Investigation of NAPL transport through a model sand cap during ebullition

Nonaqueous‐phase liquid (NAPL) migration from sediments to the surface of water bodies has been reported frequently at sites with sediments contaminated with NAPLs, such as coal tar and creosote. Commonly, transport of NAPL from sediment is facilitated by gas ebullition caused by anaerobic biodegradation of organic matter in the sediment. A remedy often specified for these sites is a sand cap, and sand caps amended with sorbent materials (such as organoclays) are being pilot‐tested. This article discusses a laboratory study to assess the effectiveness of a sand layer for controlling NAPL migration. The study used a test column composed of a Plexiglas tube containing a tar source that was buried beneath a 30‐cm‐thick layer of fine sand. Water was added to the column until 5 cm of standing water covered the sand layer. To simulate ebullition, air was injected into the base of the sand column at approximately 200 mL/min. It was observed that the gas and NAPL migrated primarily through channels and fractures in the sand, and was not filtered through a network of stable pores. Tar migrated through the sand layer in 12 hours and accumulated on the water surface for several hours before losing its buoyancy and settling back down to the sand surface. After ending the tar migration experiment, the test column was frozen to preserve structures in the sand. The study showed that the tar migrated through the simulated sand cap in small (2‐mm) channels only a few sand grains thick. The results of this laboratory work call into question the effectiveness of sand caps for controlling NAPL migration from sediment in the presence of ebullition. © 2009 Wiley Periodicals, Inc.     

Community Forestry as Perceived by Local People Around Cross River National Park, Nigeria

The prior identification of local people’s preferences for conservation-development projects will help gear nature-conservation strategies toward the needs of different groups of local people. This will help policy-makers in designing a more acceptable and effective conservation strategy. This article reports a study of local perceptions of a community forestry project that aims to help improve the design as well as local acceptance of the project. The data originated from personal interviews conducted in communities around Okwangwo Division of the Cross River National Park in southeast Nigeria and were analysed using ordered logit and binary logit models. The results showed that >50% of the respondents were satisfied with the community forestry project. The respondents’ perceptions were mainly influenced by education, age, gender, and willingness to contribute money to tourism as well as the contributions of cocoa, banana, and afang (Gnetum africanum) to the respondents’ income. The results from this study have important implications for nature conservation in Nigeria and potentially other conservation contexts across the developing world.     

Environmental response to intentional dissemination of Bacillus anthracis spores in the United States–2001

The intentional dissemination of Bacillus anthracis (anthrax) spores at multiple locations in the United States in the fall of 2001 resulted not only in several deaths and illnesses (including psychological effects), but likely changed lifestyles and attitudes, and increased the public's awareness of individual vulnerability. While federal resources had previously been committed to preparing local public health agencies for counter‐terrorism activities and to enhance environmental and medical response, these release episodes have increased the consistency of environmental and medical response activities, and increased government resources for homeland security. This article abstracts current information from many sources that summarize the environmental responses to the anthrax releases. The article discusses the international agreements and the U.S. regulations concerning biological weapons, the characteristics of the anthrax organism, potential exposure pathways, adverse health conditions resulting from inhalation exposure, the environmental response to two specific release episodes, environmental sampling and analytical procedures, recommended personal protective equipment, and the subsequent federal efforts to improve response capabilities. © 2003 Wiley Periodicals, Inc.     

Estimation of Organic Carbon Blank Values and Error Structures of the Speciation Trends Network Data for Source Apportionment

Abstract

Because the particulate organic carbon (OC) concentrations reported in U.S. Environment Protection Agency Speciation Trends Network (STN) data were not blank corrected, the OC blank concentrations were estimated using the intercept in particulate matter ≤2.5 µm in aerodynamic diameter (PM_2.5) regression against OC concentrations. The estimated OC blank concentrations ranged from 1 to 2.4 μg/m³ showing higher values in urban areas for the 13 monitoring sites in the northeastern United States. In the STN data, several different samplers and analyzers are used, and various instruments show different method detection limit (MDL) values, as well as errors. A comprehensive set of error structures that would be used for numerous source apportionment studies of STN data was estimated by comparing a limited set of measured concentrations and their associated uncertainties. To examine the estimated error structures and investigate the appropriate MDL values, PM_2.5 samples collected at a STN site in Burlington, VT, were analyzed through the application of the positive matrix factorization. A total of 323 samples that were collected between December 2000 and December 2003 and 49 species based on several variable selection criteria were used, and eight sources were successfully identi?ed in this study with the estimated error structures and min values among different MDL values from the ?ve instruments: secondary sulfate aerosol (41%), secondary nitrate aerosol (20%), airborne soil (15%), gasoline vehicle emissions (7%), diesel emissions (7%), aged sea salt (4%), copper smelting (3%), and ferrous smelting (2%). Time series plots of contributions from airborne soil indicate that the highly elevated impacts from this source were likely caused primarily by dust storms.     

Workplace monitoring for volatile organic compounds using thermal desorption-gas chromatography-mass spectrometry

The interest in the identification of volatile organic compounds in the workplace has been a major focus of many National Institute for Occupational Safety and Health (NIOSH) field studies. A primary technique for sampling and analysis of these compounds is summarized by NIOSH Manual of Analytical Methods (NMAM) 2549. This is a screening method that uses a multi-bed sorbent to trap a wide variety of compounds and compound classes. Thermal desorption techniques are used as a first attempt to characterize potential contaminants in a workplace and to determine what future sampling and analyses must be performed. Field examples are provided to show the versatility of thermal desorption methods and techniques. Due to their sensitivity, thermal desorption tube methods are sometimes required in order to measure the workplace concentrations of unusual compounds. In other situations, the exposures are too high or varied to make thermal desorption tubes practical. In these cases, the identification of contaminants with thermal desorption tubes leads to new method developments for the quantification of specific compounds using more conventional solid sorbent-solvent desorption based methods.     

Preferences and willingness to pay for close to home nature for outdoor recreation in Sweden

In Sweden there is a strong tradition of using nature areas for outdoor recreation. This paper reports on a study which explored preferences and willingness to pay for outdoor recreation close to home (≤100 km away from home and ≤24 hours stay at a recreation site) using the contingent valuation method. The data originated from a mail survey that involved Swedish residents who were randomly selected from a national register. An ordinary least squares regression model was used to account for factors influencing willingness to pay. The results showed that approximately 50% of the respondents used nature areas close to their home for recreation and their average frequency of visits to these areas was 74 times annually. Areas dominated by forests were the most preferred, followed by water. The respondents were willing to pay approximately 7200 SEK (US$1080) annually. Their willingness to pay was influenced by factors such as type of nature area, distance to and time spent at the recreation site and income. The results provide one input to the land use planning process by considering the demand for nature-based outdoor recreation close to home.     

Combining land-use planning and tenure security: a tenure responsive land-use planning approach for developing countries

There is tenure insecurity around land ownerships and land rights in most developing countries. There are also many land-use planning projects being implemented in these countries. Often, land-use planning exists in these countries but is not formally linked with tenure security. This study argues that combining them by conducting land-use planning in a way that promotes tenure security presents a new approach. A central premise for the rationale of this intervention is that processes of land-use planning may inadvertently increase tenure security. By way of methodology, it evaluates land-use planning case studies from Africa, Asia and South America. It uses the three case study examples to build a case for making tenure security one of the major planned outcomes of a land-use planning process and provides a detailed framework for operationalising the concept. Its main contribution to the literature is that it introduces the concept of tenure responsive land-use planning.     

Nonlinear and competitive sorption of apolar compounds in black carbon-free natural organic materials

Numerous studies have reported a spectrum of sorption phenomena in soils, sediments, and organic matter isolates of those materials that are inconsistent with a partition model proposed in the late 1970s and early 1980s, a model predicated on a hypothesis that sorption is linear and noncompetitive. To explain these nonideal phenomena, prior studies have proposed a hard-soft (glassy-rubbery) model for SOM (soil and sediment organic matter), while others have attributed them singularly to BC (black carbon: soot and charcoal) particles present in topsoils and sediments. In this study, we demonstrated nonideal sorption behavior (isotherm nonlinearity, competitive effects) for a group of apolar compounds in a large set of natural and model organic materials, including a commercial lignin and humic acids from different sources. Complete oxidation of samples by an acidic dichromate method was taken to signify the absence of BC. (However, polymethylene units are stable even if functionalized on both ends, making the technique unreliable for quantifying BC.) Other samples were inferred free of BC by their source and method of preparation. Characterization by thermalanalytical methods indicated the glassy character of the organic materials. The origin of the nonideal behaviors appears to be the glassy character of these materials. Sorption nonlinearity increased or decreased by changing temperature, cosolvent content, or degree of cross-linking by metal ions as predicted for organic solids in a glassy state. We conclude that macromolecular humic substances in the environment may exhibit nonideal sorption behavior in soils and sediments, quite apart from any such behaviors attributable to BC.