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The sorption process of selected non-steroidal anti-inflammatory drugs (ibuprofen, naproxen, ketoprofen, diclofenac) on biofilm covered river sediments were investigated in laboratory. In the course of the experiments, the effect of pH of aqueous phase, the effect of TOC (total organic carbon) content of biofilm on the sorption processes were studied. The determination of concentration of drugs was performed by gas chromatography mass spectrometry (GC-MS) both in liquid and solid phases. The pseudo-first-order rate constant of the sorption was found to be 83 min(-1). The effect of pH on the sorption of diclofenac was significantly lower than the obtained values in case of the other three drugs. The calculated K(d) (sorption coefficient) values increased in the sequence of ibuprofen, naproxen, ketoprofen and diclofenac and varied between 0.1-0.4; 0.2-0.7; 0.2-1.2; 0.2-1.4 kg L(-1) respectively, depending on the characteristics of the sediments. The value of K(d)×f(oc) showed a straight line as function of f(oc) (fraction of organic carbon) therefore, instead of the widely distributed normalization process (K(d)/f(oc)), an empirical equation (K(d)=A/f(oc)+B) was suggested for estimation of the K(d) values in case of different TOC content sediments. 相似文献
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Abstract The effect of sulfonylurea (SU) acetolactate synthases (ALS) inhibitors (chlorsulfuron and triasulfuron) and their 13 guanidine and 7 azole derivatives was studied on 17 fungal and 21 plant species. The efficacy of chlorsulfuron and triasulfuron against Fusarium oxysporum and Thielaviopsis basicola was higher than carbendazim. Two azole derivatives were highly selective for maize. The antifungal activity spectrum of both guanidine and azole derivatives differed from that of chlorsulfuron and triasulfuron, and did not exert notable antifungal activity in vitro. However, they had significant anti‐Fusarium efficacy on rye that surpassed that of carbendazim. 相似文献
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Janis Hajimichael Gyula Horváth László Pap Sándor Botár István Székely 《Journal of environmental science and health. Part. B》2013,48(3):515-519
Abstract SZI‐121, a tetrazine type acaricide, has been improved by Chinoin. The compound is very active against phytophagous mites and has good toxicological and environmental properties. The chemical structure was designed to get improvements in mode of action and efficacy simultaneously. SZI‐121 acts not only as a contact ovicide but due to very good translaminar activity it can enter mites via ingestion. SZI‐121 possesses transovarian activity and it also able to stop the development of mites at chrysalis stages. 相似文献
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The growth inhibitory effect of 30 synthetic dyes on 22 bacteria (test organisms) belonging to various taxonomic groups was determined. The strength (potency) and selectivity of the biological effect were separated by the spectral mapping technique, reducing the dimensionality of the selectivity maps to two by the nonlinear mapping technique. The relationship between biological effect and physicochemical parameters of dyes was elucidated by stepwise regression analysis. It has been established that the strength of the effect of anthracene and trityl derivatives was higher than that of azobenzene dyes and significantly depended on the hydrophobicity of the compound. The selectivity of the effect also depended on hydrophobicity and on the nonpolar unsaturated surface area of the dyes. Gram negative and Gram positive bacteria differed in the strength and selectivity of their response to dyes indicating the marked impact of the taxonomical position on the response. Contrary to other multivariate mathematical statistical methods biological activity may be divided by SPM into potency and selectivity values, therefore, application of the technique in future QSAR studies is highly recommended. 相似文献
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A type of organizational reward system based on personal power is described and partially tested. The theory, developed from observations of Hungarian organizations, is grounded in theories of procedural justice and learned helplessness. Person-based organizational reward systems are characterized by highly valued rewards combined with personalistic criteria for reward distribution. Such organizational reward systems were hypothesized to lead to employee perceptions of organizational unfairness; negative evaluations of others; anxiety; and perceptions of self, collegial and organizational inefficacy. These hypotheses were supported in tests in a sample of three Hungarian state-owned organizations classified as having person-based systems and five non-person-based organizations (two Hungarian privately-owned companies, one American state-owned and two American privately-owned organizations). In addition, several behavioral effects of person-based reward systems were proposed: they foster bargaining behavior, withholding of information, avoidance of collaborative tasks, ingratiation and noncompliance with rules. 相似文献
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