硼氢化钠还原法回收电镀废液中的铜

采用NaBH4作为还原剂回收电镀废液中的铜。正交实验结果表明,各因素对剩余铜离子质量浓度的影响的显著性顺序为n(NaBH4)∶n(CuSO4)反应时间反应温度。最佳实验条件为:n(NaBH4)∶n(CuSO4)=1.50,反应温度30℃,反应时间25min。经该工艺可获得平均粒径为33nm的近球形立方晶系纳米铜粉,处理后废液中铜离子质量浓度低至0.2mg/L。在铜粉制备过程中加入非离子型表面活性剂可有效阻止晶粒长大,并提高其分散性能,使产物粒径均匀。采用苯骈三氮唑处理后的铜粉抗氧化能力明显提高。     

乌鲁木齐市噪声监测现状、问题及对策

简要介绍了乌鲁木齐市噪声环境监测工作的现状,在主城区选择了具有代表意义的点位,采用"定点监测法"与"普查监测法"进行监测,对影响乌鲁木齐市声环境质量的生活噪声、交通噪声、工业噪声和建筑施工噪声做了定点或连续(24h在线)监测。就存在的问题做了分析探讨,并提出了相应的对策建议,以期为进一步改进乌鲁木齐市噪声监测和管理提供参考。     

Determination of antibiotics in sewage from hospitals, nursery and slaughter house, wastewater treatment plant and source water in Chongqing region of Three Gorge Reservoir in China

Sewage samples from 4 hospitals, 1 nursery, 1 slaughter house, 1 wastewater treatment plant and 5 source water samples of Chongqing region of Three Gorge Reservoir were analyzed for macrolide, lincosamide, trimethoprim, fluorouinolone, sulfonamide and tetracycline antibiotics by online solid-phase extraction and liquid chromatography-tandem mass spectrometry. Results showed that the concentration of ofloxacin (OFX) in hospital was the highest among all water environments ranged from 1.660 μg/L to 4.240 μg/L and norfloxacin (NOR, 0.136-1.620 μg/L), ciproflaxacin (CIP, ranged from 0.011 μg/L to 0.136 μg/L), trimethoprim (TMP, 0.061-0.174 μg/L) were commonly detected. Removal range of antibiotics in the wastewater treatment plant was 18-100% and the removal ratio of tylosin, oxytetracycline and tetracycline were 100%. Relatively higher removal efficiencies were observed for tylosin (TYL), oxytetracycline (OXY) and tetracycline (TET)(100%), while lower removal efficiencies were observed for Trimethoprim (TMP, 1%), Epi-iso-chlorotetracycline (EICIC, 18%) and Erythromycin-H₂O (ERY-H₂O, 24%). Antibiotics were removed more efficiently in primary treatment compared with those in secondary treatment.     

基于偏离份额分析法的产业结构分析研究——以山东省为例

以1999—2009年为考察期,利用偏离份额分析法(SSM)分析了山东省17个城市在产业结构与区位竞争力方面的优势和劣势,并根据产业结构偏离分量和区位偏离分量的组合情况,对各地区的经济增长状况进行了定位,有助于调整各城市的产业结构,缩小城市间的经济差距。     

Ambient TSP concentration and dustfall in major cities of China: Spatial distribution and temporal variability

Based on environmental monitoring data in 93 major cities and meteorological records at 398 weather stations in China from 1981 to 2007, total suspended particle (TSP) concentration, the intensity of dustfall, and sand and dust storm frequency (F_d) were analysed. During the past 27 years, the annual average TSP concentration (C_TSP) in 93 cities was 402 μg m^?3. Annual average C_TSP decreased from the north to the south and from inland to the coast areas with a peak value of 628.8 μg m^?3 in Lanzhou. In the 1980s, 1990s and 2000s, annual average C_TSP was 628.7, 319.2, and 250.1 μg m^?3, respectively. Annual average intensity of dustfall (I_d) was 240.5 t km^?2 a^?1, decreased from northern to southern China and from inland to the coast areas with the maximum value of 717.2 t km^?2 a^?1 in Baotou. In the 1980s, 1990s and 2000s, annual average I_d was 334.8, 220.9, 146 t km^?2 a^?1 respectively. Annual average I_d in the Loess Plateau region was commonly higher than 200 t km^?2 a^?1. The annual average F_d decreased from arid regions in northwestern China to humid areas in southeastern China with two sand and sand storm centers existing in Xinjiang Taklamakan Desert and western Inner Mongolia. The annual average F_d in the 1980s, 1990s, 2000s was 16, 8, 6 days respectively, decreased steadily from 18 days in 1981–5 days in 2007. Annual average I_d had a positive linear relation to annual average C_TSP (R² = 0.96). Annual average F_d had a positive relation with annual average C_TSP (R² = 0.97) as well as annual average I_d (R² = 0.94). TSP was the chief pollutant influencing Air Pollution Index (API) in northern China in spring and winter seasons. Sand and dust storm might be a major factor affecting the temporal variability and spatial distribution of TSP and dustfall in China.     

太湖湿地生态系统服务功能价值评估

随着生物资源价值估算方法的日益成熟,生态系统的服务评估成为生态系统研究的热点。运用市场价值、影子工程、碳税法等方法对太湖湿地生态系统的物质生产功能、环境调节功能和文化社会功能等直接与间接价值进行评估。结果表明：太湖湿地生态系统具有巨大和多重服务价值,总价值为112.39×10⁸元。其中,生态环境调节与维护功能价值最大,占总服务价值的48.98%;其次是物质生产与供给功能,占29.1%;文化社会功能最小,占21.91%。通过对9项子功能进行评估得出,调蓄洪水的功能价值最大,约占26.23%,供水功能其次,约占24.56%,气候调节功能,约占18.23%,科研教育价值约占13.16%,植被资源生产功能价值最小,约占0.09%。此项研究首次定量评估了太湖湿地生态系统的服务功能价值,研究成果对于认识太湖湿地的价值,有针对性地保护太湖湿地具有现实意义。     

汶川灾区居民环境意识现状与提升对策研究——以龙门山镇为例

以彭州市龙门山镇为例,实地调查、问卷调查与访谈相结合,从知识、态度和行为三个角度对灾后公众环境意识状况进行研究。当地居民环境知识水平普遍较低;对环境问题关注度较高,环境态度较好;环境行为差异较大。职业、性别、年龄和文化程度对环境意识影响主要体现在环境知识方面而对环保态度和环保行为影响不大。旅游业受地震破坏严重,灾后物资紧缺,环境教育应结合实际,针对学生、村民、公务员等不同人群分别采取对应措施。     

直播稻田渗漏水磷素动态变化及渗漏流失潜力研究

通过田间实验,对太湖流域丹阳地区直播水稻田不同施磷水平下渗漏水磷素动态变化特征及流失潜力进行了研究。结果表明,施磷能明显提高地下60cm以上深度土层渗漏水磷的含量。各土层渗漏液总磷浓度随土层深度的增加呈下降趋势。随着施磷量的增加,稻田渗漏水磷素含量也会随之增加。土壤磷素发生渗漏流失的土壤表层Olsen-P含量的"突变点"change-Point为25.17 mg/kg。当土壤中的Olsen-P浓度小于25.17mg/kg时,20～40cm土层渗漏水中TP浓度基本上不随土壤Olsen-P浓度的变化而变化,但当土壤中Olsen-P大于25.17mg/kg时,20～40cm土层渗漏水中TP浓度会大量增加,且土壤中的Olsen-P每增加10 mg/kg,渗漏水TP将增加0.21 mg/L。稻田当季累计土壤磷素渗漏流失负荷为1.02 kg/ha,占当季施磷量的2.80%。     

UV-H_2O_2联用工艺去除水中阿特拉津的研究

采用间歇式反应器考察了UV-H2O2高级氧化技术去除水中阿特拉津的效果及其影响因素,并进行了相关的反应动力学研究。结果表明,在pH值6.9,阿特拉津初始浓度500μg/L,紫外辐照强度172μW/cm2时,H2O2投加量50mg/L,反应10min后,阿特拉津的去除率90%。UV-H2O2联用工艺对阿特拉津的降解符合一级反应动力学。H2O2在该联用工艺降解阿特拉津中具有双重作用,一方面,当H2O2投加量较小时,一级反应速率常数随H2O2投加量的增加基本呈现线性增加的趋势;另一方面,当H2O2浓度增加到一定程度(90mg/L)后,阿特拉津的降解速率随H2O2浓度的变化已不明显,而H2O2浓度为102mg/L时,则出现了抑制作用。