ATRAZINE IN SPRING RUNOFF AS RELATED TO ENVIRONMENTAL SETTING EBRASKA, 19921

ABSTRACT: A synoptic sampling of five surface-water sites in central Nebraska was conducted by the U.S. Geological Survey as part of its National Water-Quality Assessment Program during storm runoff in May 1992 to relate transport, yields, and concentrations of atrazine to environmental setting. Atrazine was the most extensively applied pesticide in the study unit. Atrazine transport was related to the size of contributing drainage area, quantity of atrazine applied, amount of precipitation, and volume of stream-flow. Estimated yields and mean concentrations of atrazine were related to the percentage of cropland in a drainage area. The largest estimated yields and mean concentrations of atrazine in surface water were associated from drainage areas with the highest percentage of cropland, and the smallest was associated with the smallest amount of cropland. Atrazine concentrations increased as streamflow increased but decreased at or near the time of peak streamflows, perhaps due to dilution. Atrazine concentrations then increased and remained elevated far into the stream recession. Atrazine is a regulated contaminant in finished public-water supplies. Large concentrations of atrazine could affect the management of public-water supplies because atrazine remains in solution in contrast to many other pesticides that are more easily removed.     

A longitudinal assessment of the determinant relationship between employee commitments to the occupation and the organization

A review of the research literature suggested that occupational commitment may be an antecedent to employees' commitment to the organization. Although several studies have assessed the general relationship between occupational and organizational commitment, none have attempted to establish the causal priority between the two constructs. In the present study, occupational commitment was viewed as a causal antecedent to organizational commitment. Based on longitudinal data from 100 management information systems professionals, this view was supported through cross-lagged analysis. Further, we examined a longitudinal causal model of the turnover process in which occupational commitment was placed as an antecedent to organizational commitment. Structural equation analysis supported the fit of this model to the data. Implications of the findings are discussed.     

Screening method for locating groundwater monitoring wells

The traditional approach to characterizing the extent of groundwater contamination is often phased over a period of several years. A screening method has been developed that allows the investigation process to be reduced to a single phase. Existing data are used to develop a preliminary estimate of the extent of contamination, which is refined by the screening method using groundwater data collected and analyzed in the field. The screening method is applicable at sites with volatile organic compound contamination. Groundwater samples are collected using direct push or drill rig assisted methods, and the groundwater headspace gas is analyzed for the contaminant of interest. The refined estimate is used to locate all of the groundwater monitoring wells necessary to finalize the estimate of the extent of contamination. Therefore, only one investigation phase is required, and time and cost savings are realized with respect to the traditional multiphase approach. The screening method was successfully applied at a CERCLA site in Nebraska with two distinct plumes of TCE-contaminated groundwater. The Nebraska remedial investigation was completed approximately 18 months earlier than the estimated completion of a comparable phased investigation, with a corresponding cost reduction estimated at approximately 10 percent. If data from the screening method were used instead of data from monitoring wells, the estimated cost savings would be over 50 percent. Additional applications and evaluations may lead to industry and regulatory acceptance of the method as a primary characterization tool.     

Fog collection's role in water planning for developing countries

In certain locations, the combination of meteorological conditions and topography are such that persistent fogs cover coastal or interior mountains. The droplets from these fogs are collected by trees or other tall vegetation. They can also be collected by appropriately designed man-made collectors, to provide large volumes of water for domestic, agriculture or forestry uses. The largest project to date has provided, since March 1992, an average of 11 000 litres of water per day (*****l/d) to a village of 330 people in the arid coastal desert of northern Chile. This project and others are reviewed. The impact of the deforestation of high elevation areas, and the subsequent loss of fog water input in a watershed are discussed, as are guidelines for water planners.     

General mathematical models for LCI recycling

Life cycle inventory (LCI) is becoming more widely used as a tool to evaluate the resource and energy use and the environmental releases associated with various products. The methodology for handling different recycling scenarios is also becoming increasingly important. Several different methods exist for handling recycling in an LCI. The method described in this paper uses mathematical models to show that the same basic equations can be used to handle a variety of recycling options for multi-product systems.     

Treatment of risk in environmental impact assessment

Risk assessment and environmental impact assessment have developed as separate traditions. While environmental impact assessment is a broad field that includes all activities that attempt to analyze and evaluate the effects of human and related actions on the environment, risk assessment has been concerned with the relatively well-defined regulatory problems and employs formal quantitative analysis of the probability of specific undesired events, such as cancer. Risk analytic approaches, particularly the explicit treatment of uncertainty, can significantly contribute to environmental assessments. This article discusses the type and sources of uncertainty in environmental assessments, techniques for their quantification, and ways to use uncertainty estimates to calculate probabilities of effects or probabilities of exceeding environmental standards and to determine the need for mitigation or additional research.This article was presented at the International Institute of Applied Systems Analysis, Task Force Meeting on Risk and Policy Analysis under Conditions of Uncertainty, Laxenburg, Austria, November 1985.     

External threats to ecosystems of US national parks

Activities beyond national park boundaries are now the principal source of threats to park natural resource integrity. Assessing the full impact of major threats as air and water pollution requires a long-term ecosystem-level approach in research design and execution, and park management. Failure to take such an approach renders most existing park data bases useless in the documentation of external threats. While the concept of managing national parks as ecosystems is not new, Park Service research and its organization have not provided the information necessary for such a basis of management. Quantifying the impacts on park resources due to external hydrologic regulation and air pollution is a good example of the need to employ an ecosystem approach in research. However, implementing such a program will require a fundamental change in research administration, priority setting, and conceptual approach.The first four of the articles in this special section arise from an AAAS symposium onExternal Threats to Ecosystems of the National Parks in the USA, which was convened in 1982. The articles have been revised to reflect subsequent developments in this field. The first article, by Dr. Stottlemyer, the symposium organizer, serves as an introduction to the topic. The fifth article in this special section was submitted separately, but included because it also is related to this particular topic.     

Legal considerations in challenging external threats to Glacier National Park,Montana, USA

External threats to the environmental integrity of Glacier National Park, Montana, USA, fit into three categories: adverse land use practices adjacent to the Park, air pollution, and water pollution. This article identifies and evaluates the laws that Glacier National Park officials might rely upon to protect the Park against these external threats. The article also assesses the available scientific information relating to external threats, and it identifies additional information needed to establish a legal basis for challenging the threats.     

IN SITU MEASUREMENT OF ADSORPTION AND BIOTRANSFORMATION AT A HAZARDOUS WASTE SITE1

ABSTRACT: A three well injection-production test was performed at the United Creosoting Company (UCC) site in Conroe, Texas, to estimate the effective in situ retardation factors for adsorption and to evaluate the significance of biotransformation in limiting the transport of polycydic aromatics present in the shallow aquifer. The field test was also used as a model to determine if this type of testing would be feasible at other hazardous waste sites. During the test, chloride, a non-reactive tracer and two organic compounds, naphthalene and paradichlorobenzene (pDCB), were injected into a center well for 24 hours followed by clean ground water for six days. Ground water was continuously produced from two adjoining wells and monitored to observe the breakthrough of these compounds. Data from the test were analyzed by comparing the statistical moments of the chloride and organics distributions. Retardation factors for naphthalene and pDCB were estimated to be 1.03 and 0.97 by comparison of the statistical moments. A significant loss of naphthalene and pDCB was also observed during the three well test, apparently due to biotransformation. These results suggest that biotransformation is the major process limiting the transport of naphthalene and similar compounds at the UCC site.