A field study of the generation of nitrate in a hill cap cloud

A field experiment to investigate the formation of nitrate as an airstream passes through a hill cap cloud has been performed at the UMIST field station on Great Dun Fell. It has been shown that the aerosol nitrate concentration increased by about 0.5 microg m(-3) as the airstream passed through the cloud during the night. At sunrise the nitrate production disappeared. It is suggested that the most likely mechanism for this nitrate production was due to the solution of N2O5 and NO3 formed from the reaction of NO2 with O3. These higher oxides build up overnight in the absence of short wave radiation to photolyse them. Other possible mechanisms of nitrate production are also discussed.     

Arrested municipal solid waste incinerator fly ash as a source of heavy metals to the UK environment

Arrested fly ash samples from most currently operating municipal solid waste (MSW) incinerators in the UK have been analysed for a range of elements. Some of the more important heavy metals ranged in concentration as follows: Cd, 21-4646 (median = 271) mg kg(-1); Cu, 296-1307 (642) mg kg(-1); Cr, 44-1328 (574) mg kg(-1); Ni, 45-2204 (74) mg kg(-1); Pb, 447-9704 (4337) mg kg(-1); and Zn, 2285-13,500 (9232) mg kg(-1). These concentrations represent considerable enrichments relative to median UK soil concentrations. Enrichment ratios (defined as median fly ash: median UK soil) were as follows: Mn 1.6; Co 2.6; Ni 3.3; Ba 11; Sr 11; Cr 15; Cu 35; Pb 108; Zn 113; Cd 387. It is estimated that MSW incinerator ash contributes c. 15 t Cd and 241 t Pb to UK landfill sites per annum. These figures compare with previous studies by Hutton & Symon (Hutton, M. & Symon, C. (1986). The quantities of cadmium, lead, mercury and arsenic entering the UK environment from human activities. Sci. Total Environ., 57, 129-50.) which estimated that annual inputs to UK landfills from coal fly ash are c. 60 t Cd and 1270 t Pb. However, it is argued that metals associated with MSW ashes are potentially of greater environmental significance than in coal ashes, because they are much more available and present at much higher concentrations.     

Spatial and Temporal Variations in the Sediment Habitat of Ranunculus spp. in Lowland Chalk Streams – Implications for Ecological Status?

Ranunculus spp. are the dominant plants of lowland chalk stream habitats in England. The spatial variability of sediment characteristics (silt–clay, organic matter, total phosphorus and total nitrogen content) within stands of Ranunculus spp. was investigated in 12 rivers in lowland England. Variability was found to be high and there were no discernible differences between samples taken from within Ranunculus and a limited number of samples from bare substrate. For two of these rivers, comparisons were also made between reaches upstream and downstream of waste water treatment works outfalls in terms of the characteristics of the sediments within Ranunculus stands. In one river a clear increase in sediment nutrient, fine and organic material content was observed downstream but in the other there was no consistent difference. Temporal variability was considered for two rivers in the Frome catchment, Dorset, by analysing the monthly variability in sediment organic matter and silt–clay content beneath Ranunculus stands over an annual cycle of growth and die-back. Whilst a clear pattern of fine and organic material retention consistent with seasonal plant growth patterns was evident at one site, the three sites displayed different temporal patterns. This inconsistency is believed to reflect differences in sediment supply at the three sites.     

Die Aleuronzellen des keimenden Getreides

Während der Vorbereitungen zu diesem Artikel war R. L. J. als Preisträger der Alexander-von-Humboldt-Stiftung in Göttingen tätig. Unsere Forschung auf diesem Gebiet wurde durch großzügige Hilfe der Deutschen Forschungsgemeinschaft und der National Science Foundation (USA) ermöglicht. Außerdem sind wir B. Raufeisen für die Herstellung der Zeichnungen sehr zu Dank verpflichtet.     

Towards an alternative criterion for the shipping safety of activated carbons

A new criterion for shipping safety of activated carbons is developed which requires microcalorimetric measurements for its implementation. It is examined by making microcalorimetric measurements on a variety of commercial activated carbons. Results are compared with those for the same carbons according to the critical ignition temperature approach.     

The persistence of polynuclear aromatic hydrocarbons (PAHs) in sewage sludge amended agricultural soils

In 1968, five metal enriched sewage sludges containing different concentrations of polynuclear aromatic hydrocarbons (PAHs) were applied to different plots on field soils at two experimental sites, Luddington and Lee Valley, in the UK. This resulted in substantial increases in the total PAH soil concentrations in all plots. Since application, losses have occurred, with the high molecular weight PAHs being more persistent. Calculated half-lives range from under 2 years for naphthalene to over 9 years for benzo[ghi]perylene and coronene. The losses of PAH compounds in these field experiments can be related, in part, to their physico-chemical properties, notably the octanol: water partition coefficient.     

Life-cycle assessment of 11 kV electrical overhead lines and underground cables

The life-cycle impacts of five different 11 kV electrical power cables (three overhead lines and two underground cables) were analysed. These were compared by their embodied impacts in production and total lifetime operational impacts. The life-cycle results revealed there to be three key issues, the impacts of climate change, fossil fuel depletion, and particulate matter formation (PMF). The former two were of particular significance. The embodied impacts, which are those associated with the materials, were generally determined to be insignificant. The exception was for underground cables at low operating loads. Under these conditions PMF was more significant as a result of the high embodied impacts of the cables. Further analysis revealed that these impacts could be mitigated with an end of life material recovery program. At present the underground cables are not recovered, but if they were the recycling benefits would give rise to a notable improvement in PMF. For the other impact categories operational conductor losses were the dominant cause of impacts. In summary it was concluded that to minimise the life-cycle impacts of 11 kV cables the system with the lowest conductor resistance should be selected.     

Causal relationships between African mahoganies exports and deforestation in Ghana: policy implications

When exploiting forest resources, the resource use must be sustainable if its use is to support its function in the natural ecosystem. The African mahogany, a prized timber species, is widely exploited, raising policy concerns about the management of forest resources to meet the social, economic, and ecological needs of present and future generations. This paper explores, for the purpose of policy implication, the relationship between the exportation and deforestation of African mahoganies. The analysis employed a Granger causality test within the error correction model to evaluate the direction of causality between African mahoganies exports and deforestation in Ghana. The results suggested that in the short run, there was significant (P < 0.01) unidirectional causality from African mahoganies exports to deforestation. However, there was no directional causality from deforestation to mahogany exports. Thus, mahogany extraction and logging in general are among the major factors contributing to deforestation in Ghana. The general assessment of historical trends in the extraction levels of the two main genera of African mahoganies revealed that Entandrophragma cylindricum and Khaya ivorensis have been the most exploited species over the years. Improvements in, and the enforcement of, existing forest institutions and incentives, as well as related policies, could minimise the rate of deforestation not only of the African mahogany but also in timber logging, thus stemming forest degradation and deforestation in the country.