Assessing inter-laboratory comparability and limits of determination for the analysis of cyclic volatile methyl siloxanes in whole Rainbow Trout (Oncorhynchus mykiss)

Cyclic volatile methyl siloxanes (cVMS) are high volume production chemicals used in a wide range of industrial and consumer products. Three cVMS compounds (D4, D5, and D6) have and are undergoing environmental risk evaluations in several countries and have been proposed for legal regulation in Canada. As interest in monitoring concentrations of these chemicals in the environment increase, there is a need to evaluate the analytical procedures for cVMS in biological matrices in order to assess the quality of data produced. The purpose of this study was to determine laboratory testing performance for measuring residues of D4, D5, and D6 in a standard set of fish homogenate samples and to estimate limits of determination for each substance. The samples sent to each laboratory consisted of homogenized whole body tissues of hatchery raised rainbow trout which were fed food fortified with D4, D5, and D6 (dosed) and trout that were fed standard food rations (control). The participants analyzed each sample using their analytical method of choice using their own standards and procedures for quantification and quality control. With a few exceptions, participating laboratories generated comparable results for D4, D5, and D6 in both the dosed and control samples having z-scores between 2 and −2. Method detection limits for the whole fish matrix were on average 2.4 ng g⁻¹ ww for D4, 2.3 ng g⁻¹ ww for D5, and 1.8 ng g⁻¹ ww for D6.     

Reporting central tendencies of chamber measured surface emission and oxidation

Methane emissions, concentrations, and oxidation were measured on eleven MSW landfills in eleven states spanning from California to Pennsylvania during the three year study. The flux measurements were performed using a static chamber technique. Initial concentration samples were collected immediately after placement of the flux chamber. Oxidation of the emitted methane was evaluated using stable isotope techniques. When reporting overall surface emissions and percent oxidation for a landfill cover, central tendencies are typically used to report “averages” of the collected data. The objective of this study was to determine the best way to determine and report central tendencies. Results showed that 89% of the data sets of collected surface flux have lognormal distributions, 83% of the surface concentration data sets are also lognormal. Sixty seven percent (67%) of the isotope measured percent oxidation data sets are normally distributed. The distribution of data for all eleven landfills provides insight of the central tendencies of emissions, concentrations, and percent oxidation. When reporting the “average” measurement for both flux and concentration data collected at the surface of a landfill, statistical analyses provided insight supporting the use of the geometric mean. But the arithmetic mean can accurately represent the percent oxidation, as measured with the stable isotope technique. We examined correlations between surface CH₄ emissions and surface air CH₄ concentrations. Correlation of the concentration and flux values using the geometric mean proved to be a good fit (R² = 0.86), indicating that surface scans are a good way of identifying locations of high emissions.     

Defending the scientific integrity of conservation‐policy processes

Government agencies faced with politically controversial decisions often discount or ignore scientific information, whether from agency staff or nongovernmental scientists. Recent developments in scientific integrity (the ability to perform, use, communicate, and publish science free from censorship or political interference) in Canada, Australia, and the United States demonstrate a similar trajectory. A perceived increase in scientific‐integrity abuses provokes concerted pressure by the scientific community, leading to efforts to improve scientific‐integrity protections under a new administration. However, protections are often inconsistently applied and are at risk of reversal under administrations publicly hostile to evidence‐based policy. We compared recent challenges to scientific integrity to determine what aspects of scientific input into conservation policy are most at risk of political distortion and what can be done to strengthen safeguards against such abuses. To ensure the integrity of outbound communications from government scientists to the public, we suggest governments strengthen scientific integrity policies, include scientists’ right to speak freely in collective‐bargaining agreements, guarantee public access to scientific information, and strengthen agency culture supporting scientific integrity. To ensure the transparency and integrity with which information from nongovernmental scientists (e.g., submitted comments or formal policy reviews) informs the policy process, we suggest governments broaden the scope of independent reviews, ensure greater diversity of expert input and transparency regarding conflicts of interest, require a substantive response to input from agencies, and engage proactively with scientific societies. For their part, scientists and scientific societies have a responsibility to engage with the public to affirm that science is a crucial resource for developing evidence‐based policy and regulations in the public interest.     

A view from the periphery

The author describes his background and relationship to the behavioral geography revolution at Clark. Key events included the independent invention of ‘turf maps’, the Place Perception Project of Blaut, Stea and McCleary, and the synergy of an exceptional cluster of faculty and students. The influence of the revolution on the author's own research has resulted in a radical redirection of effort toward applied research on children's environmental behavior, geographic learning, and participatory design methods in particular.     

An investigation into pay valence and performance in a pay-for-performance field setting

Inconsistent findings have been reported in the few studies investigating the relationship between the perceived value of pay and incentive performance. One hundred and seventy-eight female incentive employees with a nine-week, non-judgmental performance measure responded to a developed valence of pay scale. This measure used items assessing the perceived ability of pay to address employee needs. Three factor-scales were found within these items. Support for the hypothesized positive relationship between pay valence and incentive performance was found, dependent on which of the three scales was used. These findings provide initial insight into the means by which pay, with its ability to address different needs, might provide differential employee motivation and performance levels. This study and future research issues are discussed.     

Book reviews

URBANIZATION AND COMMUNITY BUILDING IN MODERN NORWAY

J. S. Tortenson, M. F. Metcalfe, T. F. Rasmussen

Urbana Press, Oslo 1985. 312 pp., figs and tables.

REGIONAL DEVELOPMENT POLICY

R. Riddell

Gower, 1985. £18.50

REVIEW OF SERVICE INDUSTRIES: A GEOGRAPHICAL APPRAISAL

P. W. Daniels

Methuen, 1985. £27.50.

ARABIC‐ISLAMIC CITIES: BUILDING AND PLANNING PRINCIPLES

Besim Selim Hakim

KPI Ltd., London, 1986. pp. 192. £46 (h/b)

FIFTY YEARS OF LANDSCAPE DESIGN

Sheila Harvey and Stephen Rettig

The Landscape Press, 1985. £12.50

CAPABILITY BROWN AND THE EIGHTEENTH CENTURY ENGLISH LANDSCAPE

Roger Turner

Weidenfeld & Nicholson. £16.95.     

A critical examination of ozone mapping from a spatial-scale perspective

Following the establishment of point measurements of ground-level ozone concentrations have been attempts by many researchers to develop ozone surfaces. This paper offers a critique of ozone-mapping endeavors, while also empirically exploring the operational scale of ground-level ozone. The following issues are discussed: aspects of spatial scale; the spatial complexity of ground-level ozone concentrations; and the problems of previous attempts at ozone mapping. Most ozone-mapping studies are beset with at least one of the following core problems: spatial-scale violations; an improper evaluation of surfaces; inaccurate surfaces; and the inappropriate use of surfaces in certain analyses. The major recommendations to researchers are to acknowledge spatial scale (especially operational scale), understand the prerequisites of surface-generating techniques, and to evaluate the resultant ozone surface properly.     

Survival of Theriosuchus (Mesoeucrocodylia: Atoposauridae) in a Late Cretaceous archipelago: a new species from the Maastrichtian of Romania

Small terrestrial non-eusuchian mesoeucrocodylians are common components of Cretaceous assemblages of Gondwanan provinces with notosuchians and araripesuchids as flagship taxa in South America, Africa and Madagascar, well into the Late Cretaceous. On the other hand, these are exceedingly rare in Laurasian landmasses during the Late Cretaceous. Small terrestrial mesoeucrocodylians from Europe were often referred to the genus Theriosuchus, a taxon with stratigraphic range extending from the Late Jurassic to the late Early Cretaceous. Theriosuchus is abundantly reported from various European localities, although Asiatic and possibly North American members are also known. It has often been closely associated with the first modern crocodilians, members of the Eusuchia, because of the presence of procoelous vertebrae, a widespread key character diagnosing the Eusuchia. Nevertheless, the relationships of Theriosuchus have not been explored in detail although one species, Theriosuchus pusillus, has been extensively described and referred in numerous works. Here, we describe a new basal mesoeucrocodylian, Theriosuchus sympiestodon sp. nov. from the Maastrichtian of the Haţeg Basin, Romania, suggesting a large temporal gap (about 58 myr) in the fossil record of the genus. Inclusion of the new taxon, along with Theriosuchus guimarotae, in a phylogenetic analysis confirms its referral to the genus Theriosuchus, within a monophyletic atoposaurid clade. Although phylogenetic resolution within this clade is still poor, the new taxon appears, on morphological grounds, to be most closely related to T. pusillus. The relationships of Atoposauridae within Mesoeucrocodylia and especially to Neosuchia are discussed in light of the results of the present contribution as well as from recent work. Our results raise the possibility that Atoposauridae might not be regarded as a derived neosuchian clade anymore, although further investigation of the neosuchian interrelationships is needed. Reports of isolated teeth referable to a closely related taxon from the Upper Cretaceous of Romania and France, together with the presence of Doratodon and Ischyrochampsa, indicate a previously unsuspected diverse assemblage of non-eusuchian mesoeucrocodylians in the Late Cretaceous European archipelago.     

The influence of use,environmental and managerial factors on the width of recreational trails

This paper evaluates the relative influences of use, managerial and environmental factors on trail width, from a survey of all formal trails in Acadia National Park, Maine, USA. A Trimble GPS was used to navigate to and collect data at sample points spaced at a 152.4 m (500 ft) interval across all National Park Service trails on Mount Desert Island. Regression analyses focus on increasing understanding of factors that influence the width of formal hiking trails. ANOVA analyses demonstrate differences in trail width based on trail surface type (class), and the presence or absence of trail borders. A novel approach of comparing intended widths to actual widths enabled us to look specifically at the avoidable and undesirable impacts associated with having a trail that is wider than intended.