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81.
Muhammad Nadeem Asghar Aneela Anwar Hafiz Muhammad Abdur Rahman Sammia Shahid Iram Nadeem 《毒物与环境化学》2013,95(8-10):659-676
AbstractThe objective of the present study is to synthesize various metal ions mixed TiO2 nanoparticles using a continuous hydrothermal synthesis pilot reactor for dye-sensitized solar cells (DSCs). In the pilot plant, aqueous solutions of the metal salts are mixed with a flow of supercritical water (450?°C and 24.1?MPa) in a confined jet mixer for continuous synthesis of metal ions-mixed nano-titania. Characterization of the particles was made using Brunauer–Emmett–Teller technique for specific surface area, powder X-ray diffraction analysis and transmission electron microscopy for identification and crystallite size, X-ray photoelectron spectroscopy for surface analysis and infrared spectroscopy for distinct group identification. Following the already existing procedures and using the titanates synthesized, dye-sensitized cells of 1?cm2 area were assembled and their photovoltaic parameters were evaluated under standard test conditions. The power conversion efficiencies (η %) for 40?mol % Zn2+, 5?mol % Zr4+ and 10?mol % Zn4+ titania were obtained to be 4.8, 4.95 and 4.9, respectively. The promising efficiency results from a greener and large-scale production of nano-titania is a step forward towards commercializing DSC technology. 相似文献
82.
Shuhei Tomita Shin-Ichi Maekawa Mustafizur Rahman Fumi Saito Ryoichi Kizu Keiko Tohi 《毒物与环境化学》2013,95(1):113-124
Epidemiological studies suggest that diesel exhaust particles (DEP) contribute to an increase in allergic diseases. To assess the effects of DEP on the central immune system, mice were exposed to DEP by intraperitoneal (IP) administration. Exposure to DEP resulted in severe thymic involution accompanied by a reduction in the number of thymocytes, especially in cortical CD4+CD8+ double positive and double negative subsets. Core carbon particles associated with a mixture of chemical compounds in DEP did not appear to be responsible for the DEP-induced thymic involution because carbon graphite does not affect neither the number nor the CD4/CD8 profile of thymocytes. Extraction of DEP by ether, acidic and basic solvents showed that several independent fractions including the neutral ether fraction, which contains polycyclic aromatic hydrocarbons (PAH), induced thymic involution. Among major PAH components of DEP, benzo[b]fluoranthene (BbF), benzo[a]pyrene (BaP), and benzo[k]fluoranthene (BkF) were very potent inducers of thymic involution at an ED50 of less than 100?ng per mouse body. Nonetheless, DEP treatment of mice with targeted disruption of genes encoding the aryl hydrocarbon receptor (AHR), AHR nuclear translocator (ARNT), or microsomal epoxide hydolase (mEH) indicated that DEP produced thymic involution even in the absence of PAH-induced AHR/ARNT signal transduction or mEH-mediated PAH catabolism. On the other hand, BaP-mediated thymic involution was completely dependent on AHR, partially dependent on ARNT in T cells, and independent of mEH. These results indicate that DEP-induced thymic involution is mediated both by PAH-AHR/ARNT-dependent and -independent mechanisms. 相似文献
83.
Mohammad Mahmudur Rahman Gary Owens Ravi Naidu 《Environmental geochemistry and health》2009,31(Z1):179-187
Chronic exposure to arsenic (As) causes significant human health effects, including various cancers and skin disorders. Naturally
elevated concentrations of As have been detected in the groundwater of Bangladesh. Dietary intake and drinking water are the
major routes of As exposure for humans. The objectives of this study were to measure As concentrations in rice grain collected
from households in As-affected villages of Bangladesh where groundwater is used for agricultural irrigation and to estimate
the daily intake of As consumed by the villagers from rice. The median and mean total As contents in 214 rice grain samples
were 131 and 143 μg/kg, respectively, with a range of 2–557 μg/kg (dry weight, dw). Arsenic concentrations in control rice
samples imported from Pakistan and India and on sale in Australian supermarkets were significantly lower (p < 0.001) than in rice from contaminated areas. Daily dietary intake of As from rice was 56.4 μg for adults (males and females)
while the total daily intake of As from rice and from drinking water was 888.4 and 706.4 μg for adult males and adult females,
respectively. From our study, it appears that the villagers are consuming a significant amount of As from rice and drinking
water. The results suggest that the communities in the villages studied are potentially at risk of suffering from arsenic-related
diseases. 相似文献
84.
85.
Ahmad Manzoor Khattak Shoukat Iqbal Khan Anwar Rahman Zia Ur 《Environmental and Ecological Statistics》2020,27(2):203-232
Environmental and Ecological Statistics - The paper proposes a new perspective in the environmental and resource economics literature by examining innovation (measured by R&D expenditures),... 相似文献
86.
87.
Abdel‐Rahman G. Abdel‐Rahman R. Don Wauchope Clint C. Truman Clyde C. Dowler 《Journal of environmental science and health. Part. B》2013,48(3):381-396
Abstract Rainfall simulation was used with small packed boxes of soil to compare runoff of herbicides applied by conventional spray and injection into sprinkler‐irrigation (chemigation), under severe rainfall conditions. It was hypothesized that the larger water volumes used in chemigation would leach some of the chemicals out of the soil surface rainfall interaction zone, and thus reduce the amounts of herbicides available for runoff. A 47‐mm rain falling in a 2‐hour event 24 hours after application of alachlor (2‐chloro‐N‐(2,6‐diethylphenyl)‐N‐(methoxymethyl)‐acetamide) and atrazine (6‐chloro‐N‐ethyl‐N‐(1‐methylethyl)‐1,3,5‐triazine‐2,4‐diamine) was simulated. The design of the boxes allowed a measurement of pesticide concentrations in splash water throughout the rainfall event. Initial atrazine concentrations exceeding its’ solubility were observed. When the herbicides were applied in 64000 L/ha of water (simulating chemigation in 6.4 mm irrigation water) to the surface of a Tifton loamy sand, subsequent herbicide losses in runoff water were decreased by 90% for atrazine and 91% for alachlor, as compared to losses from applications in typical carrier water volumes of 187 L/ha. However, this difference was not due to an herbicide leaching effect but to a 96% decrease in the amount of runoff from the chemigated plots. Only 0.3 mm of runoff occurred from the chemigated boxes while 7.4 mm runoff occurred from the conventionally‐treated boxes, even though antecedent moisture was higher in the former. Two possible explanations for this unexpected result are (a) increased aggregate stability in the more moist condition, leading to less surface sealing during subsequent rainfall, or (b) a hydrophobic effect in the drier boxes. In the majority of these pans herbicide loss was much less in runoff than in leachate water. Thus, in this soil, application of these herbicides by chemigation would decrease their potential for pollution only in situations where runoff is a greater potential threat than leaching. 相似文献
88.
M. M. Rahman Saad Mekhilef R. Saidur A. G. M. Mustayen Billah S. M. A. Rahman 《International Journal of Green Energy》2016,13(4):344-351
This article presents two mathematical models for drying mushrooms considering the shrinkage effect. Both the models consider the physical changes of mushrooms during drying using the diffusion equation. A convective term is presented in the first model while, in the second model, the effective diffusion co-efficient is employed. Although the diffusion co-efficient is mainly dependent on the water content of the mushrooms, both models are suitable for analyzing the drying process. Moreover, in this study it has been demonstrated that both models are equivalent. The Genetic Algorithmic process was used to estimate the parameter values in different conditions. The information regarding the moisture content and the thickness evaluation taken from the models shows the best fit with the experimental data. The mathematical models developed to simulate the drying curve of mushroom have been evaluated and compared. 相似文献
89.
Kamrun Nahar Motiar Rahman Mirza Hasanuzzaman Md. Mahabub Alam Anisur Rahman Toshisada Suzuki Masayuki Fujita 《Environmental science and pollution research international》2016,23(21):21206-21218
The role of exogenous spermine (0.25 mM Spm, a type of polyamine (PA) in reducing Cd uptake and alleviating Cd toxicity (containing 1 and 1.5 mM CdCl2 in the growing media) effects was studied in the mung bean (Vigna radiata L. cv. BARI Mung-2) plant. Exogenously applied Spm reduced Cd content, accumulation, and translocation in different plant parts. Increasing phytochelatin content, exogenous Spm reduced Cd accumulation and translocation. Spm application reduced the Cd-induced oxidative damage which was reflected from the reduction of H2O2 content, O2 ?– generation rate, lipoxygenase (LOX) activity, and lipid peroxidation level and also reflected from the reduction of spots of H2O2 and O2 ?– from mung bean leaves (compared to control treatment). Spm pretreatment increased non-enzymatic antioxidant contents (ascorbate, AsA, and glutathione, GSH) and activities of antioxidant enzymes such as superoxide dismutase (SOD), catalase (CAT), glutathione S-transferase (GST), monodehydroascorbate reductase (MDHAR), dehydroascorbate reductase (DHAR), and glutathione reductase (GR) which reduced oxidative stress. The cytotoxicity of methylglyoxal (MG) is also reduced by exogenous Spm because it enhanced glyoxalase system enzymes and components. Through osmoregulation, Spm maintained a better water status of Cd-affected mung bean seedlings. Spm prevented the chl damage and increased its content. Exogenous Spm also modulated the endogenous free PAs level which might have the roles in improving physiological processes including antioxidant capacity, osmoregulation, and Cd and MG detoxification capacity. The overall Spm-induced tolerance of mung bean seedlings to Cd toxicity was reflected through improved growth of mung bean seedlings. 相似文献
90.
Roshanida A. Rahman Abul Hossain Molla A. Fakhru’l-Razi 《Environmental science and pollution research international》2014,21(2):1178-1187
Sustainable, environmental friendly, and safe disposal of sewage treatment plant (STP) sludge is a global expectation. Bioremediation performance was examined at different hydraulic retention times (HRT) in 3–10 days and organic loading rates (OLR) at 0.66–7.81 g chemical oxygen demand (COD) per liter per day, with mixed filamentous fungal (Aspergillus niger and Penicillium corylophilum) inoculation by liquid-state bioconversion (LSB) technique as a continuous process in large-scale bioreactor. Encouraging results were monitored in treated sludge by LSB continuous process. The highest removal of total suspended solid (TSS), turbidity, and COD were achieved at 98, 99, and 93 %, respectively, at 10 days HRT compared to control. The minimum volatile suspended solid/suspended solid implies the quality of water, which was recorded 0.59 at 10 days and 0.72 at 3 days of HRT. In treated supernatant with 88 % protein removal at 10 days of HRT indicates a higher magnitude of purification of treated sludge. The specific resistance to filtration (SRF) quantifies the performance of dewaterability; it was recorded minimum 0.049 × 1012 m kg?1 at 10 days of HRT, which was equivalent to 97 % decrease of SRF. The lower OLR and higher HRT directly influenced the bioremediation and dewaterability of STP sludge in LSB process. The obtained findings imply encouraging message in continuing treatment of STP sludge, i.e., bioremediation of wastewater for environmental friendly disposal in near future. 相似文献