黄河三角洲人工草场群落土壤盐分动态集成预报模型及其应用

提出了以ＧＭ（１,１）模型拟合发展的趋势、傅里叶变换撮周期分量ＡＲ（ｐ）模型模拟随机过程的集成预报模型,并用于黄河三角洲人工草场群落土壤盐分的定量研究中,经理论和应用检验证明：该模型能以较高的精度模拟或预报土壤盐分在较长时期内的动态变化过程,方法简单,计算工作量小,并优于传统的单一预报模型。     

1984～2017年太湖岛屿的动态变化及驱动因子分析

近些年来,围堰、跨区域调水、清淤等人类活动导致太湖中的岛屿面积的变化及其边界的迁移。基于Landsat遥感影像探究太湖内岛屿面积的变化趋势及边界的迁移方向,一定程度上反映人为因素对岛屿动态变化的的影响,进而指导太湖治理工作。通过波段分析、非监督分类以及分类后处理的方法从Landsat影像中提取岛屿信息,获得1984～2017年不同时期的岛屿面积和边界数据,并对岛屿面积和边界数据进行动态变化趋势的分析,最终结合从文献、年鉴和其他与太湖相关资料中总结的与太湖岛屿相关的人为活动信息分析引起太湖主要岛屿动态变化的原因。研究表明:小贡山、漫山岛和三山岛屿总面积均呈下降趋势,但下降程度与年际间波动幅度不同,岛屿面积变化的人为驱动因素可归纳为清淤和旅游开发,自然驱动因子为流水侵蚀;岛屿边界的迁移与"禁止围网养殖"、"湿地公园建设"等政策实施呈现显著相关性,且具体变化与政策颁布之间存在时间上的滞后性。     

浅谈我国推行排污许可制度难点及对策

我国排污许可制度推行已有二十余年,但由于在政策设计层面、技术支撑层面及配套保障层面尚有不足之处,排污许可制度在推行过程中遇到很多阻碍,排污许可制度的应用范围、实施效果和改革举措实际落地都还不尽如人意,依然处于难以推广的境地。本文基于对以上各层面存在问题的深入分析,进而指出目前阻碍排污许可制度推行的难点问题及具体成因,其中难点问题主要包括专项法律法规缺失、管理要求落地难、各方权责落实难、多套数据并行、排放标准滞后、部分行业标准缺失、与环境目标未建立响应关系、管理方式落后、数据支撑和人员配备不足等方面。根据前述问题的论证,本文相应提出了推进排污许可制度改革的各项对策措施,并建议排污许可制度应形成上下联动的工作格局,进一步夯实技术支撑基础和完善配套保障措施,以期助力排污许可制度各项改革举措的实际落地,更好地推进排污许可制度的有效实施,建立系统完整、权责清晰、监管有效的管理格局,最终实现排污许可"一证式"管理模式。     

Influence of Al-oxide on pesticide sorption to woody biochars with different surface areas

Biochars’ properties will change after application in soil due to the interactions with soil constituents, which would then impact the performance of biochars as soil amendment. For a better understanding on these interactions, two woody biochars of different surface areas (SA) were physically treated with aluminum oxide (Al-oxide) to investigate its potential influence on biochars’ sorption property. Both the micropore area and mesopore (17～500 Å in diameter) area of the low-SA biochar were enhanced by at least 1.5 times after treatment with Al-oxide, whereas the same treatment did not change the surface characteristics of the high-SA biochar due partly to its well-developed porosity. The enhanced sorption of the pesticide isoproturon to the Al-oxide-treated low-SA biochar was observed and is positively related to the increased mesopore area. The desorption hysteresis of pesticide from the low-SA biochar was strengthened because of more pesticide molecules entrapped in the expanded pores by Al-oxide. However, no obvious change of pesticide sorption to the high-SA biochar after Al-oxide treatment was observed, corresponding to its unchanged porosity. The results suggest that the influence of Al-oxide on the biochars’ sorption property is dependent on their porosity. This study will provide valuable information on the use of biochars for reducing the bioavailability of pesticides.     

Deodorization of pig manure using lignin peroxidase with different electron acceptors

Odor pollution is a big environmental problem caused by large-scale livestock production in China, and developing a practical way to reduce these odors is pressing. In this study, a combination of 0.2–1.0 U/mL lignin peroxidase (LiP) and one of three peroxides (H₂O₂, CaO₂, 2Na₃CO₃·3H₂O₂) was examined for its efficiency in reducing the release of eight chemicals (propionic acid, isobutyric acid, isocaproic acid, isovaleric acid, phenol, p-cresol, indole, and skatole), NH₃, H₂S, and odor intensity from pig manure. The results showed an approximately 90% reduction in p-cresol, 40–60% reduction in odor intensity, 16.5–40% reduction in indolic compounds, and 25–40% reduction in volatile fatty acids. Being the electron acceptors of LiP, 2Na₃CO₃·3H₂O₂ and CaO₂ performed better than H₂O₂ in reducing the concentration of eight chemicals, NH_3, H₂S, and odor intensity from pig manure. The effect of deodorization can last for up to 72 hr.

Implications: In China, one of the major environmental problems caused by confined feeding is odor pollution, which brings a major threat to the sustainability, profitability, and growth of the livestock industry. To couple the LiP with the electron acceptors, a low–cost, simple, and feasible method for odor removal was established in this study. Based on the study results, a practical treatment method was provided for odor pollution and supply the farm operators a more flexible time to dispose treated manure.     

Pollination ecology of <Emphasis Type="Italic">Eomecon chionantha</Emphasis> Hance (Papaveraceae), an endemic species in China

Eomecon chionantha Hance, the only species in the genus Eomecon, is an angiosperm species endemic to China. Here we investigated the pollination syndrome, pollinator generalization of E. chionantha. Our results showed that the individual flower longevity of E. chionantha was 3–5 days. The flowering phenology of E. chionantha can be divided into five phases. We found significant differences in the pollination efficiency of the different insects visiting E. chionantha with bees and flies being the most efficient pollinators. This, in addition to floral morphology and phenology, suggests that E. chionantha is generalized on bees and flies and possesses an outcrossing, partially self-compatible and pollinator-dependent breeding system.     

农业源水污染物削减技术探讨

农业面源污染是水体中COD、氮、磷等指标的主要来源。它包括农药化肥施用、畜禽养殖和农村生活污水排放。对农业源水污染物进行削减是实现污染物总量控制的重要手段。通过详细总结国内外现有农业源水污染物削减技术方法,分析对比其优缺点和实用性,筛选出适用于不同农业污染来源的污水处理技术。结果表明,畜禽养殖废水的适宜处理技术有厌氧/缺氧/好氧(A/A/O)、序批式活性污泥法(SBR)、膜生物反应器(MBR)、升流式厌氧污泥床(UASB)、厌氧沼气池;农地施肥污水的适宜处理技术有SBR、MBR、UASB;农村生活污水的适宜处理技术有厌氧沼气池、生物滴滤池、人工湿地、稳定塘。     

不同培养条件下锰过氧化物酶(MnP)的合成及其对甲基橙的降解

高效、大规模、低成本合成木质素降解酶是直接采用其降解难降解有机污染物所必须解决的问题.对锰过氧化物酶(MnP)降解甲基橙和在非灭菌的反应器中连续合成MnP的可行性进行考察.结果表明,在采用2 mmol H2O2和1.5 mmol MnSO4的降解体系中,获最大脱色效果,且100、200和300 U/L的MnP可在8h内将甲基橙分别脱色18％、23％和35％;在非灭菌的反应器水平上实现了固定化培养的P.chrysosporium连续23 d合成MnP,但MnP酶活仅为2～ 23 U/L,难以酶解甲基橙;然而,在摇瓶培养条件下固定化的P.chrysosporium合成的MnP却能达1 152 U/L.因此,直接采用MnP对污染物进行降解以及在非灭菌的反应器中持续合成MnP是可行的,但就在非灭菌条件下如何提高MnP的合成量还有待开展深入的研究.     

MCM-41分子筛负载铁铈催化降解甲基橙

采用等体积浸渍法制备了负载型有序介孔Fe-Ce/MCM-41催化剂。研究了该催化剂降解甲基橙的适宜工艺条件,并采用XPS,XRD,TEM技术对该催化剂进行了表征。实验结果表明,该催化剂Fenton氧化降解甲基橙的较适宜工艺条件为:溶液pH 5.0、甲基橙溶液初始质量浓度100 mg/L、催化剂加入量2.0 g/L、H_2O_2浓度20 mmol/L,在此适宜条件下反应120 min时,甲基橙去除率接近100%。表征结果显示:Fe-Ce/MCM-41催化剂主要由铁、铈、氧、碳4种元素组成;铁与铈的摩尔比接近3∶1;铁和铈主要以Fe_3O_4和CeO_2的形态存在于催化剂表面。     

流动注射分光光度法测定水中铝的含量

以桑色素作显色剂,采用流动注射分光光度法测定水中铝的含量。在桑色素质量浓度为0．8g／L、聚氧乙烯辛基苯基醚体积分数为1．0％、进样环体积为400μL、检测波长420nm的条件下,采用流动注射分光光度法对水中铝的含量进行测定,本方法的线性范围为2～300μg／L,检出限（信噪比为3）为0．124μg／L,相对标准偏差为2．9％,加标回收率为96．4％～101．8％。