Evaluation of the best compromise between the urban air quality monitoring resolution by diffusive sampling and resource requirements

The need to collect data representative of overall urban pollution is all-important in order to monitor the population exposure. High spatial resolution monitoring using diffusive samplers allows studying of the urban pollutant distribution, thus enabling deeper investigation of their generation and diffusion mechanisms. Nevertheless, such a monitoring campaign has a certain cost. In this study we point out how to find the best compromise between the number of necessary measurements and the affordable costs for monitoring campaigns. We also describe an innovative method for the proper design of a fixed urban monitoring network by means of preliminary high spatial resolution campaigns using diffusive samplers. Four European capital cities (Dublin, Madrid, Paris and Rome) were monitored six times, each time for seven days. Benzene, toluene, ethylbenzene, xylenes (BTEX) and NO(2) concentrations were measured at 146 sites in Dublin, 293 in Madrid, 339 in Paris and 290 in Rome. Multiscale grids have been drawn which ranged in mesh size from 500 m to 2 km. The statistical processing of data produced a twofold result: the creation of isoconcentration maps with geostatistical procedures, and an algorithm aimed at locating the minimum number of sampling sites where the fixed monitoring stations should be placed. Average urban levels estimated on the basis of these selected sites differ by less than 8% from those calculated on the whole populations of the sampled points. The aim of this work is to investigate how far the resolution of a monitoring campaign of urban pollution by diffusive sampling can be reduced, thus making the monitoring less expensive in terms of human and financial resources, while preserving the same quality of the results that could be achieved with a higher resolution. We found that there is no significant loss of information when the resolution of the monitoring grid for BTEX is lowered to a mesh size of 1.85 km, that is a sampling site each 3.4 km(2), and that the minimum number of sampling sites to be used is N = 0.29 A, where A is the urban surface to be monitored (in km(2)). As the spatial distribution of NO(2) is less sensitive to the distance from the emission source than that of BTEX, this relationship could be retained as a valid lower limit for the mesh grid size also for NO(2) monitoring.     

YouTube,Social Norms and Perceived Salience of Climate Change in the American Mind

This online experiment explored how contextual information embedded in new media channels such as YouTube may serve as normative social cues to users. Specifically, we examined whether the number of views listed under a YouTube video about climate change would elicit inferences regarding how “others” feel about the climate issue and, consequently, might influence perceptions of issue salience. Participants in this experiment were exposed to a YouTube video about climate change using two experimental conditions, one providing a small number of views under the video and the second listing a large number of views. Results suggest that the “number of views” cue did, indeed, influence participant perceptions of the importance assigned by other Americans to the issue of climate change. Further, compared to low self-monitoring participants, high self-monitoring participants registered an increase in their own judgment of issue importance.     

There Are More Than Three Reasons to Consider Sustainable Remediation,a Dutch Perspective

This article provides an overview of the developments concerning sustainable remediation (SR) from the authors’ perspective. A short history of policy development is outlined, in which the focus mainly lies on the Netherlands since this is the homeland of the majority of the authors. The Netherlands is a densely populated country with high pressure on land and was in the forefront of developments in soil policy. The authors plead for simplicity in approaches, as history has proven that the simpler theory more often is true, and above all will better be understood by stakeholders and, thus, will more easily lead to consensus. Implicitly the authors make clear that SR not only has benefits from a societal, economic, and environmental point of view, but if the methodologies are implemented correctly, it leads to more robust and supported decision making. Moreover, it opens the road to flexible and integral remedial objectives that enable innovative and creative solutions for soil and groundwater contamination. The proposed methodologies and creative innovations are illustrated with full‐scale operational cases. ©2017 Wiley Periodicals, Inc.     

Diversity of active microbial communities subjected to long-term exposure to chemical contaminants along a 40-year-old sediment core

In estuarine ecosystems, metallic and organic contaminants are mainly associated with fine grain sediments which settle on mudflats. Over time, the layers of sediment accumulate and are then transformed by diagenetic processes mainly controlled by microbial activity, recording the history of the estuary’s chemical contamination. In an environment of this specific type, we investigated the evolution of the chemical contamination and the structure of both total and active microbial communities, based on PhyloChip analysis of a 4.6-m core corresponding to a 40-year sedimentary record. While the archaeal abundance remained constant along the core, a decrease by one order of magnitude in the bacterial abundance was observed with depth. Both total and active microbial communities were dominated by Proteobacteria, Actinobacteria, and Firmicutes in all sediment samples. Among Proteobacteria, alpha-Proteobacteria dominated both total (from 37 to 60 %) and metabolically active (from 19.7 to 34.6 %) communities, including the Rhizobiales, Rhodobacter, Caulobacterales, and Sphingomonadales orders. Co-inertia analysis revealed a relationship between polycyclic aromatic hydrocarbons, zinc and some polychlorobiphenyls concentrations, and the structure of total and active microbial communities in the oldest and most contaminated sediments (from 1970 to 1975), suggesting that long-term exposure to chemicals shaped the structure of the microbial community.     

Organic micropollutants’ distribution within sludge organic matter fractions explains their dynamic during sewage sludge anaerobic digestion followed by composting

The simultaneous fate of organic matter and 4 endocrine disruptors (3 polycyclic aromatic hydrocarbons (PAHs) (fluoranthene, benzo(b)fluoranthene, and benzo(a)pyrene) and nonylphenols (NP)) was studied during the anaerobic digestion followed by composting of sludge at lab-scale. Sludge organic matter was characterized, thanks to chemical fractionation and 3D fluorescence deciphering its accessibility and biodegradability. Total chemical oxygen demand (COD) removal was 41% and 56% during anaerobic digestion and composting, respectively. 3D fluorescence highlighted the quality changes of organic matter. During continuous anaerobic digestion, organic micropollutants’ removal was 22?±?14%, 6?±?5%, 18?±?9%, and 0% for fluoranthene, benzo(b)fluoranthene, benzo(a)pyrene, and nonylphenols, respectively. Discontinuous composting allowed to go further on the organic micropollutants’ removal as 34?±?8%, 31?±?20%, 38?±?10%, and 52?±?6% of fluoranthene, benzo(b)fluoranthene, benzo(a)pyrene, and nonylphenols were dissipated, respectively. Moreover, the accessibility of PAH and NP expressed by their presence in the various sludge organic matter fractions and its evolution during both treatments was linked to both the quality evolution of the organic matter and the physicochemical properties of the PAH and NP; the presence in most accessible fractions explained the amount of PAH and NP dissipated.

     

Long-term records of cadmium and silver contamination in sediments and oysters from the Gironde fluvial-estuarine continuum - evidence of changing silver sources

The Gironde fluvial estuarine system is impacted by historic metal pollution (e.g. Cd, Zn, Hg) and oysters (Crassostrea gigas) from the estuary mouth have shown extremely high Cd concentrations for decades. Based on recent work (Chiffoleau et al., 2005) revealing anomalously high Ag concentrations (up to 65 mg kg⁻¹; dry weight) in Gironde oysters, we compared long-term (∼1955-2001) records of Ag and Cd concentrations in reservoir sediment with the respective concentrations in oysters collected between 1979 and 2010 to identify the origin and historical trend of the recently discovered Ag anomaly. Sediment cores from two reservoirs upstream and downstream from the main metal pollution source provided information on (i) geochemical background (upstream; Ag: ∼0.3 mg kg⁻¹; Cd: ∼0.8 mg kg⁻¹) and (ii) historical trends in Ag and Cd pollution. The results showed parallel concentration-depth profiles of Ag and Cd supporting a common source and transport. Decreasing concentrations since 1986 (Cd: from 300 to 11 mg kg⁻¹; Ag: from 6.7 to 0.43 mg kg⁻¹) reflected the termination of Zn ore treatment in the Decazeville basin followed by remediation actions. Accordingly, Cd concentrations in oysters decreased after 1988 (from 109 to 26 mg kg⁻¹, dry weight (dw)), while Ag bioaccumulation increased from 38 up to 116 mg kg⁻¹, dw after 1993. Based on the Cd/Ag ratio (Cd/Ag ∼ 2) in oysters sampled before the termination of zinc ore treatment (1981-1985) and assuming that nearly all Cd in oysters originated from the metal point source, we estimated the respective contribution of Ag from this source to Ag concentrations in oysters. The evolution over the past 30 years clearly suggested that the recent, unexplained Ag concentrations in oysters are due to increasing contributions (>70% after 1999) by other sources, such as photography, electronics and emerging Ag applications/materials.     

Impact of sewage sludge treatment processes on the removal of the endocrine disrupters nonylphenol ethoxylates

Several treatment processes of mixed sludge naturally contaminated with nonylphenol ethoxylates (NPE) were compared in order to evaluate their efficiency for the removal of these endocrine disrupters. Anaerobic and aerobic treatments were carried out in continuous stirred tank reactors, operated separately or combined together, at mesophilic and thermophilic temperatures and with or without ozone post-treatment. Anaerobic mesophilic removal of NPE consisted of complete removal of nonylphenol diethoxylate, incomplete removal of nonylphenol monoethoxylate and non stoechiometric production of nonylphenol, with consequently a NPE removal of 25%. At thermophilic temperature, anaerobic digestion led to an increase of the total solids removal efficiency, while improving NPE degradation (30%). Under thermophilic aerobic condition, the three compounds were removed simultaneously with a NPE removal efficiency higher than under anaerobic condition (39%). This removal is always well correlated to the total solids removal meaning that bioavailability remains the main limiting factor. Combination of either thermophilic aerobic-mesophilic anaerobic or mesophilic anaerobic-ozonation treatments enhanced the NPE removal by comparison to single systems (45% and 48%, respectively). These results confirm the high potential of existing and up-grading sewage sludge treatments to degrade such refractory and aged compounds.     

Application of SMR to Modeling Watersheds in the Catskill Mountains

Very few hydrological models commonly used in watershed management are appropriate for simulating the saturation excess runoff. The Soil Moisture Routing model (SMR) was developed specifically to predict saturation excess runoff from variable source areas, especially for areas where shallow interflow controls saturation. A recent version of SMR was applied to two rural catchments in the Catskill Mountains to evaluate its ability to simulate the hydrology of these systems. Only readily available meteorological, topographical, and landuse information from published literature and governmental agencies was used. Measured and predicted streamflows showed relatively good agreement; the average Nash–Sutcliffe efficiency for the two watersheds were R ²=72% and R ²=63%. Distributed soil moisture contents and the locations of hydrologically sensitive areas were also predicted well.     

Bus fleet emissions: new strategies for mitigation by adopting natural gas

Energy consumption is related to local, regional and global impacts. Thus, by comparing different replacement scenarios of diesel vehicles with compressed natural gas, this article estimates pollutants and greenhouse gases emission in the city of São Paulo, Brazil. The calculation of fuel consumption is based on fleet characteristics, in terms of vehicle age, the average annual distance travelled by bus depending on the year and average fuel consumption. These values served as a basis to develop scenarios considering that a percentage of new vehicles that will be phased out and replaced with ones running on natural gas. Results show that the total avoided emissions can range from 579 thousand tons to 1.375 million tons of carbon dioxide (CO₂₎ over 20 years, depending on the scenario. For particulate matter, accumulated avoided emissions vary from 251 thousand to 584 tons over 20 years. The replacement of diesel buses with natural gas-fuelled buses presents favourable results, in comparison with the tendency scenario for CO₂ and particulate matter. Thus, a public policy for fuel replacement in largest cities, such as Sao Paulo, has an important global impact, especially when allowing the introduction of a renewable energy source, such as biogas. It will benefit from the natural gas previous infrastructure, which is largely available in Brazil. As recommendations, we explain the need to review the city of Sao Paulo Climate Change Law to allow the use of natural gas. Fuel replacement should be integrated with a public policy/public policies and operational strategies to promote citizens´ health as well as historical, cultural and heritage conservation for the city and its future generations.     

Prenatal diagnosis of MPPH syndrome

We report the prenatal sonographic detection of a fetus with megalencephaly, polymicrogyria, postaxial polydactyly and hydrocephaly. Only 14 patients have been reported in the literature so far, all but one were diagnosed postnatally. The polymicrogyria in the frontoparietal lobe was confirmed by prenatal magnetic resonance imaging. Additionally, a hypoplastic thymus as seen in a 22q11 deletion was present. Although polymicrogyria along with pre-axial polydactyly has been described in 22q11 deletion, the diagnosis of Di George syndrome was ruled out. The etiology of megalencephaly, polymicrogyria, postaxial polydactyly and hydrocephaly has not been revealed yet. A dominant as well as recessive inheritance has been suggested. © 2013 John Wiley & Sons, Ltd.