全文获取类型
收费全文 | 2526篇 |
免费 | 77篇 |
国内免费 | 865篇 |
专业分类
安全科学 | 186篇 |
废物处理 | 145篇 |
环保管理 | 203篇 |
综合类 | 1252篇 |
基础理论 | 440篇 |
污染及防治 | 901篇 |
评价与监测 | 123篇 |
社会与环境 | 94篇 |
灾害及防治 | 124篇 |
出版年
2024年 | 1篇 |
2023年 | 42篇 |
2022年 | 119篇 |
2021年 | 93篇 |
2020年 | 76篇 |
2019年 | 88篇 |
2018年 | 77篇 |
2017年 | 107篇 |
2016年 | 108篇 |
2015年 | 144篇 |
2014年 | 218篇 |
2013年 | 265篇 |
2012年 | 196篇 |
2011年 | 210篇 |
2010年 | 193篇 |
2009年 | 167篇 |
2008年 | 163篇 |
2007年 | 128篇 |
2006年 | 147篇 |
2005年 | 102篇 |
2004年 | 90篇 |
2003年 | 79篇 |
2002年 | 86篇 |
2001年 | 112篇 |
2000年 | 74篇 |
1999年 | 70篇 |
1998年 | 72篇 |
1997年 | 51篇 |
1996年 | 41篇 |
1995年 | 36篇 |
1994年 | 30篇 |
1993年 | 21篇 |
1992年 | 18篇 |
1991年 | 7篇 |
1990年 | 14篇 |
1989年 | 3篇 |
1988年 | 5篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 1篇 |
排序方式: 共有3468条查询结果,搜索用时 623 毫秒
921.
抗生素作为疾病预防和促进生长的药物被广泛用于水产养殖业中,不可避免地造成了周围环境抗生素的残留,从而带来各种潜在风险。为了对水产养殖水和沉积物中的抗生素残留特征进行研究,建立了环境样品中抗生素的富集方法。对沉积物中抗生素的提取溶剂、HLB小柱活化溶剂和洗脱溶剂进行了筛选,利用高效液相色谱串联质谱仪对15种抗生素进行检测分析,并检测了上海市某水产养殖区7个养殖塘2018年9、12月抗生素的残留水平。结果表明,选用乙腈/磷酸盐缓冲溶液(V∶V=1∶1)作为提取溶剂,依此用甲基叔丁基醚、甲醇和超纯水作为活化溶剂,甲醇作为洗脱溶剂时目标抗生素的回收率最高;在养殖塘水体中共检测出10种抗生素,检出浓度中间值依次为:磺胺类>甲氧苄啶>阿莫西林>氟喹诺酮类>喹乙醇>四环素类和呋喃唑酮。养殖塘沉积物中共检测出13种抗生素,检出浓度中间值依次为:氟喹诺酮类>四环素类>磺胺类>甲氧苄啶>喹乙醇>阿莫西林和呋喃唑酮;不同品种的养殖塘中抗生素的检出种类均不相同,其中青鱼塘和白水鱼塘10种、虾塘9种、扣蟹塘仅5种。对比抗生素检出浓度发现:氟喹诺酮类抗生素在鱼类养殖塘中检出浓度最高,磺胺甲恶唑仅在蟹塘检出,喹乙醇在虾塘检出浓度达3 612.85 ng·L~(-1)。9月与12月抗生素的残留水平也存在差异,抗生素在9月的平均含量比12月高。 相似文献
922.
精神活性物质是一类摄入人体后对中枢神经系统具有强烈兴奋或抑制作用的新型污染物,其在水环境中的存在可能对水生生物、水生态系统甚至人体健康产生潜在的危害。为评价太湖中精神活性物质的污染水平和生态风险,利用超高效液相色谱-质谱联用法检测了太湖19条入湖河流中13种典型精神活性物质的质量浓度和空间分布规律。结果表明,在太湖19条入湖河流中除苯甲酰牙子碱(BE)和去甲氯胺酮(NK)外,其余11种目标物均有检出,质量浓度范围为n.d.~43.2 ng·L~(-1)。其中麻黄碱(EPH)的检出率和中间浓度最高,分别为100%和11.0 ng·L~(-1);其次为甲基苯丙胺(METH),检出频率为58%,浓度中值为1.0 ng·L~(-1);苯丙胺(AMP)在东部湖区均未检出。大部分精神活性物质浓度水平较高的河流分布在竺山湾和西太湖,而海洛因(HR)的高值区主要在南太湖。运用风险熵方法对其进行风险评估,结果显示,太湖流域地表水中检出的13种精神活性物质的风险熵值均<0.1,生态风险较低,但其对水生生态系统的长期和综合风险值得关注。 相似文献
923.
Yanxiu Guo Chaoyun Wang Xingren Pan Xiaofei Dong Wansong Zong 《Journal of environmental science and health. Part. B》2020,55(3):230-238
AbstractCiprofloxacin (CPFX) and enrofloxacin (ENFX), two of the most widely used fluoroquinolones (FQs), pose a great threat to humans and the ecosystem. In this study, the toxic mechanisms between the two FQs and trypsin were evaluated by means of multiple spectroscopic methods, as well as molecular docking. During the fluorescence investigations, both FQs quenched the intrinsic fluorescence of trypsin effectively, which was due to the formation of moderately strong complexes (mainly through van der Waals forces and hydrogen bonds). The binding of two FQs not only caused the conformational and micro-environmental changes of trypsin, but also changed its molecular activity; shown by the UV–Visible absorption spectroscopy, synchronous fluorescence spectroscopy, and functional tests. The established methods in this work can help to comprehensively understand the transport of FQs in the human body. 相似文献
924.
The coupling of sand with ZVI/oxidants achieved proportional and highly efficient removal of arsenic
Sana Ullah Xuejun Guo Xiaoyan Luo Xiangyuan Zhang Yameng Li Ziyu Liang 《Frontiers of Environmental Science & Engineering》2020,14(6):94
925.
926.
为了探究热脱附装置降低能耗的方法,对新疆油田某井油基岩屑热脱附处理工艺参数进行了研究。结果表明:在残渣的含油率≤2%的标准下,当加热温度、停留时间、油基岩屑固相含量这3个关键因素变量分别为350~550℃、35~55 min、60%~90%时,油基岩屑热脱附处理后残渣的含油率能达到标准要求;在以上条件下,以能耗为考核指标,通过响应曲面法研究发现,单因素变量的交互项均对能耗影响显著;将加热温度由550℃降低至430℃时,停留时间由45 min降至40 min,能耗可节约17.47%,残渣的含油率0.3%;通过调整热脱附工艺参数,可在油基岩屑热脱附处理后残渣的含油率达标的基础上,实现节能降耗。上述研究结果可为合理设置油基岩屑热脱附装置的运行工艺参数提供参考。 相似文献
927.
Baoyuan Guo Jiao Meng Xinyu Wang Chengnan Yin Weiyu Hao Baiwen Ma Zhang Tao 《Frontiers of Environmental Science & Engineering》2020,14(1):2
928.
Mi Jun Bian Jie Liu Yaru Guo Wenxia 《Environmental science and pollution research international》2020,27(30):37199-37209
Environmental Science and Pollution Research - The aim of this study was to explore the enterprises in the mining area, in the face of environmental pollution, to use relationship embedding to... 相似文献
929.
Guo ChengJun Xu YaLan Tian Zhong 《Environmental science and pollution research international》2020,27(30):37333-37346
Environmental Science and Pollution Research - Human civilization has reached an unprecedented height, but the industrialization of economic development also brings global warming, ozone depletion,... 相似文献
930.
The extensive reclamation of marshland into cropland has tremendously impacted the ecological environment of the Sanjiang Plain in northeast China. To understand the impacts of marshland reclamation and restoration on soil properties, we investigated the labile organic carbon fractions and the soil enzyme activities in an undisturbed marshland, a cultivated marshland and three marshlands that had been restored for 3, 6 and 12?years. Soil samples collected from the different management systems at a depth of 0-20?cm in July 2009 were analyzed for soil organic carbon (SOC), dissolved organic carbon (DOC), microbial biomass carbon (MBC) and easily degradable organic carbon. In addition, the activities of the invertase, β-glucosidase, urease and acid phosphatase were determined. These enzymes are involved in C, N and P cycling, respectively. Long-term cultivation resulted in decreased SOC, DOC, MBC, microbial quotient and C (invertase, β-glucosidase) and N-transforming (urease) enzyme activities compared with undisturbed marshland. After marshland restoration, the MBC and DOC concentrations and the soil invertase, β-glucosidase and urease activities increased. Soil DOC and MBC concentrations are probably the main factors responsible for the different invertase, β-glucosidase and urease activities. In addition, marshland restoration caused a significant increase in the microbial quotient, which reflects enhanced efficiency of organic substrate use by microbial biomass. Our observations demonstrated that soil quality recovered following marshland restoration. DOC, MBC and invertase, β-glucosidase and urease activities were sensitive for discriminating soil ecosystems under the different types of land use. Thus, these parameters should be considered to be indicators for detecting changes in soil quality and environmental impacts in marshlands. 相似文献