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71.
Maria Antonia Sánchez-Trujillo Silvia Lacorte Jaime Villaverde Carlos Barata Esmeralda Morillo 《Environmental science and pollution research international》2014,21(1):507-517
A decontamination technique based in cyclodextrin extraction has been developed to eliminate nonylphenol (NP) and 16 polycyclic aromatic hydrocarbons (PAHs; the US Environmental Protection Agency priority pollutants list) from sewage sludge. In a first step, PAHs and NP were characterised in six sludges to determine contamination levels according to limit values proposed by the European Union Sludge Directive draft. There were few variations in the total PAHs content with levels of 1.88 to 3.05 mg kg?1. Three-ring PAHs predominated, but fluoranthene and pyrene were also present. None of the sludge exceeded the PAHs limit proposed by the European Union’s draft Directive. On the contrary, NP content in four of the six sludges was over the recommended limits of 50 mg kg-1 for NP ethoxylates. With the aim of obtaining NP values below the concentration limits proposed to use the sewage sludge as agricultural amendments, a preliminary study using hydroxypropyl-β-cyclodextrin (HPBCD) extractions as a decontamination technique was carried out. About 90 % of NP content was removed with only one extraction with HPBCD, whereas after three sequential extractions using an aqueous solution without HPBCD, the NP extraction percentage was less than 1 %. Simultaneously, PAHs extraction percentages obtained with HPBCD were also much higher than when aqueous solution was used, especially in the case of two- and three-ring PAHs. Finally, the potential environmental hazard of HPBCD leachates to aquatic organisms (Daphnia magna) was tested. These results indicate that the treatment of sewage sludge with cyclodextrin could allow their safe use as fertiliser in agriculture. 相似文献
72.
Michelle A. Colledge Jaime R. Julian Vihra V. Gocheva Cheryl L. Beseler Harry A. Roels Danelle T. Lobdell 《Journal of the Air & Waste Management Association (1995)》2013,63(8):948-957
This study was conducted to derive receptor-specific outdoor exposure concentrations of total suspended particulate (TSP) and respirable (dae ≤ 10 µm) air manganese (air-Mn) for East Liverpool and Marietta (Ohio) in the absence of facility emissions data, but where long-term air measurements were available. Our “site-surface area emissions method” used U.S. Environmental Protection Agency’s (EPA) AERMOD (AMS/EPA Regulatory Model) dispersion model and air measurement data to estimate concentrations for residential receptor sites in the two communities. Modeled concentrations were used to create ratios between receptor points and calibrated using measured data from local air monitoring stations. Estimated outdoor air-Mn concentrations were derived for individual study subjects in both towns. The mean estimated long-term air-Mn exposure levels for total suspended particulate were 0.35 μg/m3 (geometric mean [GM]) and 0.88 μg/m3 (arithmetic mean [AM]) in East Liverpool (range: 0.014–6.32 μg/m3) and 0.17 μg/m3 (GM) and 0.21 μg/m3 (AM) in Marietta (range: 0.03–1.61 μg/m3). Modeled results compared well with averaged ambient air measurements from local air monitoring stations. Exposure to respirable Mn particulate matter (PM10; PM <10 μm) was higher in Marietta residents.Implications: Few available studies evaluate long-term health outcomes from inhalational manganese (Mn) exposure in residential populations, due in part to challenges in measuring individual exposures. Local long-term air measurements provide the means to calibrate models used in estimating long-term exposures. Furthermore, this combination of modeling and ambient air sampling can be used to derive receptor-specific exposure estimates even in the absence of source emissions data for use in human health outcome studies. 相似文献
73.
The photocatalytic efficiency of two 2,4,6-triphenylpyrylium (TP(+)) based photocatalysts (supported on silica or incorporated inside zeolite Beta, 3wt%) for the degradation of 2,4-dichlorophenol (DCP) in aqueous media has been compared with TiO(2) (Degussa P-25). It was found that the efficiency of the degradation depends on the photocatalytic setup, recirculation through a tubular reactor being highly unfavorable for the TP(+)-based photocatalysts due to the deposition of the silica or zeolite particles. In contrast, high efficiency in DCP disappearance (up to 87%) and in the total organic content decrease (up to 62%) were obtained using a discontinuous batch reactor in which the TP(+) photocatalysts were uniformly suspended. Kinetic studies were also made and DCP degradation follows a first order kinetics. The obtained kinetic constants when corrected to account for the influence of the fraction of light absorbed and the amount of active sites shows that the intrinsic activity of TP(+) adsorbed on silica or incorporated inside zeolite Beta was over one order of magnitude higher than TiO(2) activity. 相似文献
74.
Eutrophication and Sedimentation Patterns in Complete Exploitation of Water Resources Scenarios: An Example from Northwestern Semi-arid Mexico 总被引:1,自引:0,他引:1
Sánchez-Carrillo S Alatorre LC Sánchez-Andrés R Garatuza-Payán J 《Environmental monitoring and assessment》2007,132(1-3):377-393
Water requirements to supply human needs lead water stakeholders to store more water during surplus periods to fulfil the
demand during – not only – scarcity periods. At the reservoirs, mostly those in semi-arid regions, water level then fluctuates
extremely between rises and downward during one single year. Besides of water management implications, changes on physical,
chemical and biological dynamics of these drawdown and refilling are little known yet. This paper shows the results, throughout
a year, on solids, nutrients (N and P), chlorophyll-a, and sedimentation changes on the dynamics, when the former policy was applied in a reservoir from the semi-arid Northwestern
Mexico. Water level sinusoidal trend impinged changes on thermal stratification and mixing, modifying nutrient cycling and
primary producer responses. According to nitrogen and phosphorus concentration as well as chlorophyll-a, reservoir was mesotrophic, becoming hypertrophic during drawdown. Nutrient concentrations were high (1.22 ± 0.70 and 0.14 ± 0.12 mg
P l−1), increasing phosphorus and lowering N:P significantly throughout the study period, although no intensive agricultural, no
urban development, neither industrial activities take place in the watershed. This suggests nutrient recycling complex mechanisms,
including nutrient release from the sediment–water interface as the main nutrient pathway when shallowness, at the same time
as mineralization, increases. Outflows controlled nitrogen and phosphorus availability on the ecosystem while organic matter
depended on river inflows. As on other subtropical aquatic ecosystems, nitrogen limited primary productivity (Spearman correlation
R = 0.75) but chlorophyll-a seasonal pattern showed an irregular trend, prompting other no-nutrient related limitants. Shallowness induced a homogeneous
temporal pattern on water quality. This observed temporal variability was mainly explained statistically by changes on solids
(mineral and organic), chlorophyll-a and flows (62.3%). Annual sedimentation rates of total solids ranged from 11.73 to 16.29 kg m−2 year−1 with organic matter comprising around 30%. N:P ratio on sedimentation rates were as high as could be expected in a resuspension
dominated ecosystem, and spatially inverse related with N:P ratio on bottom sediments. Distance from river inlet into the
reservoir reveals a marked spatial heterogeneity on solid and nitrogen sedimentation, showing the system dependence on river
inflows and supporting resuspension as the main phosphorus pathway. Accretion rates (2.19 ± 0.40 cm year−1) were not related to hydrological variability but decreased with the distance to the river input. Total sediment accumulation
(9,895 tons km−2 year−1) denotes siltation as other serious environmental problem in reservoirs but possibly not related with operational procedures. 相似文献
75.
Rodríguez-Estival J Barasona JA Mateo R 《Environmental pollution (Barking, Essex : 1987)》2012,160(1):118-124
The effects of Pb pollution on cattle and sheep raised in an ancient mining area were studied through the use of blood Pb (PbB) levels and δ-aminolevulinic acid dehydratase (δ-ALAD) activity. Lead levels in livestock blood from the mining area (n=110) were significantly elevated when compared to the controls (n=79). In 91.4% of cattle (n=58) and 13.5% of sheep (n=52) sampled in the mining area, PbB levels corresponded to subclinical exposure (6-35 μg/dl). Two young cattle (<2 years) from the mining area (n=5) had PbB levels indicative of clinical poisoning (>35 μg/dl). Elevated PbB was also accompanied by δ-ALAD activity inhibition in blood, which confirms that measurable effects of Pb poisoning were taking place. Observed PbB levels suggest that a potential risk to human consumers of beef from the Pb polluted areas may also exist, as has been shown previously for game meat from the same mining area. 相似文献
76.
Rodrigues Ana Sofia Silveira Jefferson E. Carbajo Jaime Zazo Juan A. Casas Jose A. Fernandes Annabel Pacheco Maria José Ciríaco Lurdes Lopes Ana 《Environmental science and pollution research international》2021,28(19):23822-23832
Environmental Science and Pollution Research - Perovskite oxides BaFeyTi1-yO3, with y = 0, 0.6, 0.8 and 1, were prepared by ceramic (CM) and complex polymerization methods (CPM) and utilized in... 相似文献
77.
78.
Sherif Abd-Elmaksoud Jaime E. Naranjo Charles P. Gerba 《Food and environmental virology》2013,5(2):87-90
Effective individual microbiological water purifiers are needed for consumption of untreated water sources by campers, emergency use, military, and in developing counties. A handheld UV light device was tested to assess if it could meet the virus reduction requirements established by the United State Environmental Protection Agency, National Science Foundation and the World Health Organization. The device was found capable of inactivating at least 4 log10 of poliovirus type 1, rotavirus SA-11 and MS-2 virus in 500 mL volumes of general case test water. But in the presence of high turbidity and organic matter, filtration was necessary to achieve a 4 log10 reduction of the test viruses. 相似文献
79.
Eduardo V. V. Varej?o Carlos R. Bellato Maur��cio P. F. Fontes Jaime W. V. Mello 《Environmental monitoring and assessment》2011,172(1-4):631-642
The Iron Quadrangle has been one of the most important gold production regions in Brazil since the end of the seventeenth century. There, arsenic occurs in close association with sulfide-rich auriferous rocks. The most abundant sulfide minerals are pyrite and arsenopyrite, yet trace metal sulfides occur in subordinate phases as well. Historical mining activities have been responsible for the release of As and trace metals to both aquatic and terrestrial environments close to mining sites in the region. Therefore, this study was aimed to evaluate the distribution and mobility of As, Cd, Co, Cr, Cu, Ni, Pb, and Zn in streams in the southeast portion of the Iron Quadrangle between the municipalities of Ouro Preto and Mariana, the oldest Brazilian Au mining province. Total concentrations of some trace metals and arsenic in water were determined. The four-stage sequential extraction procedure proposed by the commission of the European Communities Bureau of Reference (BCR) was used to investigate the distribution of these elements in stream sediments. Arsenic concentration in water was >10 ??g L???1 (maximum limit permitted by Brazilian environmental regulations for water destined for human consumption) at all sampling sites, varying between 36.7 and 68.3 ??g L???1. Sequential extraction in sediments showed high concentrations of As and trace metals associated with easily mobilized fractions. 相似文献
80.
Medina-Contreras Diana Cantera-Kintz Jaime Sánchez Alberto 《Environmental science and pollution research international》2022,29(41):61608-61622
Environmental Science and Pollution Research - Mangroves are important ecosystems of tropical and subtropical shorelines. Anthropogenic activity decreases their habitat quality, affecting... 相似文献