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131.
Preparation and Properties of Thermoplastic Starch/Montmorillonite Nanocomposite Using N-(2-Hydroxyethyl)formamide as a New Additive 总被引:1,自引:0,他引:1
Hongguang Dai Peter R. Chang Fengying Geng Jiugao Yu Xiaofei Ma 《Journal of Polymers and the Environment》2009,17(4):225-232
N-(2-Hydroxyethyl)formamide (HF) was synthesized efficiently and used as a new additive to prepare thermoplastic starch/montmorillonite
nanocomposite (TPS/MMT). Here, HF acted as both plasticizer for TPS and swelling agent for MMT. The hydrogen bond interaction
among HF, starch and MMT was proven by Fourier-transform infrared (FT-IR) spectroscopy. By scanning electron microscope (SEM),
starch granules were completely disrupted. Atomic force microscopy demonstrated that partially exfoliated TPS/MMT nanocomposite
was formed. The crystallinity of corn starch, MMT, HF-plasticized TPS (HTPS) and TPS/MMT nanocomposite was characterized by
X-ray diffraction (XRD). Thermal stability of HTPS and TPS/MMT was determined by thermogravimetric analysis (TGA). The water
resistance of TPS/MMT nanocomposite increased compared with that of pure HTPS. Tensile strengths of TPS/MMT nanocomposites
were higher than those of HTPS, but just the reverse for elongations at break. 相似文献
132.
133.
Hong Geng Hae-Jin Jung YooMyung Park HeeJin Hwang HyeKyeong Kim Yoo Jung Kim Young Sunwoo Chul-Un Ro 《Atmospheric environment (Oxford, England : 1994)》2009,43(21):3364-3373
Determination of the chemical compositions of atmospheric single particles in the Yellow Sea region is critical for evaluating the environmental impact caused by air pollutants emitted from mainland China and the Korean peninsula. After ambient aerosol particles were collected by the Dekati PM10 cascade impactor on July 17–23, 2007 at Tokchok Island (approximately 50 km west of the Korean coast nearby Seoul), Korea, overall 2000 particles (on stage 2 and 3 with cut-off diameters of 2.5–10 μm and 1.0–2.5 μm, respectively) in 10 samples were determined by using low-Z particle electron probe X-ray microanalysis. X-ray spectral and secondary electron image (SEI) data showed that soil-derived and sea-salt particles which had reacted or were mixed with SO2 and NOx (or their acidic products) outnumbered the primary and “genuine” ones (59.2% vs. 19.2% in the stage 2 fraction and 41.3% vs. 9.9% in the stage 3 fraction). Moreover, particles containing nitrate in the secondary soil-derived species greatly outnumbered those containing sulfate. Organic particles, mainly consisting of marine biogenic species, were more abundant in the stage 2 fraction than in the stage 3 fraction (11.6% vs. 5.1%). Their relative abundance was greater than the sum of carbon-rich, K-containing, Fe-containing, and fly ash particles, which exhibited low frequencies in all the samples. In addition, many droplets rich in C, N, O, and S were observed. They tended to be small, exhibiting a dark round shape on SEI, and generally included 8–20 at.% C, 0–12 at.% N, 60–80 at.% O, and 4–10 at.% S (sometimes with <3 at.% Mg and Na). They were attributed to be a mixture of carbonaceous matter, H2SO4, and NH4HSO4/(NH4)2SO4, mostly from the reaction of atmospheric SO2 with NH3 under high relative humidity. The analysis of the relationship between the aerosol particle compositions and 72-h backward air-mass trajectories suggests that ambient aerosols at Tokchok Island are strongly affected not only by seawater from the Yellow Sea but also by anthropogenic pollutants emitted from China and the Seoul–Incheon metropolis, resulting in the dominance of complex secondary aerosol particles. 相似文献
134.
湖北省湿地冬季水鸟多样性研究 总被引:11,自引:1,他引:11
报道了2004年1~4月湖北冬季水鸟调查结果,记录水鸟 66 种,种群数量 59 613 只,分属8目15科,其中列入国家重点保护的一级鸟类 4 种,115 只,国家二级 7 种,2 968 只。分析了冬季水鸟群落结构、分布和种群变动,并用生物多样性指数、物种丰富度与生物量3个不同的测度指标对其中12个湖泊的水鸟群落进行了评价,认为沉湖、梁子湖、龙感湖和网湖是较为成熟稳定的群落;并从沉湖东方白鹳(Ciconia boyciana)、龙感湖白头鹤(Grus monacha)、洪湖鸭科水鸟近40年的种群动态探讨了湿地水鸟现状,认为种群衰退趋势明显、湿地干扰和威胁严重。对此提出了加强湿地保护区的建设,理顺管理体制,合理规划与发展湿地产业和保护湿地资源对策。 相似文献
135.
136.
生态环境监测管理制度改革对省级生态环境监测机构的管理能力提出更高要求,在数字化发展战略背景下,推动生态环境监测数字化建设是促进监测能力现代化的必由之路.以广东省为例,从生态环境监测管理需求出发,分析改革面临的难点和问题,提出了构建智慧生态环境监测管理体系的思路.以监测业务为主线,串联全省监测人、财、物、事的管理,利用数... 相似文献
137.
日益严重的电子垃圾污染已直接或间接地危害到人类的健康,因此,电子垃圾的有效管理变得越来越重要。文章简要分析了目前世界总体电子垃圾的产生特点以及中国电子垃圾的污染现状,通过分析中国对于电子垃圾污染和管理采取的一系列政策和措施的有效性,重点对比研究了现阶段中国与几个发达国家电子垃圾的管理回收手段及政策,试图寻找中国电子垃圾管理的有效措施。最后,综合各国管理经验提出了电子垃圾的管理方案,从而为中国的电子垃圾管理提供借鉴与建议。 相似文献
138.
对京杭运河常州段8个研究点位水体中的氮形态(TN、NH4+-N、NO2--N和NO3--N)和环境因子(pH、T和DO)进行了连续9个月的动态监测,全面研究了各氮形态的随时间和空间的动态变化规律,并对各氮形态及环境因子进行了相关性分析。常州段水体月平均NH4+-N变化范围为(0.589±0.351)~(3.148±1.178)mg.L-1,TN变化范围为(3.373±1.379)~(7.373±2.307)mg.L-1,枯水期到丰水期各氮形态整体表现出波动性下降趋势,其中出境断面NH4+-N下降趋势平稳,NO3--N则是主导出境断面TN含量的主要形态。各点位NH4+-N的平均浓度范围为(1.202±0.492)~(2.813±1.566)mg.L-1,TN范围为(3.520±0.504)~(8.349±3.679)mg.L-1,各形态氮含量基本呈现出上游段(S)〈新运河(G)〈老运河(L)〈下游(X)的空间分布特征,其中下游段存在一个重要的氮素上升突变段,NO3--N是对TN的贡献率(43.8%~57.4%)最大的无机态氮,其次是NH4+-N、ON、NO2--N,其中有机氮对TN的贡献率(13.3%)则以老河段最高。NH4+-N和NO3--N、TN、pH相关系数分别为0.397**、0.932**、0.261*,与DO相关系数为-0.344**,陆源输入及DO不足是京杭运河常州段氮污染严重的重要原因。 相似文献
139.
Sun Zhifang Gao Rufei Chen Xuemei Liu Xueqing Ding Yubin Geng Yanqing Mu Xinyi Liu Taihang Li Fangfang Wang Yingxiong He Junlin 《Environmental science and pollution research international》2021,28(31):42024-42036
Environmental Science and Pollution Research - Butylated hydroxytoluene (BHT), one of the most widely used synthetic phenolic antioxidants, is a popular food additive. Previous studies have... 相似文献
140.
砷(As)在土壤中的赋存形态复杂, 常规固化稳定化材料处理不同形态As时存在局限。针对该问题,通过整合生物炭(bio-char, BC)表面吸附-静电引力-络合螯合与铁锰双氧化物(ferric manganese binary oxides, FMBO)共沉淀-氧化还原作用, 制得负载了FMBO的BC新功能材料BCFM, 并与硅酸盐水泥复配固化稳定化As, 利用响应面法探讨影响因素对处理效果的影响。结果表明:在BCFM与硅酸盐水泥配比为9.88%和8.80%、养护20.53 d条件下, As浸出浓度最低为0.055 mg/L, 可交换态含量占比从4%降至0.5%, 残渣态含量占比从77%升至87%, 无侧限抗压强度>50 kPa。推测BCFM固化稳定化机制为Fe-O(H)-As共沉淀、Mn-O(H)-As氧化和BC功能的联合作用。该研究结果可为长效固化稳定化As提供新的技术方案。 相似文献