砒霜生产化工厂危险废物处置工程设计

通过对砒霜生产化工厂原场址废渣及污染场地调查的基础上,进行了处置方案比选及技术经济比较,确定了就地安全填埋的处置方案。根据区域性危险废物集中安全填埋场的设计经验,本工程采用先进的HDPE双层防渗的安全填埋方式,并设置了雨水分流系统、渗滤液收集系统、封场处理和填埋气体导排系统,整个场区布置合理,对周围环境的影响小,投资少,取得了良好的社会效益和环境效益,并对危险废物处理处置工程设计中应注意的问题提出了建议。     

基于工业以太网的烟粉尘在线监测系统的研究

为实现工厂矿山的烟粉尘浓度的实时在线监测,提出了在废气排放监测装置中引入工业以太网技术。以嵌入式S3C2410芯片为核心,扩展相应的外围电路,实现对废气中烟粉尘浓度等参数监测功能,集显示、信息处理、监测和通讯等功能于一体。文章给出了烟粉尘浓度的采样原理和系统的软硬件设计方案,详细给出了以太网控制芯片CS8900A与ARM硬件接口方法与软件实现方案。     

聚硅酸锌铝的制备及其性能研究

以硅酸钠、硫酸锌、硫酸铝为原料,通过共聚法制备了无机高分子絮凝剂聚硅酸锌铝（PSZAS）,研究了Na₂SiO₃的摩尔浓度、活化时间、Al/Si、Zn/Si 配比及絮凝剂的投加量对絮凝效果的影响,用X-射线衍射（XRD）和电子扫描电镜（SEM）对该絮凝剂的结构及形貌进行了表征。结果表明：当硅酸钠的浓度为0.4 mol/L,硅酸活化时间为2 h,Si∶Al∶Zn=1∶1∶1.5,絮凝剂投加量为20 mL/L废水时,絮凝剂的电中和能力和吸附架桥能力最强,絮凝剂对含H-酸染料模拟废水的絮凝效果最好。     

新型转式垃圾焚烧过程中脱氯脱硫机理的研究

为了探讨有机垃圾焚烧过程钙基添加剂对HCl,SO_x生成特性的影响,分别在自行设计的中空水冷转式垃圾焚烧炉和固定床加热炉中进行了一系列的实验,研究结果表明新型转式焚烧炉具有强化传热传质特性,能提高HCl、SO_x的脱除率,可抑制有害气体的生成;同时也研究了 HCl,SO₂气体同时存在时,钙基添加剂对脱氯脱硫效率的影响规律。     

美国对石油天然气勘探开发中废物的环境监管

石油天然气勘探开发及生产过程中会产生大量的废物,对这些废物的管理目前受到各国高度的重视。文章介绍了美国石油和天然气勘探开发中废物的监管机构、监管要求和管理实践,以期对我国油气行业勘探开发废物的环境监管有所启示。     

以人为本 开创高校工会工作新局面

认真落实科学发展观,以科学发展观统领工会工作,必须体现在党对工会工作的要求上,体现在准确全面履行好工会的职责上,从而充分发挥工会在支持改革开放、促进经济发展、推动社会进步中的积极作用。     

层次分析法在精细化工园区生态环境效益评价中的应用

介绍了杭州湾精细化工园区的概况;设计指标重要性专家打分表,依据指标得分构造了层次分析法的判断矩阵;运用层次分析法确定了精细化工园区生态环境效益评价指标体系中准则层和指标层的权重,进而依据指标权重分析r影响园区生态化改造的关键指标.结果表明,工业废水达标排放率、工业用水重复利用率、创新投入能力、染料行业单位产品新鲜水消耗量等指标是影响总目标的关键指标.     

我国资源型企业资源效率管理行为分析及政策建议

资源综合利用直接影响我国可持续发展战略的实现。我国资源型企业在资源开发利用过程中存在大量的浪费现象。运用演化博弈理论分析企业群体策略的选择和演化路径,揭示企业资源效率管理行为的内在机理。研究表明治理收益、治理成本、治理风险是企业资源保护行为系统演化的重要参数,企业群体选择策略的相对适应性取决于对方企业是否治理及企业自身治理的收益与成本,演化稳定状态不仅依赖于博弈双方的学习速度和方向,也取决于博弈双方的初始状态。政府应该根据上述机理和资源型企业现实状况,制定相应的政策。     

Sources and seasonal variation of PAHs in the sediments of drinking water reservoirs in Hong Kong and the Dongjiang River (China)

The main objective of this study was to investigate occurrence of polycyclic aromatic hydrocarbons (PAHs) in the sources of the drinking water supply of Hong Kong. The main emphasis was on the Dongjiang River in mainland China which is the major source, supplying 80% of the total consumption in Hong Kong (the remaining 20% is obtained from rain water). Sediments were collected from four sites along the Dongjiang River and four reservoirs in Hong Kong during both the dry and wet weather seasons. The concentrations of total PAHs in the sediments ranged between 36 and 539 microg/kg dry wt. The lower levels were detected at the upstream site on the Dongjiang River and at the reservoirs in Hong Kong (44-85 microg/kg dry wt), while the mid- and downstream sites on the Dongjiang River were more polluted (588-658 microg/kg dry wt). Examination of the PAH profiles revealed that the mid- and downstream sections of the Dongjiang River contained high percentages of 4,5,6-ring PAHs, similar to the amounts of atmospheric particulate matter and road dust collected during the dry weather season from the Pearl River Delta region as reported in the literature. Seasonal changes were revealed in the reservoirs of Hong Kong, with higher PAH levels in the wet weather season than in the dry weather season. For those reservoirs in Hong Kong that store water from the Dongjiang River, a distinct seasonal pattern was also observed, namely, that under dry weather season conditions the PAHs found in the sediments were primarily from petrogenic source, while under wet weather season conditions they were from pyrolytic sources. No such pattern was detected in the reservoirs which stored only rain water.     

Decomposition pathways and reaction intermediate formation of the purified, hydrolyzed azo reactive dye C.I. Reactive Red 120 during ozonation

In this study, an aqueous solution of purified, hydrolyzed C.I. Reactive Red 120 (RR 120, Color Index), was selected as a model to investigate the degradation pathways and to obtain additional information on the reaction intermediate formation. The dye was purified to avoid the influence of the impurities on the ozonation process and on the formation of oxidation by-products. To simulate the dye-bath effluents from dyeing processes with azo reactive dyes, a hydrolyzed form of the dye was chosen as a representative compound. High performance liquid chromatography/mass spectrometry and its tandem mass spectrometry was chosen to identify the decomposition pathways and reaction intermediate formation during the ozonation process. In addition total organic carbon and high performance ion chromatography analysis were employed to obtain further information on the reaction processes during ozonation. Purified, hydrolyzed RR 120 was decomposed under the direct nucleophilic attack by ozone resulting in oxidation and cleavage of azo group and aromatic ring, while the triazine group still remained in the solution even after prolonged oxidation time (120 min) due to its high resistance to ozonation. Phenol, 1,2-dihydroxysulfobezene, 1-hydroxysulfonbezene were detected as the degradation intermediates, which were further oxidized by O(3) and *OH to other open-ring products and then eventually led to simple oxalic and formic acid identified by HPIC.