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51.
临界区甲醇的聚碳酸酯降解研究 总被引:2,自引:0,他引:2
在间歇高压反应器中研究了聚碳酸酯在甲醇临界区域的降解行为 .降解无需借助催化剂 ,降解温度 2 2 0— 2 6 0℃ ,压力5 2 0— 8 6 7MPa ,时间 5— 4 5min ,通过GC MS与GC FID对液相产物进行了定性和定量分析 ,聚碳酸酯醇解主要产物为碳酸二甲酯 (DMC)和双酚A(BPA) .降解温度和时间为 2 4 0℃和 30min时 ,DMC和BPA的产率分别 91 75 %和 90 0 3% .通过凝胶渗透色谱 (GPC)对 2 4 0℃醇解反应的固相聚合物进行了分析 .降解初期 ,聚合物大分子发生断裂 ,PC的数均分子量 (Mn)迅速下降 ,仅有少量DMC和BPA生成 ;降解的中间阶段 ,低聚物在降解产物中的比例快速增加 ,同时DMC与BPA相应增多 ,最终PC被完全分解 . 相似文献
52.
Xu Peidong Wu Ji Wang Hui Tang Shan Cheng Wenlong Li Min Bu Rongyan Han Shang Geng Mingjian 《Environmental science and pollution research international》2023,30(2):2676-2684
Environmental Science and Pollution Research - The influence of the combined application of chemical fertilizer with green manure on the stabilization of organic carbon (C) was explored in the... 相似文献
53.
Emission factors of gaseous carbonaceous species from residential combustion of coal and crop residue briquettes 总被引:3,自引:0,他引:3
Qin WANG Chunmei GENG Sihua LU Wentai CHEN Min SHAO 《Frontiers of Environmental Science & Engineering》2013,7(1):66-76
Experiments were performed to measure the emission factors (EFs) of gaseous carbonaceous species, such as CO2, CO, CH4, and non-methane volatile organic compounds (NMVOCs), from the combustion of five types of coal of varying organic maturity and two types of biomass briquettes under residential burning conditions. Samples were collected in stainless steel canisters and 2,4-dinitrophenylhydrazine (DNPH) cartridges and were analyzed by GC-FID/MS and HPLC, respectively. The EFs from crop residue briquette burning were generally higher than those from coals, with the exception of CO2. The dominant NMVOC species identified in coal smoke were carbonyls (41.7%), followed by C2 unsaturated hydrocarbons (29.1%) and aromatics (12.1%), while C2 unsaturated hydrocarbons were the dominant species (68.9%) emitted from the combustion of crop residue briquettes, followed by aromatics (14.4%). A comparison of burning normal crop residues in stoves and the open field indicated that briquettes emitted a larger proportion of ethene and acetylene. Both combustion efficiency and coal organic maturity had a significant impact on NMVOC EFs from burning coal: NMVOC emissions increased with increasing coal organic maturity but decreased as the combustion efficiency improved. Emissions from the combustion of crop residue briquettes from stoves occurred mainly during the smoldering process, with low combustion efficiency. Therefore, an improved stove design to allow higher combustion efficiency would be beneficial for reducing emissions of carbonaceous air pollutants. 相似文献
54.
55.
The fast growing of urban areas in developing countries has brought serious problems on municipal solid waste (MSW) management. It will be rational to adopt an integrated approach to deal with such a challenge so that the overall eco-efficiency of MSW management could be improved. To better examine how attributes of integrated MSW management are being interpreted and put into practice, and to explore what changes should be made to improve the application of integrated MSW management, we employ a case study method so that lessons learned could be used to inform initiatives in other cities and the potential solution may offer feasible strategies. The case study city is Dalian, a typical seaport city with fast growing rate in economy. The outcomes of this case study show us that fragmented management structure, ineffective and inefficient enforcement of relevant regulations, backward technologies, limited financial resources and lack of public participation are main barriers for the implementation of integrated MSW management. Consequently, in order to overcome these barriers, we propose an integrated management framework on MSW management, aiming to maximize the overall eco-efficiency of MSW management. 相似文献
56.
Qiuqing Geng Fang Chen Ingvar Holmér 《International journal of occupational safety and ergonomics》2013,19(1-2):15-29
This article presents a study on the effect of different protective gloves (which are commercially available and commonly used in the cold) on manual dexterity in cold environments. The experiments compared statistically four different types of gloves and two different types of gloving (outer or double) at +19 °C and -10 °C. Performance was determined both objectively and subjectively using two manual dexterity tasks: bolt-nut and pick-up tasks. The response measured was the time of performing each task. Statistical analysis showed that all independent factors such as glove type, participant, object size, and temperature had significant effects on the hand cooling reaction. A significant difference in the performance between the gloves was found in the bolt-nut task. It was also found that outer-inner combination gloving may be an approach to use for precision tasks. 相似文献
57.
散装液体危化品码头的污染原因分析及防控对策 总被引:1,自引:0,他引:1
介绍了液体危化品的特点,对散装液体危化品码头的污染原因进行了分析,并提出了相应的防控对策,为确保码头安全稳定运行提供了保障. 相似文献
58.
废水经格栅去除杂物后,用潜污泵抽至斜板沉淀池,同时加入去磷剂,出水自流进入曝气生物滤池,DO控制在3-5 mg/l,出水进入清水池后再进入消毒池,二氧化氯加入量为30 g/M3 废水,停留时间1.5 h.曝气生物滤池12~24小时进行反冲洗一次,反冲洗出水再返回调节池、斜板沉淀池每天排泥一次,排入污泥沉淀池,其上清液进入调节池,剩余污泥定期消毒后环卫清污车运走.经处理后水质达到(GB8978-1996)一级排放标准.以曝气生物滤池为主工艺处理医院污水,工艺可靠、出水稳定,但必须按严格的管理程序、即质量测试、操作设备、工艺技术管理环节,同时设备必须一年进行一次大修,处理后水质稳定达标排放是可行的. 控制在3-5 mg/l,出水进入清水池后再进入消毒池,二氧化氯加入量为30 g/M3 废水,停留时间1.5 h.曝气生物滤池12~24小时进行反冲洗一次,反冲洗出水再返回调节池、斜板沉淀池每天排泥一次,排入污泥沉淀池,其上清液进入调节池,剩余污泥定期消毒后环卫清污车运走.经处理后水质达到(GB8978-1996)一级排放标准.以曝气生物滤池为主工艺处理医院污水,工艺可靠、出水稳定,但必须按严格的管理程序、即质量测试、 作设备、工艺技术管理环节,同时设备必须一年进行一次大修,处理 相似文献
59.
中国环境影响评价管理的现状、问题及展望 总被引:4,自引:0,他引:4
文章在客观分析中国环境影响评价的发展历史、现有法规体系、管理体制和主要成绩的基础上,指出了环境影响评价管理中存在的规划环评滞后、监管环节薄弱、公众参与不足以及队伍能力欠缺等主要问题。结合中国环境影响评价管理的特点和相关领域的发展变化,对未来环境影响评价工作的开展进行了展望。认为应该重点加强四个方面的工作,即通过确立环境目标来促进经济增长方式的转变,通过完善空间规划体系为规划环评提供基本依据,通过加强环境监管来促进环保措施落实,通过加强队伍能力建设来提高环评质量。 相似文献
60.
In 1999 China adopted the "Conversion of Cropland to Forest and Grassland Program" (CCFGP), a nationwide ecological recovery program, to minimize wide-scale soil erosion and vegetation degradation in China, as well as to improve water budgeting results. In the 10 yr since implementation, the CCFGP has resulted in the recovery and reforestation of >100,000 km of cropland and bare land, though the quantitative effect of this program on catchment water budget is not entirely clear. Therefore, we used the Soil and Water Assessment Tool to evaluate and quantify the effects of the CCFGP on the water budget of the Jinghe River catchment, a tributary of the Yellow River covering the central region of the Loess Plateau. Our results indicated that precipitation had dropped by 12.0% from the 1970s (611.6 mm) to the 2000s (538 mm) and that there was a corresponding 25.2% decrease in humidity index from 0.48 to 0.36. Before the CCFGP's implementation, forest and grassland had been decreasing, while bare land, cropland, and shrub land had been increasing. After the implementation of the CCFGP, the opposite trend was observed. Moreover, streamflow increased by about 15 and 20% for the upstream and middle stream subbasins, respectively, while soil water content also showed an obvious increase. Over the same period, evapotranspiration decreased by 5.2 and 13.5 mm and runoff decreased by 37.5 and 38.6% in the two subbasins. The same trends were obtained in the downstream subbasin, where changes were even greater. As a result of the reduced runoff and evapotranspiration, utilization of water resources was more efficient and ecological environment was improved under the CCFGP policy. Our results indicate the CCFGP resulted in a favorable ecological impact and should therefore be maintained. 相似文献