mn0.1O3的催化活性最高,且稳定性好,连续使用5次后催化活性未见明显减弱;在H2O2投加量3.0 g/L、n（H2O2）∶n（LaFe0.9Mn0.1O3）=12∶1、反应温度160 ℃、反应压力1 MPa、浓缩液pH 3、反应时间60 min的最优条件下,COD、UV254和TOC的去除率分别达到80.9%、95.2%和68.0%,BOD5/COD由0.02提升至0.40,可生化性大幅提高。     

Polychlorinated biphenyls (PCBs) and halogenated flame retardants (HFRs) in multi-matrices from an electronic waste (e-waste) recycling site in Northern China

The present study investigated the occurrence of polychlorinated biphenyls (PCBs) and halogenated flame retardants (HFRs) in soil, water, reed, air and dust samples collected from the e-waste recycling region in Ziya Town, Northern China. The results showed that the concentrations of PCBs reached relative high level in environmental matrices in the study area. HFRs including polybrominated diphenyl ethers (PBDEs), dechlorane plus (DP), allyl 2,4,6-tribromophenyl ether (ATE), tetrabromoethylcyclohexane (TBECH), pentabromotoluene (PBT), pentabromoethylbenzene (PBEB), 2,3-dibromopropyl 2,4,6-tribromophenyl ether (DPTE), 1,2-bis-(2,4,6-tribromophenoxy) ethane (BTBPE) and so on were also widely detected in multi-matrices. Long-range atmospheric transport (LRAT) potentials of non-BDE HFRs were assessed to address the LRAR abilities of these compounds. Analysis of soil–air exchange of PCBs and HFRs showed that soil acted as a secondary source to the atmosphere only for a few low molecular weight compounds, while the direction of the flux of most detected chemicals was from air to soil.     

工业企业安全生产管理的规范化研究

根据安全系统工程原理,探讨和提出了一种被当地试点所证明、可行的工业企业安全生产综合、简便的规范化管理方法。把国家有关安全生产法律法规有机地贯穿于基础规范管理工作过程之中;建立了动态性管理模式;为积极引导企业的安全管理工作,由事故管理向预防性管理,从行政管理向依法管理,由传统管理向技术性管理的方向转变,并为促进现代企业形成自主经营,相互制约,依法管理安全生产的运行机制提供了新思路     

Characterization and control of odorous gases at a landfill site: a case study in Hangzhou, China

Municipal solid waste (MSW) landfills are one of the major sources of offensive odors potentially creating annoyance in adjacent communities. At the end of May 2007, an odor pollution incident occurred at the Tianziling landfill site, Hangzhou, China, where the residents lodged complaints about the intense odor from the landfill, which drew a significant attention from the government. In this study, ambient air monitoring was conducted at the Tianziling landfill site. The main odor composition of the gas samples collected on June 1st 2007 and the reduction of various odorous gases from the samples collected on June 1st 2009 due to the applied odor control techniques were determined using gas chromatography-mass spectrometry (GC-MS). In addition, variations of primary odorous gaseous (NH₃ and H₂S) concentrations at different locations in the landfill site from July 2007 to June 2009 were also investigated by using classical spectrophotometric methods. Results showed that a total of 68 volatile compounds were identified among which H₂S (56.58-579.84 μg/m³) and NH₃ (520-4460 μg/m³) were the notable odor components contributing to 4.47-10.92% and 83.91-93.94% of total concentrations, respectively. Similar spatial and temporal shifts of H₂S and NH₃ concentrations were observed and were significantly affected by environmental factors including temperature, air pressure and wind direction. Odor pollution was worse when high temperature, high humidity, low air pressure, and southeast, northeast or east wind appeared. Moreover, the environmental sampling points of the dumping area and the leachate treatment plant were found to be the main odor sources at the Tianziling landfill site. The odor control technologies used in this project had a good mitigating effect on the primary odorous compounds. This study provides long-term valuable information concerning the characteristics and control of odors at landfill sites in a long run.     

企业安全评价分析的主成分方法

依据某机车车辆厂的特点,建立了安全性评价指标体系,并应用主成分分析法对数据进行分析处理,求出指标综合表达式和排序结果,从而得到指标的客观权重,并指出了主成分法应用于安全评价中的特点。     

风险评价标准值初探

提出了风险指标和ALARP原则的含义,从风险评价的ALARP原则出发,得出个人风险评价标准值和社会风险评价标准值的制定方法。     

空中交通管制中人的可靠性模糊综合评价研究

人是空中交通管制系统中最灵活、最具适应性和最有价值的因素 ,而其行为也是最易受到不利影响的。由于空中交通管制中产生的人为失误 ,往往会导致航空器空中危险接近 ,严重的后果甚至会酿成空难。笔者从人 -机 -环境系统工程的观点出发 ,提出了空中交通管制中人的可靠性评价的指标体系结构模型。从人自身因素、软件、硬件、环境等方面指出了影响空中交通管制中人的可靠性的心理、空中环境等 17个子因素。运用模糊数学的方法 ,建立空中交通管制中人的可靠性定量评价模型 ,并用实例进行了验证。研究表明 ,该方法应用于空中交通管制中人的可靠性评价是一种新的尝试 ,其评价结果可为各级领导机构提供航空安全管理的决策依据。     

长袋低压脉冲除尘器的创新与发展

依靠科技进步，应用多项专利技术，研制与开发的LFDM型长袋低压脉冲除尘器，成功应用于冶金、有色、建材、电力、机械和矿业等行业的工业气体除尘与净化；具有明显的达标排放和占地小、阻力低、投资省、运行费用少等特点。     

基层应急预案框架研究

1 基层应急预案研究对象 　　基层的概念是指最低的层次.实行直接性管理,是它最突出的特点,即直接面对人民群众,直接接受人民群众的监督,其一切管理活动都具有直接性而没有中间环节.我国基层社会单元一般可分为两类,一类是群众性自治组织,即居民委员会和村民委员会,是以保障居民或村民利益为出发点,在基层政权组织的指导、支持和帮助下开展工作的;另一类是企事业单位,如学校、科研机构、企业等,是以社会公益或盈利为目的,主要受法律法规和行业管理约束,具有独立法人资格的机构.……     

浅谈石化企业体系审核策划的增值

从审核方案策划和审核实施策划两个方面就审核策划的增值方案制订、实施方式和途径进行了探讨。