Assessing effects of aerobic and anaerobic conditions on phosphorus sorption and retention capacity of water treatment residuals

Water treatment residuals (WTRs) are the by-products of drinking water clarification processes, whereby chemical flocculants such as alum or ferric chloride are added to raw water to remove suspended clay particles, organic matter and other materials and impurities. Previous studies have identified a strong phosphorus (P) fixing capacity of WTRs which has led to experimentation with their use as P-sorbing materials for controlling P discharges from agricultural and forestry land. However, the P-fixing capacity of WTRs and its capacity to retain sorbed P under anaerobic conditions have yet to be fully demonstrated, which is an issue that must be addressed for WTR field applications. This study therefore examined the capacity of WTRs to retain sorbed P and sorb further additional P from aqueous solution under both aerobic and anaerobic conditions. An innovative, low cost apparatus was constructed and successfully used to rapidly establish anoxic conditions in anaerobic treatments. The results showed that even in treatments with initial solution P concentrations set at 100 mg l(-1), soluble reactive P concentrations rapidly fell to negligible levels (due to sorption by WTRs), while total P (i.e. dissolved + particulate and colloidal P) was less than 3 mg l(-1). This equated to an added P retention rate of >98% regardless of anaerobic or aerobic status, indicating that WTRs are able to sorb and retain P in both aerobic and anaerobic conditions.     

Occurrence of PAHs and PCBs in the Alna River, Oslo (Norway)

Thirty two polychlorinated biphenyl congeners (PCBs), hexachlorobenzene (HCB) and pentachlorobenzene (PeCB) were analysed in passive sampler extracts from surface water-exposed semipermeable membrane devices (SPMDs) and in bed sediment samples from a small urban watercourse, the River Alna (Oslo, Norway). Performance reference compound-corrected data from the passive samplers deployed at three sites along the river were used to track PCB contamination in the overlying water. SPMDs were able to detect an increase in dissolved PCB concentrations at the site furthest downstream that was corroborated by bed sediment concentrations. In comparison, no major increase in concentration of HCB, PeCB or PAHs could be observed. Comparison of passive sampling-based overlying water concentrations with total concentrations measured in bed sediments supports the possibility of further PCB sources upstream of the study area. Diagnostic PAH ratios (from SPMDs) and PCB congener pattern (from sediments) were used in an attempt to identify possible contaminant sources to the Alna River. Selected PAH diagnostic ratios support a multiple emission source scenario and demonstrate the complexity of identifying specific sources of these compounds to surface waters. PCB congener patterns in sediments from all three sites tend to indicate a source of highly chlorinated PCBs (of the Archlor 1260 type) and either a source of lower chlorinated PCBs or the less-likely occurrence of dechlorination in sediment. Information collected during the present screening study also confirms the Alna River as a continuous source of PCBs to the Oslofjord.     

Neglected biological patterns in the residuals

One of the fundamental assumptions underlying linear regression models is that the errors have a constant variance (i.e., homoscedastic). When this assumption is violated, standard errors from a regression can be biased and inconsistent, meaning that the associated p values and 95% confidence intervals cannot be trusted. The assumption of homoscedasticity is made for statistical reasons rather than biological reasons; in most real datasets, some form of heteroscedasticity is likely to exist. However, a survey of the behavioural ecology literature showed that only about 5% of articles explicitly mentioned heteroscedasticity, leaving 95% of articles in which heteroscedasticity was apparently absent. These results strongly indicate that the prevalence of heteroscedasticity is widely under-reported within behavioural ecology. The aim of this article is to raise awareness of heteroscedasticity amongst behavioural ecologists. Using topical examples from fields in behavioural ecology such as sexual dimorphism and animal personality, we highlight the biological importance of considering heteroscedasticity. We also emphasize that researchers should pay closer attention to the variance in their data and consider what factors could cause heteroscedasticity. In addition, we introduce some simple methods of dealing with heteroscedasticity. The two methods we focus on are: (1) incorporating variance functions within a generalised least squares (GLS) framework to model the functional form of heteroscedasticity and; (2) heteroscedasticity-consistent standard error (HCSE) estimators, which can be used when the functional form of heteroscedasticity is unknown. Using case studies, we show how both methods can influence the output from linear regression models. Finally, we hope that more researchers will consider heteroscedasticity as an important source of additional information about the particular biological process being studied, rather than an impediment to statistical analysis.     

Empirical assessment of incorporating sediment quality triad data into a single index to distinguish dominant stressors between sites

Benthic infaunal community structure, sediment contamination, and sediment toxicity data (Sediment Quality Triad) were condensed into a single index based on the area of tri-axial plots, which were examined in relation to various habitat parameters. The purpose was to assess its utility for evaluating the relative impact of contaminants versus other stressors on benthic communities. The regression relationship between the areal index and the Effects Range?CMedian quotient (ERMq) was used to separate contaminant-impacted sites from sites impacted by hypoxia in Chesapeake Bay. Regression using the areal index and bottom oxygen confirm the utility of the approach. Data from Delaware, Galveston, and Biscayne Bays were also examined to determine if the approach may be effective in other estuaries.     

Can you tell a green field from a cold steel rail? Examining the “green” of Green Infrastructure development

The rapid development of Green Infrastructure as an approach to planning has enabled landscape practitioners to implement a range of projects utilising its principles. Discussions though exist examining what Green Infrastructure is, how it should be planned, and whether it can be identified as only those elements of the landscape that are green. A further element of this argument examines the use of water within this process. Therefore, as planners, we can ask: can we tell a green field from a cold steel rail? Both may have a green or sustainable function with only the visual appearance differing. Debates, however, focus on practitioner selectivity of the interpretation of “green” infrastructure planning exploring whether physical landscape characteristics or the function of an investment is the main focus of discussion. Using the grey–green continuum developed by Davies et al. [2006. Green infrastructure planning guide project: Final report. Annfield Plain: NECF], this paper examines whether geographical differences exist in the application of the Green Infrastructure and examine how practitioners use the ambiguity of Green Infrastructure planning to guide investment. Drawing on academic and practitioner literature provides this paper with a balance of conceptual and process-based assessments evaluations of global Green Infrastructure focusing on the design and implementation of terrestrial and marine resources. This paper also examines whether the dominant landscape planning framework in each region could be considered contradictory to the wider application of Green Infrastructure principles.     

A High Performance Liquid Chromatographic Determination of Free Amino Acids in Natural Waters in the Picomolar (M X 10-12) Range Suitable for Shipboard Use

A reliable method for the determination of amino acids, suitable for routine shipboard use, is presented. Using reverse-phase high-performance liquid chromatography with computer-controlled gradient elution optimization, the amino acids commonly found in sea-water were clearly resolved and determined at the picomole level. A procedure was also developed to enable repeat injections of sea water samples to be made without deterioration of column material or performance. Thus the analysis was made more operator-independent and consequently more suitable for use at sea.     

化学危险品管理(Infosafe概念)

澳大利亚安工有限公司是在1987年由叶恩柯维先生(Mr.lan Cowie)创立。该公司以提供化工安全软件为主。这次中国第一届企业安全与健康管理高峰年会上,柯维先生主持第二天工作会议,并向中国工业安全专家详细讲解了他对工业安全的经验。     

Amino Acids in Sea Water

Free amino acids in the waters of the English Channel have been measured over a twelve month period using a newly developed field technique. Samples have been taken over a wide area both from the surface and at depth. The results show that the levels of amino acids found in these studies are greater than those previously generally accepted. These findings are of considerable importance in productivity studies since amino nitrogen as a source of nutrient for phytoplankton has been largely neglected. This paper shows that the levels of amino acids in the upper layers of the sea are not insignificant and should not be disregarded as an alternative nitrogen source for phytoplankton.