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21.
Jun Shishido Keiko Yoshii Yoshihiro Takubo Yoshiaki Okamoto Takeshi Yamamoto Yoshiko Kato Kazuhito Watabe Masaomi Kondo 《Chemosphere》1984,13(2):331-338
A three dimensional mass chromatography (TDMC), which is the extended method of mass chromatography, has been developed for the analysis of environmental chemicals. A considerable performance was suggested by the combination of TDMC to gas chromatography-mass spectrometry-computer system. 相似文献
22.
Hajime Yasuda Osamu Yamada Mamoru Kaiho Hideki Nakagome 《Journal of Material Cycles and Waste Management》2014,16(1):151-155
Hydrogasification of a coal/polyethylene mixture was carried out using a low concentration of polyethylene in the samples with the aim of industrial application. Coal/polyethylene mixtures in the ratio of 90:10 and 75:25 were used in this study. A hydrogasification experiment was conducted using a unique batch reactor at 1073 K under a 7.1 MPa hydrogen atmosphere. The reaction time varied from 1 to 80 s. The results revealed a methane yield from the mixtures that was noticeably greater than the values calculated from experimental results obtained from coal and polyethylene respectively, assuming no mutual influences. A significant synergistic effect was observed even when the polyethylene content was as low as 10 %. It is suggested that there might be an advantage in hydrogasification processes if waste plastics are mixed with coal, such content being practically assumed. 相似文献
23.
Zhenzi Jing Xinwei Fan Lei Zhou Junjie Fan Yi Zhang Xiaohui Pan Emile Hideki Ishida 《Waste management (New York, N.Y.)》2013,33(5):1182-1189
Municipal solid waste incineration (MSWI) bottom ash could be solidified with and without slaked lime (calcium hydroxide) addition by a hydrothermal method under steam pressure of 1.56 MPa at 200 °C for up to 72 h. Experimental results showed that CSH gel or tobermorite exerted a main influence on strength development, and without any additives CSH gel was easy to form, while slaked lime addition favored to form tobermorite. Tobermorite seemed to exert a larger effect on the strength development than CSH gel. Leaching results showed that the concentrations of heavy metals dissolved from the solidified specimens were effectively reduced after hydrothermal processing. The immobilization was mainly due to the tobermorite or CSH gel formation, and Pb2+ and Zn2+ seemed to be fixed more readily than Cr6+, which might be the reason that the structural Ca2+ within tobermorite or CSH gel was exchanged by Pb2+ and Zn2+ more easily than Cr6+. In addition, there existed a close relationship between leaching concentration and strength enhancement, and a higher strength seemed to exert a larger effect on immobilization of heavy metals. 相似文献
24.
25.
Oshita K Takaoka M Nakajima Y Morisawa S Kanda H Makino H Takeda N 《Water environment research》2012,84(2):120-127
In this study, a method for removing water from biosolids that uses dimethyl ether (DME) as an extractant was considered. This study evaluates the applicability of the DME dewatering method to biosolid cakes by using a DME flow-type experimental apparatus. It was found that a high dewatering ratio is clearly achieved by increasing the liquefied DME/biosolid ratio and lowering the liquefied DME linear velocity. As the liquefied DME/biosolid ratio was increased, the carbon content in dewatered biosolid showed a slight decrease and the TOC concentration in separated liquid increased significantly. Finally, the input energy Es to remove 1 kg of water from the biosolid cake, using both the DME dewatering method and the conventional drying method was estimated. The calculation shows that Es for the DME dewatering process is approximately a third of Es for the conventional thermal drying process. 相似文献
26.
Akata N Kakiuchi H Shima N Iyogi T Momoshima N Hisamatsu S 《Journal of environmental radioactivity》2011,102(9):837-842
This study aimed at obtaining background tritium concentrations in precipitation and air at Rokkasho where the first commercial spent nuclear fuel reprocessing plant in Japan has been under construction. Tritium concentration in monthly precipitation during fiscal years 2001-2005 had a seasonal variation pattern which was high in spring and low in summer. The tritium concentration was higher than that observed at Chiba City as a whole. The seasonal peak concentration at Rokkasho was generally higher than that at Chiba City, while the baseline concentrations of both were similar. The reason for the difference may be the effect of air mass from the Asian continent which is considered to have high tritium concentration. Atmospheric tritium was operationally separated into HTO, HT and hydrocarbon (CH3T) fractions, and the samples collected every 3 d-14 d during fiscal year 2005 were analyzed for these fractions. The HTO concentration as radioactivity in water correlated well with that in the precipitation samples. The HT concentration was the highest among the chemical forms analyzed, followed by the HTO and CH3T concentrations. The HT and CH3T concentrations did not have clear seasonal variation patterns. The HT concentration followed the decline previously reported by Mason and Östlund with an apparent half-life of 4.8 y. The apparent and environmental half-lives of CH3T were estimated as 9.2 y and 36.5 y, respectively, by combining the present data with literature data. The Intergovernmental Panel on Climate Change used the atmospheric lifetime of 12 y for CH4 to estimate global warming in its 2007 report. The longer environmental half-life of CH3T suggested its supply from other sources than past nuclear weapon testing in the atmosphere. 相似文献
27.
Qingrong Qian Motoi Machida Masami Aikawa Hideki Tatsumoto 《Journal of Material Cycles and Waste Management》2008,10(1):53-61
Activated carbons were prepared from cattle manure compost (CMC) by ZnCl2 activation with various ZnCl2/CMC mass ratios. Based on the N2 adsorption-desorption isotherms, mathematical models including the Dubinin-Radushkevich (DR) equation, the αs plot, and the Horvath-Kawazoe method were used to analyze the pore structural characteristics of the prepared activated carbons.
It was found that for carbons possessing both micro-and mesopores, the DR method provided a more accurate estimation than
the αs method for the extent of microporosity. The effect of the ZnCl2 impregnation ratio on the pore structure was discussed using the DR method. The results revealed that pore evolution involved
three distinct regions with increases in the amount of impregnated ZnCl2: raising the ZnCl2/CMC mass ratio from 0.00 to 0.50 resulted in a 19-fold increase in micropore volume (Vme
D) but caused no change in the mesopore volume (Vme
D); increasing the ZnCl2/CMC mass ratio from 0.50 to 1.00 led to an increment in Vmi
D of about 50% and in Vme
D of 170%; while raising the ratio from 1.50 to 2.50 caused a slight decrease in Vmi
D but a 200% increment in the value of Vme
D. 相似文献
28.
Katsuhiro Okamoto Norimichi Watanabe Yasuaki Hagimoto Koji Miwa Hideo Ohtani 《Journal of Loss Prevention in the Process Industries》2010,23(1):89-97
Evaporation rate of multi-component liquid such as motor gasoline is expected to change greatly with progress of evaporation because its composition changes. Therefore it is difficult to predict accurately amount of generated combustible vapor in the case that a multi-component liquid is spilt on a floor. Then, we assumed an evaporation model that composition of the vapor obeys the Raoult's law which considers the activity coefficient. Using the model, we calculated the vapor composition, the vapor pressure and the evaporation rate of the liquid. Then, comparison was done between the calculated values and the measured values obtained in this study. “Weight loss fraction” was used as a parameter signifying the progress of evaporation. The variations of the evaporation property were accurately predicted by the model. We derived a prediction model of the amount of generated combustible vapor from the relation between weight loss fraction and evaporation rate. It was found that the amount of generated vapor was expressed as a logarithmic function of time in case of a five-component liquid. Furthermore, we showed that the predicted flash point of a liquid using the composition obtained from the model was in good agreement with an experimental result. 相似文献
29.
30.
黑龙江省公路雪冰基本特征与灾害防治对策 总被引:4,自引:2,他引:2
黑龙江省冬季降雪不多,但在寒冷和强风条件下,容易产生风吹雪,使某些地点形成较深的积雪,阻塞交通.风吹堆积下的积雪在低温下形成密实坚硬的硬深霜.涎流冰是冬季影响山区交通的另一个主要因素,它的各个部位呈现出间歇性增厚的特征,是涌出水在各处反复交替流动、冻结的结果.随着经济发展,交通流量增加,正常降雪将会产生越来越大的影响和危害,必须给予足够的重视.因此,在雪冰减灾战略对策上,应逐步推广使用防滑汽车轮胎,建立较为完善的公路雪冰清除服务体系,并辅以必要的工程措施. 相似文献