Control strategies for particulate emissions from vehicular diesel exhaust

The advantages and disadvantages of several possible control strategies for particulate emissions from vehicular diesel exhaust are discussed. The evaluation of the potential usefulness of the various control strategies is based on available data concerning the mass loading and particle size distribution and on anticipated control standards. Several studies have been made on devices for removing particulate emissions from vehicular diesel exhaust. These studies, which include the techniques of filtration, wet scrubbers, and electrostatic precipitation, are summarized. A comparison of the various control devices is made based on such factors as size, efficiency, and maintenance requirements.     

杜邦企业安全文化建设探析

拥有200多年历史的杜邦公司,在安全管理的过程中逐渐形成了其优秀的安全文化,把安全、健康和环境保护作为企业的核心价值之一,每位员工不仅对自己的安全负责,也要对同事的安全负责。这种对个人和集体都要负责的理念,使企业有能力实现零伤害、零疾病、零事故的安全目标。同时,为杜邦在工业安全方面奠定了领先地位,并享誉全球。     

Evaluation of Gauge‐Radar Merging Methods Using a Semi‐Distributed Hydrological Model in the Upper Thames River Basin,Canada

Gauge‐radar merging methods combine rainfall estimates from rain gauges and radar to capitalize on the strengths of the individual instruments. The performance of four well‐known gauge‐radar merging methods, including mean field bias correction, Brandes spatial adjustment, local bias correction using kriging, and conditional merging, are examined using Environment Canada radar and the Upper Thames River Basin in southwestern Ontario, Canada, as a case study. The analysis assesses the effect of gauge‐radar merging methods on: (1) the accuracy of predicted rainfall accumulations; and (2) the accuracy of predicted streamflows using a semi‐distributed hydrological model. In addition, several influencing factors (i.e., gauge density, storm type, basin type, proximity to the radar tower, and time‐step of adjustment) are analyzed to determine their effect on the performance of the rainfall estimation techniques. Confirming results of previous studies, the merging methods provide an increase in the accuracy of both rainfall accumulation estimations and predicted streamflows. The results also indicate specific factors such as gauge density, rainfall intensity, and time‐step of adjustment can reduce the accuracy of merging methods and play a key role in the examination of its use for operational purposes. Results provide guidance for hydrologists and engineers assessing how best to apply corrected radar products to improve rainfall estimation and hydrological modeling accuracy.     

Trends in Raindrop Kinetic Energy with Modeled Climate Warming in the Lake Tahoe Basin

Two means by which climate change may increase surface soil erosion in mountainous terrain are: (1) increasing the frequency of extreme rainfall events and (2) decreasing the duration of snow cover on bare soil. We used output from four general circulation models (GCMs) and two greenhouse gas trajectories to produce a suite of hydrologic variables at a daily time‐step for historic and projected 21st Century conditions. We statistically disaggregated the daily rainfall to hourly, using hourly rainfall from a network of nine weather stations in the Tahoe Basin, and filtered out rain falling on a snowpack. We applied published equations to convert hourly intensity to raindrop kinetic energy (KE) for each day and grid cell in the Basin, averaged across grid cells, and created time series of total annual and maximum annual hourly kinetic energy (TKE and MKE) on snow‐free ground. Using the Generalized Extreme Value distribution, we calculated the significance of long‐term trends in KE on snow‐free ground, and estimated energy levels for return periods of 2, 20, and 100 years. We then detrended the snowpack data and compared the resulting trends in KE with the trends resulting from changes in both rainfall energy and snowpack under two GCMs. Principal findings include (1) upward trends in MKE, (2) stronger upward trends in TKE; and (3) an effect of increasing rainfall intensities on KE in some cases, and a strong effect of reduced snowpack in all cases examined.     

Observations of particle growth at a remote,Arctic site

Observations of particle size distributions suggest that particles grow significantly just above the snow surface at a remote, Arctic site. Measurements were made at Summit, Greenland (71.38°N and 31.98°W) at approximately 3200 m above sea level. No new particle formation was observed locally, but growth of ultrafine particles was identified by continuous evolution of the geometric mean diameter (GMD) during four events. The duration of the growth during events was between 24 and 115 h, and calculated event-average growth rates (GR) were 0.09, 0.30, 0.27, and 0.18 nm h^?1 during each event, respectively. Four-hour GR up to 0.96 nm h^?1 were observed. Events occurred during below- and above-average temperatures and were independent of wind direction. Correlation analysis of hourly-calculated GR suggested that particle growth was limited by the availability of photochemically produced precursor gases. Sulfuric acid played a very minor role in particle growth, which was likely dominated by condensation of organic compounds, the source of which was presumably the snow surface. The role of boundary layer dynamics is not definite, although some mixing at the surface is necessary for the observation of particle growth. Due to the potentially large geographic extent of events, observations described here may provide a link between long-range transport of mid-latitude pollutants and climate regulation in the remote Arctic.     

Sources,distribution, and acidity of sulfate–ammonium aerosol in the Arctic in winter–spring

We use GEOS-Chem chemical transport model simulations of sulfate–ammonium aerosol data from the NASA ARCTAS and NOAA ARCPAC aircraft campaigns in the North American Arctic in April 2008, together with longer-term data from surface sites, to better understand aerosol sources in the Arctic in winter–spring and the implications for aerosol acidity. Arctic pollution is dominated by transport from mid-latitudes, and we test the relevant ammonia and sulfur dioxide emission inventories in the model by comparison with wet deposition flux data over the source continents. We find that a complicated mix of natural and anthropogenic sources with different vertical signatures is responsible for sulfate concentrations in the Arctic. East Asian pollution influence is weak in winter but becomes important in spring through transport in the free troposphere. European influence is important at all altitudes but never dominant. West Asia (non-Arctic Russia and Kazakhstan) is the largest contributor to Arctic sulfate in surface air in winter, reflecting a southward extension of the Arctic front over that region. Ammonium in Arctic spring mostly originates from anthropogenic sources in East Asia and Europe, with added contribution from boreal fires, resulting in a more neutralized aerosol in the free troposphere than at the surface. The ARCTAS and ARCPAC data indicate a median aerosol neutralization fraction [NH₄⁺]/(2[SO₄^2?] + [NO₃^?]) of 0.5 mol mol^?1 below 2 km and 0.7 mol mol^?1 above. We find that East Asian and European aerosol transported to the Arctic is mostly neutralized, whereas West Asian and North American aerosol is highly acidic. Growth of sulfur emissions in West Asia may be responsible for the observed increase in aerosol acidity at Barrow over the past decade. As global sulfur emissions decline over the next decades, increasing aerosol neutralization in the Arctic is expected, potentially accelerating Arctic warming through indirect radiative forcing and feedbacks.     

Low Emissions from Controlled Combustion for Automotive Rankine Cycle Engines

Rankine cycle engines have a high potential for meeting the emission levels established by the 1970 amendment to the Federal Clean Air Act for the 1975-76 automobile. This paper discusses a Solar research and development program sponsored by EPA/APCO which demonstrates a full scale 2 million Btu per hour working model of a Rankine cycle engine combustor and controls which can surpass the emission goals established.

Special features of the combustor are the unique methods of precisely controlling both the fuel and air to provide optimum flame performance at any engine power level. This paper discusses the special requirements of the Rankine cycle engine and shows why the very wide range of fuel flow required necessitates use. of special techniques in fuel atomization, fuel and air control, and aerodynamics. Sufficient discussion is included to show the design methods that are necessary, in general, to achieve low emissions in continuous flow combustion systems. Emphasis is placed on the importance of interfacing a combustion system with other engine parts if a successful low emission, wide turndown ratio combustor working model is to be achieved. Sufficient discussion on combustion kinetics is included to advise on approaches necessary to minimize NO formation in external combustion systems while maintaining high efficiency and low CO and unburned hydrocarbons.     

Use of a Continuous Nephelometer to Measure Personal Exposure to Particles During the U.S. Environmental Protection Agency Baltimore and Fresno Panel Studies

ABSTRACT

In population exposure studies, personal exposure to PM is typically measured as a 12- to 24-hr integrated mass concentration. To better understand short-term variation in personal PM exposure, continuous (1-min averaging time) nephelometers were worn by 15 participants as part of two U.S. Environmental Protection Agency (EPA) longitudinal PM exposure studies conducted in Baltimore County, MD, and Fresno, CA. Participants also wore iner-tial impactor samplers (24-hr integrated filter samples) and recorded their daily activities in 15-min intervals. In Baltimore, the nephelometers correlated well (R² = 0.66) with the PM₂₅ impactors. Time-series plots of personal nephelometer data showed each participant's PM exposure to consist of a series of peaks of relatively short duration. Activities corresponding to a significant instrument response included cooking, outdoor activities, transportation, laundry, cleaning, shopping, gardening, moving between microenvironments, and removing/putting on the instrument. On average, 63-66% of the daily PM exposure occurred indoors at home (about 2/3 of which occurred during waking hours), primarily due to the large amount of time spent in that location (an average of 7277%). Although not a reference method for measuring mass concentration, the nephelometer did help identify PM sources and the relative contribution of those sources to an individual's personal exposure.