Characteristics of wastes from electric and electronic equipment in Greece: results of a field survey.

The lifespan of electric and electronic equipment is becoming shorter and the amount of related waste is increasing. This study aimed to contribute to the knowledge about qualitative and quantitative characteristics of such wastes in Greece. Specifically, results are presented from a field survey, which took place in the city of Thessaloniki, Greece, during the year 2002. The survey was conducted with suitable questionnaires in department stores and in households of various municipalities. Household appliances were grouped as follows: (A) large (refrigerator, freezer, washing machine, clothes dryer, electric cooker, microwave oven, electric heater), (B) small (vacuum cleaner, electric iron, hair dryer), (C) information technology and telecommunication equipment (PC, laptop, printer, phone) and (D) consumer equipment (radio, TV, video, DVD, console). The analysis indicated that the lifespan of all new goods is gradually reducing (apart from refrigerators, for which the lifespan was surprisingly found to be increasing) and provided linearized functions for predicting the lifespan, according to the year of manufacture, for certain large appliances.     

Trace Metals in Different Crop/Cultivation Systems in Greece

Typical soils in Greece are neutral or alkaline and frequently are lime-rich, conditions that favour the accumulation of trace elements. The traditional use of metal-based fungicides in orchards and vineyards may have led to the accumulation of trace metals. Concentrations of Fe, Cu, Mn, Zn (aqua regia digestion) and some other soil parameters were measured in organically and conventionally cultivated soils (0–30 cm) from vineyards, olive groves and citrus groves of varying ages, and in uncultivated soils. Many vineyards and olive groves are situated in hilly or mountainous areas with sloping ground or terraces in contrastto citrus, which is cultivated in lower lying areas. Due to the difficulty of access, these crops often are cultivated extensively in both systems. Trace metal concentrations were found to lie withinthe ranges expected for the predominant soil types. Cu concentrations were relatively high (>100 mg kg^-1) in a few samples, but were not correlated with the age of the cultivation. A two-way ANOVA analysis showed larger differences in the mean concentrations of Cu, Mn and Zn between different crops (p≤ 0.001 for Cu, p≤ 0.05 for Zn, and p≤ 0.1 for Mn) than between different cultivation systems (no significant differences). The crop by cultivation interaction was not statistically significant for any metal (p > 0.8). Strong correlations (p≤ 0.001) were found between Fe, Mn and Zn and both clay concentration and CEC, although these relationshipswere not uniform throughout the different crop and cultivation systems. Concentrations of Cu were related to clay concentrations only for vineyards and to CEC only for citrus. Correlations were not found with organic matter or pH.     

An alternative method for the treatment of waste produced at a dye and a metal-plating industry using natural and/or waste materials.

The aim of this study was to develop cost-effective, appropriate solidification technologies for treating hazardous industrial wastes that are currently disposed of in ways that may threaten the quality of local groundwater. One major objective was to use materials other than cement, and preferably materials that are themselves wastes, as the solidification additives, namely using wastes to treat wastes or locally available natural material. This research examines the cement-based and lime-based stabilization/solidification (S/S) techniques applied for waste generated at a metal-plating industry and a dye industry. For the lime-based S/S process the following binder mixtures were used: cement kiln dust/ lime, bentonite/lime and gypsum/lime. For the cement-based S/S process three binder mixtures were used: cement kiln dust/cement, bentonite/cement and gypsum/cement. The leachability of the wastes was evaluated using the toxicity characteristic leaching procedure. The applicability and optimum weight ratio of the binder mixtures were estimated using the unconfined compressive strength test. The optimum ratio mixtures were mixed with waste samples in different ratios and cured for 28 days in order to find the S/S products with the highest strength and lowest leachability at the same time. The results of this work showed that the cement-and lime-based S/S process, using cement kiln dust and bentonite as additives can be effectively used in order to treat industrial waste.     

Weed mapping in cotton using ground-based sensors and GIS

Site-specific weed management presupposes the careful monitoring and mapping of weed infestation areas. Cut-edge sensor technologies coupled with geographical information systems (GIS) provide the means for reliable decision-making concerning weed management even in sub-field level. In present research, two different spectral sensing systems were engaged in order to digitally map weed patches as grown in four different cotton fields in Central Greece. The systems used were a set of two Crop Circle multispectral sensors ACS-430 and a digital camera Nikon D300S. The spaces between cotton rows were scanned and photographed with the two systems accordingly. Raw recorded data were stored and analyzed in GIS environment producing spatially interpolated maps of red-edge normalized difference vegetation index (NDVI) and weed cover percentage values. Both mapping approaches were satisfactorily related to weed distribution as occurred in the fields; however, the photographic method tended to underestimate weed populations. Correlation of red-edge NDVI and weed cover values, at the points where photographs were taken, as revealed by Pearson’s correlation coefficient was high (r?>?0.83) and statistically significant at the 0.01 level. A first-degree linear equation adequately modeled (R²?>?0.7) the between value pair relations, strengthening the validity of the two methodologies in spatially monitoring weed patches. The methodologies and the technologies used in the study can be used for yearly mapping weed flora in cotton cultivation and potentially constitute a means of rationalizing herbicide application in terms of doses and spatio-temporal decision-making.     

Building a strategy for soil protection at local and regional scale—the case of agricultural wastes landspreading

Agricultural wastes (AW) are produced in huge quantities worldwide and may cause detrimental effects on environmental quality, affecting soil, water, and air quality. Given the growing soil degradation worldwide, the need for more food of good quality and therefore the intensified agriculture, it is important to develop recycling plans even for those types of treated AW (e.g., composts) that are not considered hazardous. Two strategic approaches for safe and sustainable landspreading of organic wastes are proposed, depending on wastes properties and hazard potential, i.e., an approach appropriate for traditionally used wastes (manures and composts) and another approach for wastes that are potentially hazardous or hazardous and should only be reused under specific restrictions. Both approaches foresee concrete steps, require close cooperation between farmers and local/regional authorities, and are appropriate to ensure environmental sustainability at AW recycling or disposal areas. Desktop and web application tools are also presented that are anticipated to assist authorities in implementing their monitoring strategies.     

Social trends of the people of the region of Eastern Macedonia and Thrace-Greece: about the potential of using biofuels from forest products residues

In the framework of enquiry of biomass usage possibilities in our country, a research was made through the whole Eastern Macedonia region, related to disposal possibilities from the production conveyors and usage possibilities from the region’s residents and businessmen, of biofuels that come from mechanical wood treatment residues and from the residues of agricultural production, in wooden form, known with the term wood pellets or wood briquettes. From the present study, it came to light that there is an intense interest for direct personal usage and application of biomass for the residents or occupational spaces heating. The necessary biomass quantity for the entire region’s households is estimated up to 205,520 t. From the biomass usage as a combustible material, a 680 €/year and household about, is made. The potential investments that will be made to the region seem to have a very short depreciation, but a business plan and a marketing plan syntax are considered as necessary for the result’s maximisation.     

Preliminary study for the management of construction and demolition waste

This paper refers to the management of the construction and demolition (C&D) waste since, according to the EU Waste Strategy, C&D waste is considered to be one of the priority waste streams and appropriate actions need to be taken with respect to its effective management. Initially, the paper presents the state-of-the-art of the problem of C&D waste, including the amount and composition of C&D waste in EU countries, differences in the characteristics of this waste stream depending on its origin, as well as collection and management practices that are applied. A methodology is described for the estimation of the quantities of the waste stream under examination, since in most cases quantitative primary data is not available. Next, the fundamentals for the development of an integrated scheme for the management of C&D waste are presented and discussed, such as appropriate demolition procedures and location of waste management (off-site waste management, on-site waste management, direct on-site recovery, centralized on-site recovery). Finally, taking into consideration all relevant parameters, alternative systems that could be applied for the management of the C&D waste are suggested.     

Multi-criteria analysis for the determination of the best WEEE management scenario in Cyprus

Waste from electrical and electronic equipment (WEEE) constitutes one of the most complicated solid waste streams in terms of its composition, and, as a result, it is difficult to be effectively managed. In view of the environmental problems derived from WEEE management, many countries have established national legislation to improve the reuse, recycling and other forms of recovery of this waste stream so as to apply suitable management schemes. In this work, alternative systems are examined for the WEEE management in Cyprus. These systems are evaluated by developing and applying the Multi-Criteria Decision Making (MCDM) method PROMETHEE. In particular, through this MCDM method, 12 alternative management systems were compared and ranked according to their performance and efficiency. The obtained results show that the management schemes/systems based on partial disassembly are the most suitable for implementation in Cyprus. More specifically, the optimum scenario/system that can be implemented in Cyprus is that of partial disassembly and forwarding of recyclable materials to the native existing market and disposal of the residues at landfill sites.     

Development and Application of Software Tools for Monitoring, Assessment and Reporting of Data Concerning the Operation of Urban Wastewater Treatment Plants in Cyprus

This work focuses on the development and application of appropriate software tools for recording, assessing and reporting data related to the operation of the Urban Wastewater Treatment Plants (UWTPs) in Cyprus. An appropriate Internet-Based Management System was designed, developed and installed at the premises of the UWTPs and of the Cypriot Competent Authority (Water Development Department — WDD) in order to coordinate and disseminate tasks and related information for monitoring the operation of UWTPs. In addition, a client Geographical Information System database was compiled to be used for obtaining and analyzing spatial information. The software tools are based on common procedures and state-of-the-art technology for the recording and transmission of data and information and they provide an integrated view related to the operation and the efficiency of wastewater treatment systems. Moreover, continuous control and systematic monitoring of the UWTPs by the operators as well as continuous and direct supervision of the UWTPs environmental performance is achieved by the personnel of the Competent Authority. Furthermore, direct and unobstructed provision of data to the Competent Authority of Cyprus is accomplished by the operators of the UWTPs, while the Competent Authority is supported to compose full and representative reports to the European Commission and other International Organizations. The developed tools enable the direct recording of data obtained through measurements and analyses, permit the comparison of data with existing legislation and provide an integrated picture of the operation of the wastewater treatment plants as well as the option to focus and assess each individual treatment stage.     

Prediction of microbial accessibility of carbon-14-phenanthrene in soil in the presence of pyrene or benzo[a]pyrene using an aqueous cyclodextrin extraction technique

Traditionally, solvent extractions are routinely used in the assessment of contaminated land. However, vigorous solvent extractions only give total concentrations rather than that relating to the bioaccessible fraction. Recently, less harsh, aqueous-based extraction methods have been shown to be a better estimate of the microbial degradation of polycyclic aromatic hydrocarbons (PAHs). The aqueous-based hydroxypropyl-beta-cyclodextrin (HPCD) extraction technique was tested using 14C-PAHs in soils and compared against indigenous microbial mineralization (a measure of bioaccessibility) of 14C-phenanthrene in the presence of pyrene or benzo[a]pyrene (B[a]P) over a range of concentrations (0, 5, 10, or 50 mg kg(-1)) and aged for 0, 25, 50, and 100 d in four soils. At each time point, the total loss, extractability, and mineralization of 14C-phenanthrene was measured in each of the soils. The presence of the other PAHs had little effect on the behavior of 14C-phenanthrene in any of the soils. Comparisons between the amounts of 14C-phenanthrene extracted using HPCD and mineralized were made and showed that there was a correlation (1:1). This study demonstrates that HPCD extraction is able to predict the microbial accessibility fraction of 14C-phenanthrene in the presence of other PAHs in a range of soils, further supporting the applicability of this technique.