曝气和pH对城市污染河道底泥氮形态的影响

以城市重污染河道表层沉积物为研究对象,采用模拟实验方法,探讨了不同曝气方式(水曝气和泥曝气)、上覆水初始pH(自然状态pH=7和pH=11)对城市污染河道底泥氮形态的影响。结果表明:采用水曝气+pH11方式对城市重污染河道上覆水、间隙水中总氮去除率分别为70.03%和44.66%;泥曝气+pH7方式对上覆水、间隙水、底泥中氨氮去除率分别为94.31%、84.07%和68.29%;底泥pH与上覆水总氮浓度呈正相关(p<0.05);泥曝气+pH11方式使底泥含水率、烧失率明显升高,继而影响各形态氮在泥水系统中的赋存,其中底泥吸附态氨氮含量与底泥含水率呈显著负相关(p<0.01),间隙水可溶态氨氮浓度与底泥烧失率显著正相关(p<0.01)。     

雾化介质阻挡放电联合电晕放电对染料溶液脱色研究

实验将介质阻挡放电与电晕放电组合在一个反应器内,以靛蓝二磺酸钠溶液为实验废水,将高压电极上通入50Hz交流高压电,在常压空气中形成介质阻挡放电-电晕放电系统,放电产生的低温等离子体及其活性基团作用于染料分子。考察了电源电压、电极间距、处理时间对染料溶液脱色率和能量效率水平的影响,确定反应器工作状态为介质阻挡放电系统电极间距30mm、电晕放电系统电极间距25mm、电源电压20kV。     

旅游相关企业松散型纵向一体化战略联盟研究

我国旅游产业发展水平不高,其深层次的原因是旅游产业链中存在着严重的纵向外部性问题。在借助演化博弈思想对旅游产业链中经济主体的决策行为进行深入分析后,认为纵向一体化战略联盟能有效提升旅游产业链和相关主体利益,在传统的纵向一体化联盟基础上提出了一种界于市场和企业,但又不同于完全一体化的"混合"组织形式——松散型纵向一体化战略联盟,并初步描绘了这一联盟模式的构建过程。     

新休假制度下长沙市城郊旅游市场分析

在我国新休假制度下,城郊游短线旅游受到越来越多旅游者的青睐。通过问卷调查,采用SPSS分析方法,得出长沙市城郊旅游市场在人口学和市场结构方面的一些特征。在市场分析的基础上,选择长沙市城郊旅游的目标市场,并针对相关问题对城郊旅游开发提出了一些建议,如以创造旅游者体验为核心提升景点价值;针对不同类型的消费者采取差异化的价格,宜采用多样化的促销方式和以直接营销渠道为主。     

Sorption kinetic characteristics of polybrominated diphenyl ethers on natural soils

Sorption kinetic characteristics of BDE-28 and BDE-47 on five natural soils with different organic carbon fractions were investigated, and could be satisfactorily described by a two (fast and slow)-compartment first-order model with the ratio of rate constants ranged from 9 to 94 times. The fast compartment made a dominant contribution (71% ∼ 94%) to the total sorption amount in the whole process, and accounted for over 90% of the increase in the total sorption amount at initial 5 h. The influence of the slow compartment on the increase in the total sorption amount became principal (above 90%) in the subsequent stage approximately from 9 h or 25 h to the apparent equilibrium at 265 h. The results proposed the different sorption behaviors of the mathematically classified compartments for BDE-28 and BDE-47, which may correspond to the different soil components, such as soil organic fractions with amorphous and condensed structures, respectively.     

造纸废水厌氧处理产沼气发电研究

以浙江某纸业企业利用造纸废水厌氧处理所产沼气发电工程为例,研究造纸废水厌氧处理产沼气发电系统工艺运行的稳定性和经济可行性。结果表明:(1)厌氧内循环(IC)反应器运行稳定,产沼气量基本在3000m3/d左右(测定点压强约为2×105Pa),平均产气率为0.38m3/kg,基本达到产气率设计要求。(2)经处理后沼气中硫化氢质量浓度始终处于20～50mg/m3,平均固体颗粒物质量浓度约为15mg/m3,平均湿度为66%,达到发电系统的要求。(3)运行期间平均日发电量为8600kW.h,回用的蒸汽量平均约为1.1t/d。(4)整个沼气发电系统总收支为6.0万元/a,实现收支平衡且略有盈余。(5)假设以煤炭替换沼气发电,以年发电258万kW.h计算,理论上沼气发电系统每年节省煤炭928.8t,减少2118t二氧化碳排放,节能减排成效显著。     

沸石载体催化剂研制及其催化臭氧氧化染料废水的研究

以沸石为载体负载不同金属氧化物来制备催化剂,通过试验分析该催化剂催化臭氧氧化染料废水的效果及其影响因素。结果表明:(1)沸石对染料废水的吸附作用很小,总有机碳(TOC)去除率基本维持在3.2%左右,对于后期的试验可以忽略其影响。(2)以沸石作为载体制得的MnO2、Fe2O3、ZnO、CuO负载型催化剂(分别简写为MnO2/沸石、Fe2O3/沸石、ZnO/沸石、CuO/沸石),对臭氧氧化反应均有催化作用,其催化效果依次为MnO2/沸石Fe2O3/沸石ZnO/沸石CuO/沸石。同时,MnO2/沸石的重复使用率高。(3)MnO2/沸石催化臭氧氧化效率及重复使用率均优于以活性炭为载体的MnO2负载型催化剂。(4)臭氧氧化和MnO2/沸石催化臭氧氧化对染料的脱色率基本一致。MnO2/沸石催化臭氧氧化的TOC去除率比臭氧氧化提高较多,对染料废水有很好的处理效果。(5)以沸石为载体制得的负载型催化剂催化臭氧氧化实际染料废水的处理效果较好,具有较高的实用价值。     

低碳理念在工业园区规划环评中的应用低碳理念在工业园区规划环评中的应用

工业园区是温室气体排放的重要源头之一,工业园区规划环评应在规划的基础上,探讨如何在评价过程中通过制定合理的对策措施,促进园区低碳发展。本文分析了低碳发展理念纳入工业园区规划环评的工作重点,建议规划环评完善评价内容,在原有评价体系中融入园区温室气体排放特征、设定低碳发展评价指标、优化设计能源结构、构建低碳产业体系、低碳发展替代方案以及碳排放跟踪评价等内容,以达到规划环评指导工业园区按低碳路径发展的目的。     

新疆“十五”至“十一五”期间影响工业固废产生及排放的主要社会经济因素分析

采用灰色关联分析,找出了影响工业固废量的主要社会经济因素,认为第二产业是影响工业固废的主要因素。第二产业结构比重加大,工业固废量增加。从减少工业固废的角度来看,调整产业结构已是当务之急;环境污染治理投资与工业固废因子关联度最小,说明环保投资已远不能满足环境治理的实际需要,需加大环保投资。     

Air ion concentrations in various urban outdoor environments

Atmospheric ions are produced by many natural and anthropogenic sources and their concentrations vary widely between different environments. There is very little information on their concentrations in different types of urban environments, how they compare across these environments and their dominant sources. In this study, we measured airborne concentrations of small ions, particles and net particle charge at 32 different outdoor sites in and around a major city in Australia and identified the main ion sources. Sites were classified into seven groups as follows: park, woodland, city centre, residential, freeway, power lines and power substation. Generally, parks were situated away from ion sources and represented the urban background value of about 270 ions cm^?3. Median concentrations at all other groups were significantly higher than in the parks. We show that motor vehicles and power transmission systems are two major ion sources in urban areas. Power lines and substations constituted strong unipolar sources, while motor vehicle exhaust constituted strong bipolar sources. The small ion concentration in urban residential areas was about 960 cm^?3. At sites where ion sources were co-located with particle sources, ion concentrations were inhibited due to the ion-particle attachment process. These results improved our understanding on air ion distribution and its interaction with particles in the urban outdoor environment.