Sorption kinetic characteristics of polybrominated diphenyl ethers on natural soils

Sorption kinetic characteristics of BDE-28 and BDE-47 on five natural soils with different organic carbon fractions were investigated, and could be satisfactorily described by a two (fast and slow)-compartment first-order model with the ratio of rate constants ranged from 9 to 94 times. The fast compartment made a dominant contribution (71% ∼ 94%) to the total sorption amount in the whole process, and accounted for over 90% of the increase in the total sorption amount at initial 5 h. The influence of the slow compartment on the increase in the total sorption amount became principal (above 90%) in the subsequent stage approximately from 9 h or 25 h to the apparent equilibrium at 265 h. The results proposed the different sorption behaviors of the mathematically classified compartments for BDE-28 and BDE-47, which may correspond to the different soil components, such as soil organic fractions with amorphous and condensed structures, respectively.     

改性CMC聚合物吸附酸法地浸废水中的铀

在温度为70～80℃、单体质量浓度为30%～35%、羧甲基纤维素∶丙烯酸(质量比)为10∶2.5、反应时间为3.5～4 h条件下对CMC进行改性,接枝率可达68%以上。以改性前后的CMC为吸附剂,对模拟酸法地浸含铀废水进行了对比吸附实验研究。结果表明:改性CMC对铀吸附效果最佳的实验条件为:改性CMC质量浓度为0.10 g/L,温度为25℃,pH为5.0,吸附时间100 min,此时铀去除率达到了97.1%,比CMC改性后对铀的吸附率平均提高了近21%。影响吸附效果程度由强到弱的顺序为:改性CMC投加量、pH、吸附时间、温度。     

土壤对铜和镉的静态吸附研究

通过静态吸附实验研究了德兴矿区大坞河下游下沽口土壤对铜和镉的吸附特点并采用Freundlich等温吸附方程进行拟合,探讨了pH值变化对铜和镉在土壤样品中分配系数的影响。结果表明：土壤铜和镉的吸附特性均符合Freundlich等温吸附方程,得到的金属铜和镉的Kf值分别为354．08、34．132;随着pH值的升高,铜和镉在土壤中的分配系数逐步增大,随后降低,pH值与分配系数关系曲线为单峰曲线。     

耐冷菌在低温下处理污水的研究进展

低温污水的生物处理一直是水处理领域的难点和热点,由于耐冷菌对温度的适应范围较宽,且在低温下仍然保持较高的代谢活性,因此在污水处理和污染环境生物修复领域中的应用逐渐受到重视。本文介绍了耐冷菌在环境中的分布、主要种类以及适冷机理,概述了耐冷菌在工业废水和生活污水处理中的主要研究进展。指出应进一步开发环境中耐冷菌菌种资源,揭示耐冷菌的冷适应特性和功能表达之间的关系,加强耐冷菌在水体修复与净化领域的理论和应用研究,从而为我国北方尤其是东北地区的水环境保护提供行之有效的新途径。     

The role of doped-Mn on enhancing arsenic removal by MgAl-LDHs

To meet the challenges posed by global arsenic water contamination, the MgAlMn-LDHs with extraordinary efficiency of arsenate removal was developed. In order to clarify the enhancement effect of the doped-Mn on the arsenate removal performance of the LDHs, the cluster models of the MgAlMn-LDHs and MgAl-LDHs were established and calculated by using density functional theory (DFT). The results shown that the doped-Mn can significantly change the electronic structure of the LDHs and improve its chemical activity. Compared with the MgAl-LDHs that without the doped-Mn, the HOMO-LUMO gap was smaller after doping. In addition, the -OH and Al on the laminates were also activated to improve the adsorption property of the LDHs. Besides, the doped-Mn existed as a novel active site. On the other hand, the MgAlMn-LDHs with the doped-Mn, the increased of the binding energy, as well as the decreased of the ion exchange energy of interlayer Cl⁻, making the ability to arsenate removal had been considerably elevated than the MgAl-LDHs. Furthermore, there is an obvious coordination covalent bond between arsenate and the laminates of the MgAlMn-LDHs that with the doped-Mn.     

农垦北安局农业生态经济系统能值分析及可持续发展对策

文章运用能值理论分析方法,对黑龙江省农垦北安局2001年-2008年农业生态经济系统发展现状进行研究分析。研究结果表明,系统能值投入和产出呈逐年增长的趋势,能值自给率、人口承载力和净能值产出率呈下降趋势,能值投资率、人均能值使用量和能值密度呈增加态势,环境压力逐年增加。根据能值指标分析结果和经济发展现状,提出农业生态系统可持续发展对策。     

清洁生产审核中基于资源、能源审核重点的评估方法

清洁生产审核是节能减排战略实施的重要手段,通常清洁生产审核一般分为七个阶段,35个步骤。其中评估阶段是对组织审核重点的原材料消耗、生产过程以及资源浪费的产生进行审核。当前进行的清洁生产审核工作重点关注的是污染物排放,对于能源节约方面的评估尚不多见。文章以资源、能源为审核重点,结合案例对评估阶段中采用的数据分析方法和资源、能源E—P图的绘制和分析进行了探讨,并从八个方面讨论了如何来查找造成资源、能源浪费的原因。     

广州轨道交通三号线高速行驶条件下对安全限界的影响研究

给出了轨道交通车辆横向偏移量的计算方法 ,并应用列车 -线路动力耦合模型 ,分析了广州地铁三号线的安全限界变化问题。确定了当前按 80km/h行车速度设计的建筑限界能满足 13 0km/h行车速度的要求 ,限界尺寸不需改动可保证列车运行安全平稳     

铁路集装箱空箱安全高效调拨的计算机算法

铁路集装箱安全运输的重要内容是确保集装箱运输的连续性 ,而集装箱空箱的高效率、低成本的调拨是铁路集装箱运输连续性的重要前提。为此 ,笔者提出了一种解决铁路路网上集装箱空箱调拨问题的计算机算法 ,该算法将此类问题视为一种特定的运输问题去求解 ,其目标是使得调拨集装箱的运输费用 (箱·公里 )最小 ,费用系数是两个相关站点的最短运输距离 ,并给出集装箱调拨的算例 ,实例证明了该算法是富有效率且可行性好 ,能够满足铁路集装箱运输的高效、快速、便捷运输要求。     

我国农业自然灾害与农业政策性保险

在详细分析了我国当前主要农业自然灾害情况的基础上,探讨了通过建立农业政策性保险来应对自然灾害风险的必要性以及我国农业保险目前面临的问题,提出了加大政府支持力度、加快农业保险立法、提高保险意识、加强保险人才培养等方面的政策建议。