汉江上游郧县曲远河河口段全新世古洪水水文状态研究

对汉江上游河谷郧县曲远河河口剖面进行了沉积学、粒度、磁化率和烧失量的研究。结果表明：夹在古土壤中的灰白色沉积层是典型的古洪水滞流沉积物,记录了一次特大洪水事件,用地层对比法和OSL方法确定其发生时间为4 950~5 450 a B.P.。用古洪水SWD尖灭点法确定古洪水行洪水位高程为169 m,采用比降法恢复其洪峰流量为60 577 m3/s。根据2011年汉江上游洪水洪痕,用相同的方法对洪峰流量进行了反演,误差为-411％,说明用比降法恢复的古洪水洪峰流量是可靠的     

An Experimental Study on the Treating River Sewage with New Bioreactor

A new bioreactor on the basis of a dynamic fluidized bed was designed, which combines advantages of the fluidized bed and a biological contactor. The experiments of start up, normal operation and parameter adjustment are carried out. The results show that the bioreactor can be quickly started up in the condition that the fill is 50%, the hydraulic retention time is 72 min, aerate speed is 2.5 m3/h, rotation-cage rotated speed is 1.5 r/min, and the removal rates of chemical oxygen demand （CODcr） and Ammonia nitrogen （NH3-N） are 75.34% and 80.98% respectively. The influence of the operation parameter on removal rates of the bioreactor is analyzed, and an appropriate operation parameter is provided.     

Polybrominated diphenyl ether in the East Asian environment: a critical review

Polybrominated diphenyl ethers (PBDEs) have been extensively used as flame retardants in consumer goods. Sufficient evidence shows that PBDEs have been rapidly accumulating in the environment worldwide. In Asia, deca-bromodiphenyl ether has been produced and used in large quantities, while penta-BDE has largely ceased in the mid-1990s. This paper summarizes and critically reviews the status of PBDE pollution in East Asia, with emphases on the comparisons with Europe and North America and the interpretation of the differences. In general, the concentrations of PBDEs in atmosphere, sludge, human and biological samples of East Asia are comparable to or lower than those in Europe and North America. However, in the sediments of waters near densely populated and heavily industrialized areas, PBDE levels are among the highest ever reported in the literature. In Japan and China, concentrations of PBDEs in sediment cores showed an increasing trend for the past 20-30 years. Also, PBDEs levels in human breast milk in Japan increased about 10-fold in the past 20 years. The presence of PBDEs in fur seal has increased about 150-fold in 1994 than that in 1972. Regional and inter-continental transport cannot be confirmed due to insufficient information. However, the detection of a number of PBDE congeners in a pristine lake on the Qinghai-Tibet Plateau may be an evidence of their long-range transport.     

On Index System and Quantitative Assessment of Eco-cities： A Case Study on Urban Agglomeration of the Yangtze Delta

Urban agglomeration of the Yangtze Delta （UAYD）, one of the most developed regions of China, has witnessed an increasing prevalence in building ecological cities when the ecological cities are pursued by many modem cities, and great achievements have been made in this regard. It is inevitable, however, that certain problems exist during the construction of ecological city, which include but not limited to non-harmonious development of urban complex ecosystem, and the difficulty in quantifying eco-city construction or incomplete quantification in assessing the construction of present and future eco-city. Based on the analysis on social-economic conditions and regional conditions of the UAYD, this paper attempts to set up an index system of eco-cities combining with local characteristics, and to adopt the indices of eco-city, urban harmony, and eco-city colligate to evaluate the ecological level, urban harmonious development and eco-city construction of cities within the UAYD. Results indicate that among 15 cities in UAYD, Suzhou City ranks the highest in terms of eco-city construction, whereas Nantong ranks relatively lower; sustainable eco-city construction is possible only when cities are developed in every respect of harmony.     

自然资源、技术进步与环境库兹涅茨曲线

不可再生自然资源的约束和环境质量的不断恶化是经济可持续发展必须要面对的挑战。就环境问题而言,现实中一个特征事实是,在不同的收入水平下人们对环境质量的需求不同,只有当收入达到一定水平之后,人们才会注重生活质量的改善。基于现有研究,在考虑非再生自然资源的约束条件下,本研究将环境质量作为生产要素的一部分引入最优增长理论的分析框架,探讨了在环境污染和自然资源双重约束下的长期经济增长问题。在非再生自然资源和环境污染的双重约束下,本研究表明解决环境问题必须要采用的手段是促使技术进步的创新研发,因为技术进步是环境库兹涅茨曲线出现拐点的不可或缺的一个必要条件。在市场竞争的环境下,由于知识的非竞争性质使得研究部门的研究是次优的。因此,政府应当通过适当的财政政策和法制安排以激励私人投资者研究与开发新技术的积极性。     

促进江湖联系的闸口调度对策及影响区管理机制

我国传统的修堤建闸、抵御洪水的治河理念,阻断了江湖联系,造成湿地的生态萎缩。为改善湿地的生态环境,保护湿地的生物多样性,提出了新的多目标闸口调度机制,替代传统的、以防洪抗旱为目的的调度机制,力求促进江湖联系,增加湿地活力;为保障该机制的运行和实施,提出了闸口调度影响区的管理办法;并以涨渡湖为例进行了讨论。     

Identification of close relationship between atmospheric oxidation and ozone formation regimes in a photochemically active region

Understanding ozone (O₃) formation regime is a prerequisite in formulating an effective O₃ pollution control strategy. Photochemical indicator is a simple and direct method in identifying O₃ formation regimes. Most used indicators are derived from observations, whereas the role of atmospheric oxidation is not in consideration, which is the core driver of O₃ formation. Thus, it may impact accuracy in signaling O₃ formation regimes. In this study, an advanced three-dimensional numerical modeling system was used to investigate the relationship between atmospheric oxidation and O₃ formation regimes during a long-lasting O₃ exceedance event in September 2017 over the Pearl River Delta (PRD) of China. We discovered a clear relationship between atmospheric oxidative capacity and O₃ formation regime. Over eastern PRD, O₃ formation was mainly in a NO_x-limited regime when HO₂/OH ratio was higher than 11, while in a VOC-limited regime when the ratio was lower than 9.5. Over central and western PRD, an HO₂/OH ratio higher than 5 and lower than 2 was indicative of NO_x-limited and VOC-limited regime, respectively. Physical contribution, including horizontal transport and vertical transport, may pose uncertainties on the indication of O₃ formation regime by HO₂/OH ratio. In comparison with other commonly used photochemical indicators, HO₂/OH ratio had the best performance in differentiating O₃ formation regimes. This study highlighted the necessities in using an atmospheric oxidative capacity-based indicator to infer O₃ formation regime, and underscored the importance of characterizing behaviors of radicals to gain insight in atmospheric processes leading to O₃ pollution over a photochemically active region.     

Phosphorus recovery from biogas fermentation liquid by Ca–Mg loaded biochar

Shortage in phosphorus (P) resources and P wastewater pollution is considered as a serious problem worldwide. The application of modified biochar for P recovery from wastewater and reuse of recovered P as agricultural fertilizer is a preferred process. This work aims to develop a calcium and magnesium loaded biochar (Ca–Mg/biochar) application for P recovery from biogas fermentation liquid. The physico-chemical characterization, adsorption efficiency, adsorption selectivity, and postsorption availability of Ca-Mg/biochar were investigated. The synthesized Ca–Mg/biochar was rich in organic functional groups and in CaO and MgO nanoparticles. With the increase in synthesis temperature, the yield decreased, C content increased, H content decreased, N content remained the same basically, and BET surface area increased. The P adsorption of Ca–Mg/biochar could be accelerated by nano-CaO and nano-MgO particles and reached equilibrium after 360 min. The process was endothermic, spontaneous, and showed an increase in the disorder of the solid–liquid interface. Moreover, it could be fitted by the Freundlich model. The maximum P adsorption amounts were 294.22, 315.33, and 326.63 mg/g. The P adsorption selectivity of Ca–Mg/biochar could not be significantly influenced by the typical pH level of biogas fermentation liquid. The nano-CaO and nano-MgO particles of Ca–Mg/biochar could reduce the negative interaction effects of coexisting ions. The P releasing amounts of postsorption Ca–Mg/biochar were in the order of Ca–Mg/B600 > Ca–Mg/B450 > Ca–Mg/B300. Results revealed that postsorption Ca–Mg/biochar can continually release P and is more suitable for an acid environment.     

东莞石马河流域水化学特征时空差异及来源辨析

石马河流域对东江饮用水源地城镇供水具有重要战略意义.为研究石马河水化学特征,分别于2012年2月、6月和11月采集石马河河水水样共39个,分析测定了水体主离子(K+、Na+、Ca2+、Mg2+、Cl-、SO2-4和HCO-3)及营养盐(PO3-4、NO-3和NH+4)浓度,探讨了水化学组成的时空差异、控制因素并对其来源进行了初步辨析.结果表明,水化学组成的时空差异显著,不同时期的河水TDS及营养盐平均浓度排序为11月2月6月;河水阴离子以HCO-3为主,2月和11月时,河水阳离子以Na++K+为主,为HCO-3-Na+水,6月时则以Ca2+为主,为HCO-3-Ca2+水;营养盐浓度在空间上的差异主要受人类活动导致N、P废水排放影响,3个时期的石马河出水口处(R7)N∶P为18.4,有利于浮游植物的生长,河道出现了富营养化的现象;Gibbs图显示,2月和11月的河水主离子受蒸发岩溶解的影响较为显著,而蒸发岩和碳酸盐岩风化共同控制6月的水化学组分;海盐沉降对石马河河水物质的贡献率较小;部分Na+、Mg2+、Cl-和SO2-4来自化肥的施用和工业废水的排放;NH+4-N、PO3-4-P和NO-3-N主要分别来源于家禽养殖废水和生活废水.     

Characteristics of phosphorus chemistry and its geographical distribution in the Haihe River valley,North China

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