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101.
Brian P. Leaderer Theodore R. Holford Jan A. J. Stolwijk 《Journal of the Air & Waste Management Association (1995)》2013,63(2):154-157
A PM10 monitoring network was established throughout the South Coast Air Basin (SOCAB) in the greater Los Angeles region during the calendar year 1986. Annual average PM10 mass concentrations within the Los Angeles metropolitan area ranged from 47.0 µg m-3 along the coast to 87.4 µg m-3 at Rubldoux, the furthest inland monitoring station. Measurements made at San Nicolas Island suggest that regional background aerosol contributes between 28 to 44 percent of the PM10 aerosol at monitoring sites In the SOCAB over the long term average. Five major aerosol components (carbonaceous material, NO- 3, SO= 4, NH+ 4, and soil-related material) account for greater than 80 percent of the annual average PM10 mass at all on-land monitoring stations. Peak 24-h average mass concentrations of nearly 300 µg m-3 were observed at inland locations, with lower peak values (?130–150 µg m-3) measured along the coast. Peak-day aerosol composition was characterized by increased NO- 3 Ion and associated ammonium ion levels, as compared to the annual average. There appears to be only a weak dependence of PM10 mass concentration on season of the year. This lack of a pronounced seasonal dependence results from the complex and contradictory seasonal variations in the major chemical components (carbonaceous material, nitrate, sulfate, ammonium ion and crustal material). At most sites within the Los Angeles metropolitan area, PM10 mass concentrations exceeded both the annual and 24-h average federal and state of California PM10 regulatory standards. 相似文献
102.
Zero-valent iron nanoparticles in treatment of acid mine water from in situ uranium leaching 总被引:3,自引:0,他引:3
Acid mine water from in situ chemical leaching of uranium (Straz pod Ralskem, Czech Republic) was treated in laboratory scale experiments by zero-valent iron nanoparticles (nZVI). For the first time, nZVI were applied for the treatment of the real acid water system containing the miscellaneous mixture of pollutants, where the various removal mechanisms occur simultaneously. Toxicity of the treated saline acid water is caused by major contaminants represented by aluminum and sulphates in a high concentration, as well as by microcontaminants like As, Be, Cd, Cr, Cu, Ni, U, V, and Zn. Laboratory batch experiments proved a significant decrease in concentrations of all the monitored pollutants due to an increase in pH and a decrease in oxidation-reduction potential related to an application of nZVI. The assumed mechanisms of contaminants removal include precipitation of cations in a lower oxidation state, precipitation caused by a simple pH increase and co-precipitation with the formed iron oxyhydroxides. The possibility to control the reaction kinetics through the nature of the surface stabilizing shell (polymer vs. FeO nanolayer) is discussed as an important practical aspect. 相似文献
103.
Plant communities in relation to flooding and soil contamination in a lowland Rhine River floodplain
Schipper AM Lotterman K Leuven RS Ragas AM de Kroon H Hendriks AJ 《Environmental pollution (Barking, Essex : 1987)》2011,159(1):182-189
Using canonical correspondence analysis (CCA), relationships were investigated between plant species composition and flooding characteristics, heavy metal contamination and soil properties in a lowland floodplain of the Rhine River. Floodplain elevation and yearly average flooding duration turned out to be more important for explaining variation in plant species composition than soil heavy metal contamination. Nevertheless, plant species richness and diversity showed a significant decrease with the level of contamination. As single heavy metal concentrations seemed mostly too low for causing phytotoxic effects in plants, this trend is possibly explained by additive effects of multiple contaminants or by the concomitant influences of contamination and non-chemical stressors like flooding. These results suggest that impacts of soil contamination on plants in floodplains could be larger than expected from mere soil concentrations. In general, these findings emphasize the relevance of analyzing effects of toxic substances in concert with the effects of other relevant stressors. 相似文献
104.
105.
106.
Trier X Nielsen NJ Christensen JH 《Environmental science and pollution research international》2011,18(8):1422-1432
Introduction
In this study, we provide strategies for detecting and quantifying the structural isomers of polyfluorinated di- and tri-alkyl surfactants (PFAS) by mass spectrometry (MS). We specifically investigate polyfluorinated dialkylated phosphate ester surfactants (x:2/y:2 diPAPS, (F(CF2) x CH2CH2O-P(O)(O)−-OCH2CH2(CF2) y F)) and their thioether analogues (x:2/y:2 S-diPAPS, F(CF2) x CH2CH2SCH2-C[CH2O)2P(O)(O)−]-CH2SCH2CH2(CF2) y F), which are used for industrial applications, such as oil- and water-repellent coatings on paper and board. DiPAPS have been found in human blood and are metabolised to the persistent perfluoroalkyl carboxylic acids (PFCA) in rats. 相似文献107.
Trier X Granby K Christensen JH 《Environmental science and pollution research international》2011,18(7):1108-1120
Introduction
In this study, we explore the identity of a range of polyfluorinated surfactants (PFS) used for food contact materials, primarily to impart oil and water repellency on paper and board. PFS are of interest, as they can be precursors of poly- and perfluorinated alkyl substances (PFAS), of which several are persistent and are found worldwide in human blood and in the environment. 相似文献108.
Patrick Riefer Timm Klausmeyer Andreas SchäFfer Jan Schwarzbauer Burkhard Schmidt 《Journal of environmental science and health. Part. B》2013,48(5):394-403
Anthropogenic contaminants like nonylphenols (NP) are added to soil, for instance if sewage-sludge is used as fertilizer in agriculture. A commercial mixture of NP consists of more than 20 isomers. For our study, we used one of the predominate isomers of NP mixtures, 4-(3,5-dimethylhept-3-yl)phenol, as a representative compound. The aim was to investigate the fate and distribution of the isomer within soil and soil derived organo-clay complexes. Therefore, 14C- and 13C-labeled NP was added to soil samples and incubated up to 180 days. Mineralization was measured and soil samples were fractionated into sand, silt and clay; the clay fraction was further separated in humic acids, fulvic acids and humin. The organo-clay complexes pre-incubated for 90 or 180 days were re-incubated with fresh soil for 180 days, to study the potential of re-mobilization of incorporated residues. The predominate incorporation sites of the nonylphenol isomer in soil were the organo-clay complexes. After 180 days of incubation, 22 % of the applied 14C was mineralized. The bioavailable, water extractable portion was low (9 % of applied 14C) and remained constant during the entire incubation period, which could be explained by an incorporation/release equilibrium. Separation of organo-clay complexes, after extraction with solvents to release weakly incorporated, bioaccessible portions, showed that non-extractable residues (NER) were preferentially located in the humic acid fraction, which was regarded as an effect of the chemical composition of this fraction. Generally, 27 % of applied 14C was incorporated into organo-clay complexes as NER, whereas 9 % of applied 14C was bioaccessible after 180 days of incubation. The re-mobilization experiments showed on the one hand, a decrease of the bioavailability of the nonylphenol residues due to stronger incorporation, when the pre-incubation period was increased from 90 to 180 days. On the other hand, a shift of these residues from the clay fraction to other soil fractions was observed, implying a dynamic behavior of incorporated residues, which may result in bioaccessibility of the NER of nonylphenol. 相似文献
109.
110.
Lifjeld JT Kleven O Jacobsen F McGraw KJ Safran RJ Robertson RJ 《Behavioral ecology and sociobiology》2011,65(9):1687-1697
When males become more ornamented and reproduce more successfully as they grow older, phenotypic correlations between ornament
exaggeration and reproductive success can be confounded with age effects in cross-sectional studies, and thus say relatively
little about sexual selection on these traits. This is exemplified here in a correlative study of male fertilization success
in a large colony of American barn swallows (Hirundo rustica erythrogaster). Previous studies of this species have indicated that two sexually dimorphic traits, tail length and ventral plumage coloration,
are positively correlated with male fertilization success, and a mechanism of sexual selection by female choice has been invoked.
However, these studies did not control for potential age-related variation in trait expression. Here, we show that male fertilization
success was positively correlated with male tail length but not with plumage coloration. We also show that 1-year-old males
had shorter tails and lower fertilization success than older males. This age effect accounted for much of the covariance between
tail length and fertilization success. Still, there was a positive relationship between tail length and fertilization success
among older males. But as this group consisted of males from different age classes, an age effect may be hidden in this relationship
as well. Our data also revealed a longitudinal increase in both tail length and fertilization success for individual males.
We argue that age-dependent ornament expression and reproductive performance in males complicate inferences about female preferences
and sexual selection. 相似文献