Renewable Resources and Enzymatic Processes to Create Functional Polymers: Adapting Materials and Reactions from Food Processing

We are exploiting materials and concepts from food science to create functionalized, environmentally friendly derivatives of the biopolymer chitosan, a byproduct of seafood processing. Functional groups are grafted onto chitosan using tyrosinase, the enzyme responsible for food browning. The functionalizing groups studied include low-molecular-weight phenols derived from natural sources and high-molecular-weight proteins. The approach of using low-molecular-weight phenols to functionalize chitosan is illustrated with arbutin, a natural phenol found in pears. Results demonstrate that tyrosinase initiates reactions that lead to the conversion of arbutin–chitosan solutions into gels. These gels can be rapidly broken by treatment with the chitosan-hydrolyzing enzyme chitosanase, demonstrating that the chitosan derivatives remain biodegradable. We briefly review other studies in which low-molecular-weight natural phenols are enzymatically grafted onto chitosan to confer functional properties. The creation of co-polymers is illustrated by results in which tyrosinase is used to couple gelatin onto chitosan. Gelatin is a proteinaceous byproduct of meat production. The tyrosinase-generated gelatin–chitosan conjugates have been observed to offer interesting rheological and thermal properties. These results demonstrate the potential for using renewable resources and enzymatic processing to create environmentally friendly polymers with useful functional properties.     

Development of Stream Water Chemistry during Spring Melt in a Northern Hardwood Forest

The role of snowmelt and subsurface hydrology in determiningthe chemistry of a small headwater stream in the TurkeyLakes Watershed (TLW) was evaluated for the spring meltperiods 1992 to 1996. Spring runoff is the dominanthydrological event at the TLW each year. Processesoccurring within the snowpack during snowmelt wereprincipally responsible for the above-ground changes inchemical fluxes relative to bulk deposition (the effect ofwinter throughfall was minimal). Large changes in chemicalfluxes occurred below ground. Organic matter decomposition,weathering, nitrification, and element cycling are some ofthe more important below-ground processes that operateduring the snow accumulation and ablation season and controlthe composition of the water ultimately appearing in thestream. Maximum stream discharge was accompanied byelevated concentrations of H⁺, NO₃ ^-, K⁺,NH₄ ⁺, DOC, Al and Mn, but reduced levels ofCa²⁺, Mg²⁺, SO₄ ^2- and SiO₂. Theconcentration-discharge relationships were consistent withwater movement through and above the forest floor duringpeak discharge, a flowpath facilitated by rapid infiltrationof meltwater and the existence of a relatively impermeablelayer in the mineral soil creating a perched water table. Averaged over the five periods of snow accumulation andablation, it was estimated that pre-melt stream flow, andwater routed through the forest floor and through the uppermineral soil contributed 9, 28 and 63%, respectively, ofthe discharge measured at the outlet of the catchment. Theforest floor contribution would be greater at peak dischargeand at higher elevations. An end-member mixing modelestimated concentrations of SO₄ ^2-, NO₃ ^-,Cl^-, Ca²⁺, Mg²⁺, Na⁺ and Al that werecomparable to average values measured in the stream. Othervariables (NH₄ ⁺, H⁺, K⁺ and DOC) wereover-estimated implying retention mechanisms operatingoutside the model assumptions.     

CONSTRUCTING A PROBLEM SOLVING ENVIRONMENT TOOL FOR HYDROLOGIC ASSESSMENT OF LAND USE CHANGE1

ABSTRACT: This paper describes the integration of a comprehensive hydrological model known as the Hydrological Simulation Program Fortran (HSPF) into a problem solving environment (PSE) for watershed management. The original PSE concept was a structure providing web‐based access to a suite of models, including HSPF and other models of in‐stream hydrodynamics, biological impacts and economic effects, for the watershed‐wide assessment of alternative land use scenarios. The present paper describes only the HSPF integration into the PSE program. Example applications to the 148 square kilometer (57 square mile) Back Creek subwatershed in the upper Roanoke River system (1,479 square kilometers or 571 square miles) in southwest Virginia are used to illustrate important concepts and linkages between land development and hydrological change using hypothetical' what if'scenarios. The features of HSPF and its limitations in this context are discussed. The paper as such is a proof‐of‐concept paper and not a completion report. It is intended to describe the PSE tool building process rather than analysis of the many possible simulation outcomes. However, the dominance of raw imperviousness as a contributor to hydrograph response is apparent in all the PSE simulations described in this paper.     

MULTISCALE RIVER ENVIRONMENT CLASSIFICATION FOR WATER RESOURCES MANAGEMENT1

ABSTRACT: River Environment Classification (REC) is a new system for classifying river environments that is based on climate, topography, geology, and land cover factors that control spatial patterns in river ecosystems. REC builds on existing principles for environmental regionalization and introduces three specific additions to the “ecoregion” approach. First, the REC assumes that ecological patterns are dependent on a range of factors and associated landscape scale processes, some of which may show significant variation within an ecoregion. REC arranges the controlling factors in a hierarchy with each level defining the cause of ecological variation at a given characteristic scale. Second, REC assumes that ecological characteristics of rivers are responses to fluvial (i.e., hydrological and hydraulic) processes. Thus, REC uses a network of channels and associated watersheds to classify specific sections of river. When mapped, REC has the form of a linear mosaic in which classes change in the downstream direction as the integrated characteristics of the watershed change, producing longitudinal spatial patterns that are typical of river ecosystems. Third, REC assigns individual river sections to a class independently and objectively according to criteria that result in a geographically independent framework in which classes may show wide geographic dispersion rather than the geographically dependent schemes that result from the ecoregion approach. REC has been developed to provide a multiscale spatial framework for river management and has been used to map the rivers of New Zealand at a 1:50,000 mapping scale.     

Public opinion and siting solid waste landfills in Kuwait

Siting municipal solid waste landfills in Kuwait had not considered public concerns about the location of such facilities. Kuwait Municipality has disposed urban waste in abandoned sand quarries for the past 20 years in an unplanned fashion. Due to this improper siting criteria, environmental and health problems have risen from old landfills that are located in residential areas. In an effort to help responsible decision-makers in assessing public support for siting landfills a structured, yet simple, questionnaire was designed and distributed to a random sample of heads of households. Statistical techniques were employed to examine trends and relationships between the sample public responses concerning landfill siting criteria. The findings of the research indicated that a significant percentage of the responding sample did not know about the various landfill impacts and less than 50% were aware of the negative impacts of landfills on the public health and the environment. The visual appearance of the landfill scored the lowest impact in the opinion of the sample public while the most important aspect in siting a landfill appeared to be its economic consideration. The research findings also directed attention to the important role that the media could play in increasing public awareness. Results from the cross-classification analysis demonstrated the existence of differences in awareness levels according to age, nationality, martial status, education, and occupation of the responding sample. Statistically, these differences were significant at the 95% significance level, as supported by the test of the χ-square.     

Appropriate water supply and sanitation technology for developing countries in tropical monsoon climates

Summary In the past, the water supply and sewage services for the urban regions of developing countries have been provided, in the main, only for the more affluent areas of these cities. This paper, dealing especially with those countries with tropical monsoon climates, advocates the construction of more comprehensive systems.Experience drawn from a wide range of projects and a review of the relevant literature provokes the authors to emphasise the need for suitable manuals of appropriate technology for use in these developing countries. These manuals should provide a full set of environmental guidelines for the design of water supply and sewage/sanitation systems for use in these countries.Dr Harvey F. Ludwig is Chairman and Greg Browder is Environmental Engineer for SEATEC International Consulting Engineers, Bangkok, Thailand.     

Book reviews

Environment Systems and Decisions -     

A GEOGRAPHICAL ANALYSIS OF WATER-RELATED CONSTITUTIONAL AMENDMENTS IN TEXAS, 1985–19911

ABSTRACT: Texans participate directly in water policy decision-making through a referendum process involving amendment of the state's constitution. Prior to 1985, Texans voted on eight amendments. Five of these were ratified (1957, 1962, 1966, 1971, 1976), and collectively resulted in the creation of the Water Development Fund, with an authorization level of $600 million, and the Texas Water Development Board, the organization charged with administering the fund. Three other amendments were defeated in 1969, 1976, and 1981 by ever-increasing margins. From 1985 to 1991, six additional amendments were proposed and subsequently ratified, resulting in a $1.8 billion increase in Water Development Fund authorization and the creation of an agricultural water conservation fund and bond insurance program. County-level electoral data for the 1985–1991 referenda were mapped to assess sectional and regional factors underlying public opinion regarding these water resource development and funding programs. Regional contrasts were most pronounced for the 1989 and 1991 referenda that targeted economically distressed areas across the state, particularly the colonias located along the Rio Grande, and the 1989 amendment that removed a time limit on the issuance of agricultural water conservation bonds. As a specific case study, the Texas experience could serve as a guide in California where similar constitutional restrictions require tax and spending programs to be approved by voters, and in other states that may be considering the development of similar state-level financial programs for water projects.