A quantitative description of vehicle exhaust particle size distributions in a highway tunnel

During the period May 18-May 22, 1999, a comprehensive study was conducted in the Tuscarora Mountain Tunnel on the Pennsylvania Turnpike to measure real-world motor-vehicle emissions. As part of this study, size distributions of particle emissions were determined using a scanning mobility particle sizer. Each measured size distribution consisted of two modes: a nucleation mode with midpoint diameter less than 20 nm and an accumulation mode with midpoint diameter less than 100 nm. The nucleation and accumulation components in some distributions also exhibited second maxima, which implies that such particle size distributions are superpositions of two particle size distributions. This hypothesis was utilized in fitting the particle size distributions that exhibited second maxima with four lognormal distributions, two for the nucleation mode and two for the accumulation mode. The fitting assumed that the observed particle size distribution was a combination of two bimodal log-normal distributions, one attributed to the heavy-duty diesel (HDD) vehicles and another attributed either to a different class of HDD vehicles or to the light-duty spark ignition vehicles. Based on this method, estimated particle production rates were 1.8 x 10(13) and 2.8 x 10(14) particles/vehicle-km for light-duty spark ignition and HDD vehicles, respectively, which agreed with independently obtained estimates.     

A modified clean-up procedure for the determination of PCDDs in soil samples

PCDDs can be determined in soil samples in the presence of high amounts of hexachlorocyclohexanes with a modified method, including a clean-up procedure with a column containing carbon. To reach low detection limits use is made of a column switching system in the GC-MS analysis.     

Landfill leachate effects on sorption of organic micropollutants onto aquifer materials

The effect of dissolved organic carbon as present in landfill leachate, on the sorption of organic micropollutants in aquifer materials was studied by laboratory batch and column experiments involving 15 non-polar organic chemicals, 5 landfill leachates and 4 aquifer materials of low organic carbon content. The experiments showed that hydrophobic organic micropollutants do partition into dissolved organic carbon found in landfill leachate potentially increasing their mobility. However, landfill leachate interacted with aquifer materials apparently increases the sorbent affinity for the hydrophobic micropollutants. The combination of these two mechanisms affected the observed distribution coefficients within a factor of two, in some cases increasing and in other cases decreasing the sorption of the chemicals. No means for prediction of the effect is currently available, but from a practical point of view, the effect of landfill leachate on retardation of organic micropollutants in aquifer material seems limited.     

Initial results from a multi-institutional collaboration to monitor harmful algal blooms in South Carolina

The rapid rate of development in the South Carolina (SC) coastal zone has heightened public concern for the condition of the state's estuaries, and alerted scientists to the potential that novel and adverse effects on estuarine ecosystems may result. Although well-developed databases from long-term monitoring programs exist for many variables valuable in predicting and following system responses, information on phytoplankton distributions in SC estuaries has lagged. Knowledge of the dynamical relationship between environmental (e.g., nutrient quantity and quality) and biological (e.g., grazing) regulation, and phytoplankton biomass and composition is critical to understanding estuarine susceptibility to eutrophication or harmful algal blooms (HABs). Recently, SC scientists from federal, state, and academic institutions established a collaborative monitoring program to assess HAB distribution and ecology statewide. The South Carolina Harmful Algal Bloom Program includes: a) intensive temporal monitoring at areas of known HAB occurrence or those exhibiting symptoms potentially related to HABs (e.g., prevalent fish lesions), b) extensive spatial monitoring in coordination with existing statewide efforts, c) a citizen volunteer monitoring network, d) nutrient response bioassays, and e) laboratory-based physiological experiments on HAB isolates. By combining trip-wire surveillance and rapid response systems, routine monitoring of environmental parameters and HAB distribution, and process-oriented studies examining the physiological functioning of HAB species, an enhanced understanding of the impact and environmental control of HABs in SC estuaries will be achieved. The application of this approach to studies on the distribution and physiological ecology of a new widespread SC red tide, and to the discovery of several potentially toxic blooms (including Pfiesteria) in SC holding ponds, are described.     

A data integration framework to support Triad projects

Cost‐effective and efficient site remediation and scientifically defensible decisions require site characterizations that are representative of site conditions. The Triad conceptual site model (CSM) is at the center of a continually improving site characterization process that begins during systematic planning and ends after the last data are developed. To gain the full benefit and greatest cost‐effectiveness, the process of CSM refinement should be performed in real time. Thus, the use of collaborative data is critical for evolving and maturing the CSM. In the field, through the use of all available data that are of known quality, a skilled and experienced field team can collect sufficient site information to mature the CSM in a timely manner. To facilitate the planning and execution of such a process, an easily understandable framework is needed to structure data quality that supports scientifically defensible decisions and efficient projects. This article explores such a framework. © 2004 Wiley Periodicals, Inc.     

The organization of integrated environmental research in The Netherlands

This article presents new concepts for the organization of increasingly complex environmental research activities on the institutional, the national, or the international level. An environmental research cycle with four phases, similar to the industrial product cycle, is described, and its implications in managing the interface between research, policy making, and enforcement are depicted. Furthermore, five main themes of future environmental research are proposed, including advanced analytical methods, environmental monitoring, an environmental management information system (EMIS), and the development of ecological targets at a national and a global level. The specific tasks of universities, private organizations, and governmental institutions in the total environmental research area are defined and a structure is proposed to develop collaborative networks.     

Coastal Environmental Impacts Brought About by Alterations to Freshwater Flow in the Gulf of Mexico

/ Freshwater inflow is one of the most influential landscape processes affecting community structure and function in lagoons, estuaries, and deltas of the world; nevertheless there are few reviews of coastal impacts associated with altered freshwater inputs. A conceptual model of the possible influences of freshwater inflows on biogeochemical and trophic interactions was used to structure this review, evaluate dominant effects, and discuss tools for coastal management. Studies in the Gulf of Mexico were used to exemplify problems commonly encountered by coastal zone managers and scientists around the world. Landscape alteration, impacting the timing and volume of freshwater inflow, was found to be the most common stress on estuarine systems. Poorly planned upstream landscape alterations can impact wetland and open-water salinity patterns, nutrients, sediment fertility, bottom topography, dissolved oxygen, and concentrations of xenobiotics. These, in turn, influence productivity, structure, and behavior of coastal plant and animal populations. Common biogeochemical impacts include excessive stratification, eutrophication, sediment deprivation, hypoxia, and contamination. Common biological impacts include reduction in livable habitats, promotion of "exotic" species, and decreased diversity. New multiobjective statistical models and dynamic landscape simulations, used to conduct policy-relevant experiments and integrate a wide variety of coastal data for freshwater inflow management, assume that optimum estuarine productivity and diversity is found somewhere between the stress associated with altered freshwater flow and the subsidy associated with natural flow. These models attempt to maximize the area of spatial overlap where favorable dynamic substrates, such as salinity, coincide with favorable fixed substrates, such as bottom topography. Based upon this principle of spatial overlap, a statistical performance model demonstrates how population vitality measurements (growth, survival, and reproduction) can be used to define sediment, freshwater, and nutrient loading limits. Similarly, a spatially articulate landscape simulation model demonstrates how cumulative impacts and ecosystem processes can be predicted as a function of changes in freshwater, sediment, and nutrient inflows.KEY WORDS: Resource management; Landscape impacts; Freshwater discharge; Coastal, ecosystem models; Coastal wetlands     

Chemotherapy of bacterial plasmids

Pharmacological approaches to plasmid chemotherapy are: 1) discovery of novel antibacterial drugs against which plasmids do not carry resistance genes, 2) molecular modification of existing drugs to render them non-susceptible to plasmid-encoded enzymes, 3) development of drugs which are selective inhibitors of plasmid DNA replication, 4) development of drugs which inhibit phenotypic expression of plasmid genes, and 5) development of drugs which are inhibitors of drug-inactivating enzymes that are plasmid gene products.