Ecotoxicological effects of an aged TiO2 nanocomposite measured as apoptosis in the anecic earthworm Lumbricus terrestris after exposure through water, food and soil

Titanium dioxide nanoparticles seem to have a low toxicity to terrestrial organisms, though few studies are published in this area. TiO(2) used in sunscreens are nanocomposites where TiO(2) has been coated with magnesium, silica or alumina, as well as amphiphilic organics like polydimethyl siloxane (PDMS), and these coatings are modified by ageing. We assessed the ecotoxicity and propensity for bioaccumulation of an aged TiO(2) nanocomposite used in sunscreen cosmetics, and its potential effect on the frequency of apoptosis in different earthworm tissues. The earthworm Lumbricus terrestris was exposed to the TiO(2) nanocomposite for 7 days in water or 2-8 weeks in soil with the nanocomposite mixed either into food or soil at concentrations ranging from 0 to 100 mg kg(-1). Apoptosis was then measured by immunohistochemistry and Ti localized by XRF microscopy. Results showed no mortality, but an enhanced apoptotic frequency which was higher in the cuticule, intestinal epithelium and chloragogenous tissue than in the longitudinal and circular musculature. TiO(2) nanoparticles did not seem to cross the intestinal epithelium/chloragogenous matrix barrier to enter the coelomic liquid, or the cuticule barrier to reach the muscular layers. No bioaccumulation of TiO(2) nanocomposites could thus be observed.     

A Native Species with Invasive Behaviour in Coastal Dunes: Evidence for Progressing Decay and Homogenization of Habitat Types

A new species has recently invaded coastal dune ecosystems in North West Europe. The native and expansive inland grass, Deschampsia flexuosa, progressively dominating inland heaths, has recently invaded coastal dunes in Denmark, occasionally even as a dominant species. A total of 222 coastal locations with 5,000 random sample plots have been investigated. These findings are in contrast to historical records, and D. flexuosa has never been considered belonging to coastal dune ecosystems. The occurrence of the typical inland grass in the coastal dunes is a strong indication of increase in nutrient level and that human influences may cause a native species to be invasive in new ecosystems. This could be a radical example of change in species composition due to a long lasting exceedance of critical load of nitrogen. The investigation also showed a general increase in cover of the most dominant species.     

Geoelectrical methods for monitoring geological CO2 storage: First results from cross-hole and surface–downhole measurements from the CO2SINK test site at Ketzin (Germany)

The feasibility of monitoring CO₂ migration in a saline aquifer at a depth of about 650 m with cross-hole and surface–downhole electrical resistivity tomography (ERT) is investigated at the CO₂SINK test site close to Ketzin (Germany). The permanent vertical electrical resistivity array (VERA) consists of 45 electrodes (15 in the injection well Ktzi201 and 15 in each of the two observation wells Ktzi200 and Ktzi202), successfully placed on the electrically insulated casings, in the depth range of about 590–740 m with a spacing of about 10 m. The three Ketzin wells are arranged as perpendicular triangle with distances of 50 and 100 m.First synthetic modelling studies indicate an increase of the electrical resistivity of about 200% caused by CO₂ injection, corresponding to a bulk CO₂ saturation of 50%, which is in good agreement with laboratory studies. Finite difference inversion of field data delivers three-dimensional resistivity distributions between the wells which are consistent with the reservoir modelling studies.To increase the limited observation area provided by the cross-hole measurements, additional surface–downhole measurements were deployed. A main CO₂ migration in SE–NW direction is deduced from surface to downhole resistivity experiments.The first cross-hole time-lapse results show that the resolution and the coverage of the electrode array in the Ketzin setting are sufficient to resolve the expected resistivity changes on the characteristic length scale of the electrode array. Significant resistivity changes could be measured, however, detailed information on the CO₂ plume could not be resolved yet by VERA under the existing geological circumstances.     

Stormwater Runoff Quality and Quantity From Traditional and Low Impact Development Watersheds1

Abstract: The quality and quantity of residential stormwater runoff from a control, traditional, and low impact development (LID) watershed were compared in a paired watershed study. A traditional neighborhood was built using typical subdivision standards while a LID design was constructed with best management practices including grass swales, cluster housing, shared driveways, rain gardens, and a narrower pervious concrete‐paver road. Weekly, flow‐weighted, composite samples of stormwater were analyzed for nitrate + nitrite‐nitrogen (NO₃ + NO₂‐N), ammonia‐nitrogen (NH₃‐N), total Kjeldahl nitrogen (TKN), total phosphorus (TP), and total suspended solids (TSS). Monthly composite samples were analyzed for total copper (Cu), lead (Pb), and zinc (Zn). Mean weekly storm flow increased (600x) from the traditional watershed in the postconstruction period. Increased exports of TKN, NO₃ + NO₂‐N, NH₃‐N, TP, Cu, Zn, and TSS in runoff were associated with the increased storm flow. Postconstruction storm flow in the LID watershed was reduced by 42% while peak discharge did not change from preconstruction conditions. Exports were reduced from the LID watershed for NH₃‐N, TKN, Pb, and Zn, while TSS and TP exports increased.     

Waste products from the steel industry with NiO as additive as oxygen carrier for chemical-looping combustion

Fe₂O₃-containing waste materials from the steel industry are proposed as oxygen carrier for chemical-looping combustion. Three such materials, red iron oxide, brown iron oxide and iron oxide scales, have been examined by oxidation and reduction experiments in a batch fluidized-bed reactor at temperatures between 800 and 950 °C. NiO-based particles have been used as additive, in order to examine if it is possible to utilize the catalytic properties of metallic Ni to facilitate decomposition of hydrocarbons into more reactive combustion intermediates such as CO and H₂. The experiments indicated modest reactivity between the waste materials and CH₄, which was used as reducing gas. Adding small amounts of NiO-based particles to the sample increased the yield of CO₂ in a standard experiment, typically by a factor of 1.5–3.5. The fraction of unconverted fuel typically was reduced by 70–90%. The conversion of CH₄ to CO₂ was 94% at best, corresponding to a combustion efficiency of 96%. This was achieved using a bed mass corresponding to 57 kg oxygen carrier per MW fuel, of which only 5 wt% was NiO-based synthetic particles. The different materials fared differently well during the experiments. Red iron oxide was fairly stable, while brown iron oxide was soft and subject to considerable erosion. Iron oxide scales experienced increased reactivity and porosity as function of the numbers of reduction cycles.     

What-You-Look-For-Is-What-You-Find – The consequences of underlying accident models in eight accident investigation manuals

Accident investigation manuals are influential documents on various levels in a safety management system, and it is therefore important to appraise them in the light of what we currently know – or assume – about the nature of accidents. Investigation manuals necessarily embody or represent an accident model, i.e., a set of assumptions about how accidents happen and what the important factors are. In this paper we examine three aspects of accident investigation as described in a number of investigation manuals. Firstly, we focus on accident models and in particular the assumptions about how different factors interact to cause – or prevent – accidents, i.e., the accident “mechanisms”. Secondly, we focus on the scope in the sense of the factors (or factor domains) that are considered in the models – for instance (hu)man, technology, and organization (MTO). Thirdly, we focus on the system of investigation or the activities that together constitute an accident investigation project/process. We found that the manuals all used complex linear models. The factors considered were in general (hu)man, technology, organization, and information. The causes found during an investigation reflect the assumptions of the accident model, following the ‘What-You-Look-For-Is-What-You-Find’ or WYLFIWYF principle. The identified causes typically became specific problems to be fixed during an implementation of solutions. This follows what can be called ‘What-You-Find-Is-What-You-Fix’ or WYFIWYF principle.     

Organohalogen contamination in breeding glaucous gulls from the Norwegian Arctic: associations with basal metabolism and circulating thyroid hormones

Exposure to organohalogens in endotherms has been suggested to impose chemically induced stress by affecting functions related to maintenance energy requirements. Effects on basal metabolic rate (BMR) have been suggested to be, in part, mediated through interactions with the thyroid hormones (THs). We investigated the relationships between plasma concentrations of major organochlorines, PBDEs, hydroxylated (OH)- and methoxylated (MeO)-PBDEs and OH-PCBs, circulating TH levels and BMR in breeding glaucous gulls (Larus hyperboreus) from the Norwegian Arctic. Negative associations were found between BMR and concentrations of sigma PCB, Sigma DDT and particularly Sigma chlordane, which combined made up 91% of the total contaminant burden. Levels of THs (thyroxine and triiodothyronine) were not associated significantly with variation of BMR or concentrations of any of the compounds determined. The present study suggests that BMR may be altered in glaucous gulls exposed to high loadings of persistent contaminants in the Norwegian Arctic environment.     

Zoobenthos as indicators of ecological status in coastal brackish waters: a comparative study from the Baltic Sea

A new method for classifying soft-bottom zoobenthic assemblages along the Finnish coasts (northern Baltic Sea) is presented and tested against traditional physicochemical monitoring data in the complex Archipelago Sea. Although multivariate methods for assessing the state of the marine environment have become widely used, few numerical indices can operate over a wide salinity range. We compare indices currently in use and propose a new index, BBI (brackish water benthic index), for the low-saline and species-poor Baltic coastal waters. BBI offers a salinity-corrected tool for classification of the soft-bottom zoobenthos under the demands of the European Union Water Framework Directive.     

Recovery of benthic invertebrate communities from acidification in Killarney Park lakes

Using a reference-condition comparison, recovery of benthic invertebrate communities from acidification was assessed in three lakes in Killarney Wilderness Park approximately 40–60 km from the massive metal smelters in Sudbury, Canada. Test site analyses (TSAs) were used to compare the park lakes to 20 reference lakes near Dorset Ontario, 200 km to the east. An extension of a previous survey (1997–2001) of two sensitive mayfly species (Stenonema femoratum and Stenacron interpunctatum) was conducted in one of the lakes. TSA results indicate that the three Killarney lakes remain significantly different from reference condition due primarily to higher abundances of a few acid-tolerant families and the presence of some less abundant sensitive families. Colonization rates differ greatly between the two mayfly species presumably because of competition for available habitat. Overall, this study suggests that early colonizers will gain an advantage to out-compete subsequent arrivals, and these competitive interactions will delay the return of communities to reference condition.     

Meat,Dairy and Climate Change: Assessing the Long-Term Mitigation Potential of Alternative Agri-Food Consumption Patterns in Canada

We use a newly developed model of the entire Canadian energy system (TIMES-Canada) to assess the climate change mitigation potential of different agri-food consumption patterns in Canada. For this, our model has been extended by disaggregating the agricultural demand sector into individual agri-food demands to allow for a more in-depth analysis. Besides a business-as-usual (baseline) scenario, we have constructed four different agri-food scenarios to assess the viability of reducing Canadian meat and dairy consumption in order to diminish Canada’s agricultural sector energy consumption and greenhouse gas (GHG) emissions. Our policy scenarios progressively restrict the consumption of different meat and dairy agricultural products until the year 2030. Our results suggest that the implementation of a meat and dairy consumption reduction policy would lead to a 10 to 40 % reduction in agricultural GHG emissions, depending on the severity of the scenario. This translates to a 1 to 3 % decrease in total Canadian GHG emissions by the year 2030. Besides these environmental benefits, health benefits associated with a reduction in meat and dairy consumption (as inferred from other studies) are presented as an additional source of motivation for implementing such a policy in Canada.