Monitoring toxics by group testing

Monitoring the environment for a large list of organic compounds present at low levels is costly. The primary purpose of such monitoring is to assure that hazardous levels of such compounds are not released into, or present in, the environment. Viewing this as a quality control problem, we suggest that samples from different sources can be composited using group testing procedures prior to analysis. Our purpose is to describe the basic concepts and suggest problems requiring study.     

LONG-TERM RECONSTRUCTION OF WATER LEVEL CHANGES FOR LAKE ATHABASCA BY ANALYSIS OF TREE RINGS1

ABSTRACT: The fact that dendrochronology can be a useful tool in water resources management is demonstrated by a study of past changes in lake levels. The study was necessitated by the recent (1967) closure of the gates on the W.A.C. Bennett Dam on the Peace River in British Columbia, causing a drop in water levels of Lake Athabasca, the lake levels control water level undulations in a series of smaller lakes which lie in the 1.5 million acre delta area along its western edge in Alberta. The W.A.C. Bennett Dam has by its regulation of the Peace River affected the river's historical role of creating a hydraulic dam during early summer flood stages thereby preventing outflow from Lake Athabasca and inducing annual inundation of the delta area. Because the ecololgy of the lake and adjacent delta region has depended on the now attenuated snow-melt flooding from the Upper Peace River Basin, it became necessary to consider some means of artificially inducing this annual inundation. It was not known, however, what the long-term water level changes were around which the present ecology had developed. Continuous historical lake level records exist only for the period 1935–1967. Was this period one of anomalously high or low water levels? Relatively old white spruce trees growing along natural levees of the channels in the delta region were found to contain tree-ring records that reflected the water stages in the channels. Because the water levels in the channels could be correlated with lake levels, it was possible to use the three-ring series to extend the known 33-year record of lake level changes to 158 years. By using canonical analysis and 10-day mean lake levels for three different subperiods in the 33-year period of calibration, along with tree-ring series from appropriately chosen stands of white spruce, reconstructions were made of the long-term record for late May, early July, and late September. The reconstructed record shows that the May 21–30 lake levels have been three times as variable in the past as in the period of historical record (1935–1967), the July 11–20 levels twice as variable, and the September 21–30 levels 10% less variable. However, the mean water level for each of the three subperiods for the long-term record is very close to the means for the period of historical record. The reconstructed record shows that, before the dam gates were closed, there was only one three-year period (1866–1868) in which the lake levels were as low as they have been since closure of the gates (that is, 1967–1970). (Levels were nearly as low, however, during the period 1942–1945.     

Modeling the annual thermal regime of lake Ohrid,Yugoslavia, using daily weather data

The time-dependent characteristics of the five weather variables which control the annual thermal response of Lake Ohrid are analyzed in detail. These are daily values for solar radiation, air temperature, humidity, wind speed and cloud cover. A simple numerical model of the lake's thermal response, forced by thermally driven density mixing, is developed and tested using observed thermal profiles for verification. The numerical model successfully reproduces the major features of the lake's thermal regime over a 6 y period from 1972 to 1977, the average root mean square value for the simulated profiles being 1.2°C with extremes of 2.2 and 0.3°C and a standard deviation of 0.4°C.     

Radium removal from mine waters in underground treatment installations

The underground mining of hard coal is widespread in the Upper Silesian Coal Basin (southern Poland). In deep mines, inflows of highly mineralised waters containing radium isotopes are numerous. These waters cause severe damage to the natural environment due to the salinity, but additionally radioactive pollution occurs. The region is densely populated, therefore mitigation methods are very important. The method of radium removal has been applied in full technical scale in two coal mines with very good results - in one of the mines radium-bearing waters are treated at the rate of approximately 0.1m(3)s(-1), while in another mine salty waters are purified at the rate of 0.1m(3)s(-1). The purification takes place in special underground galleries without any contact of the mining crew with the radioactive deposits produced during the process. As a result, release of radium is significantly lower, more than 200MBq of (226)Ra and (228)Ra remains underground each day.     

Air Quality Criteria for the Effects of Fluorides On Man

Minute traces of fluoride are found in the air of rural communities and of cities, having been contributed perhaps from volcanic effluvia, perhaps from burning coal, and perhaps from industrial sources. Atmospheres of urban areas of the U. S. have been found to contain from less than 0.2 μg F/m³ to as much as 1.9/μg F/m³. Fluorides released from industrial processes may release elemental fluorine, soluble gaseous fluorides, and soluble or insoluble fluoride dusts. At least in some instances inhaled fluoride from fluoride containing dusts has proven to be as biologically available as that from similar concentrations of inhaled HF. Measurement of the amount of fluoride excreted in the urine has proven to be a valuable index of exposure and a means of preventing cumulative injury. Average urinary F concentrations not exceeding 5 mg/liter, which corresponds approximately to a daily intake of 5 mg, are not associated with osteosclerosis in such workmen, and such changes are unlikely at daily intakes of 5 – 8 mg F. The amount of fluoride which is retained by an individual inhaling air containing 2.5 mg of fluoride dusts per m³ (the current TLV) is approximately 5-6 mg. A review of the literature describing the exposure of work forces to fluorides in industrial atmospheres indicates that concentrations have ranged from a fraction of a milligram/m³ to values mostly less than 10 mg/ml Surveys of populations living near installations emitting fluoride fumes or dusts indicate that, with few exceptions, the health of these persons has not been adversely affected. Many species of vegetation are far more susceptible to the effects of fluoride than is man, hence an air quality standard to protect vegetation will be far lower than those encountered in the factory, and can be expected to be of the order of 10 ppb or less. The probable daily intake of F at this level of exposure is 0.16 mg, an intake far below that required for the production of clear-cut effects in the human. Thus, air quality standards set to protect vegetation would contribute negligible quantities of F in terms of any possible adverse effect on human health, and would give a wide margin of protection for man.     

Dynamics of pheromone production and communication in the mountain pine beetle, Dendroctonus ponderosae Hopkins, and the pine engraver, Ips pini (Say) (Coleoptera: Scolytidae)

Summary. The mountain pine beetle, Dendroctonus ponderosae Hopkins, and the pine engraver, Ips pini (Say), often co-exist in lodgepole pine, Pinus contorta var. latifolia Engelmann. Intra- and interspecific semiochemical communication occurs in both species and their complete semiochemical repertoire and precise dynamics of pheromone production have not been elucidated. Porapak-Q extracts of captured volatiles from beetles of each species aerated at different attack phases (freshly emerged, pioneer sex alone in the log and both sexes paired in new galleries), followed by gas chromatographic-electroantennographic detection (GC-EAD) and GC-mass spectroscopic analyses identified 17 compounds (seven compounds common to both species, six present in D. ponderosae and four present in I. pini) that excited the antennae of either or both species. Seven compounds for D. ponderosae and nine for I. pini had not been assessed for behavioural activity. In field trapping experiments, 2-phenylethanol produced by both species inhibited the response of D. ponderosae to its aggregation pheromones. exo- and endo-Brevicomin produced by D. ponderosae significantly decreased the response of I. pini to its aggregation pheromone ipsdienol. Nonanal, a ubiquitous compound found in the volatiles of lodgepole pine, various nonhosts and in both beetle species deterred the response of I. pini to ipsdienol. The occurrence of cis-verbenol, trans-verbenol and verbenone in emergent I. pini, and verbenone and 2-phenylethanol in emergent D. ponderosae suggests that these compounds may inhibit aggregation and induce dispersal following emergence. Termination of aggregation in D. ponderosae appears to depend on the production of frontalin in combination with changes in the relative ratios of verbenone, exo-brevicomin, trans-verbenol and 2-phenylethanol. In I. pini, the cessation of ipsdienol production by males is probably the main factor in terminating aggregation. Received 16 November 1999; accepted 7 August 2000