Photocatalysis for arsenic removal from water: considerations for solar photocatalytic reactors

Environmental Science and Pollution Research - The following work provides a perspective on the potential application of solar heterogeneous photocatalysis, which is a nonselective advanced...     

Avian herbivory: an experiment, a field test, and an allometric comparison with mammals

Mechanistic studies on herbivore functional responses have largely taken place in mammals; very little has been done in herbivorous birds so far. Here we aim to fill that gap by experimentally quantifying the (short-term) functional response of a large avian herbivore, the Bewick's Swan (Cygnus columbianus bewickii). We explicitly distinguish between encounter-limited and handling-limited foraging by analyzing the results in the framework of the models of D. E. Spalinger and N. T. Hobbs, originally developed for mammalian herbivory. Bite size in captive swans was experimentally manipulated by varying sward height. The time interval between two bites increased with bite size, which supports the handling-limited model (process 3) and rejects the encounter-limited models (processes 1 and 2). Subsequently, we took the obtained functional response parameters into the field in order to predict, from measurements of sward height, (1) bite sizes, (2) handling times, and (3) short-term intake rates in free-ranging swans. Indeed, for all three variables, the observed values closely matched the experimentally based predictions. Finally, we review functional response parameters available in the literature on avian herbivores and scale them allometrically in relation to mammals. This analysis revealed that maximum bite sizes, and therefore maximum intake rates, in herbivorous birds are smaller than in herbivorous mammals. We hypothesize and provide evidence that birds compensate by longer daily foraging times.     

Combining passive sampling and toxicity testing for evaluation of mixtures of polar organic chemicals in sewage treatment plant effluent

Effluent from sewage treatment plants has been associated with a range of pollutant effects. Depending on the influent composition and treatment processes the effluent may contain a myriad of different chemicals which makes monitoring very complex. In this study we aimed to monitor relatively polar organic pollutant mixtures using a combination of passive sampling techniques and a set of biochemistry based assays covering acute bacterial toxicity (Microtox), phytotoxicity (Max-I-PAM assay) and genotoxicity (umuC assay). The study showed that all of the assays were able to detect effects in the samples and allowed a comparison of the two plants as well as a comparison between the two sampling periods. Distinct improvements in water quality were observed in one of the plants as result of an upgrade to a UV disinfection system, which improved from 24x sample enrichment required to induce a 50% response in the Microtox assay to 84x, from 30x sample enrichment to induce a 50% reduction in photosynthetic yield to 125x, and the genotoxicity observed in the first sampling period was eliminated. Thus we propose that biochemical assay techniques in combination with time integrated passive sampling can substantially contribute to the monitoring of polar organic toxicants in STP effluents.     

Dioxin-/Furan-“Verbrennungsprofile” in Abgasen aus Hochtemperaturprozessen

Different mechanisms downstream from high temperature processes lead to the formation of polychlorinated dibenzo(p) dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs). Independent from any concentrations, these mechanisms cause comparable PCDD/F patterns, the percentage proportion of single congeners or homologous groups related to the total of 17 2,3,7,8-Cl-substituted congeners or with respect to the sum of the homologous groups tetra to octa CDD/F. The characteristics of these so-called “combustion profiles” can help to interpret corresponding data from burning and melting facilities, such as municipal waste incinerators, coal power plants, sintering plants, metal finishing facilities, cement kilns, crematoria, hazardous waste incinerators and landfill gas burners     

Passive air sampling theory for semivolatile organic compounds

The mathematical modelling underlying passive air sampling theory can be based on mass transfer coefficients or rate constants. Generally, these models have not been inter-related. Starting with basic models, the exchange of chemicals between the gaseous phase and the sampler is developed using mass transfer coefficients and rate constants. Importantly, the inter-relationships between the approaches are demonstrated by relating uptake rate constants and loss rate constants to mass transfer coefficients when either sampler-side or air-side resistance is dominating chemical exchange. The influence of sampler area and sampler volume on chemical exchange is discussed in general terms and as they relate to frequently used parameters such as sampling rates and time to equilibrium. Where air-side or sampler-side resistance dominates, an increase in the surface area of the sampler will increase sampling rates. Sampling rates are not related to the sampler/air partition coefficient (K(SV)) when air-side resistance dominates and increase with K(SV) when sampler-side resistance dominates.     

Estimating the quantity of solid waste generation in Oyo, Nigeria.

The study established waste multipliers that could be used in conjunction with the population figure of a city to estimate the quantity of solid waste generation in the developing world. Oyo, a traditional city in Nigeria was the focus of the study. Two sets of data were collected. The first was the information on the socio-economic attributes of residents obtained from 648 households through questionnaires administered using a systematic random sampling technique. The second was the measurement of waste generated in 25% of the households for a week in each of the 12 months of the year. The study established that 23.3% of the residents surveyed have educational qualifications beyond secondary school, with 51.2% engaged in occupations requiring very little or no formal education and 50.9% were in the low-income group. The daily per capita solid waste generation was 0.129 kg. The highest (9.8%) and lowest (6.5%) of the annual quantities of waste were produced in October and February, respectively. Similarly, 20.2% of the weekly generation was produced on Saturday and the 10.2% produced on Thursday was the lowest. Animal dung, which accounted for 18.0%, constituted the highest component of the total solid waste generated. The study further established that the organic component of the waste generation was 75.4%. The results of the regression analysis R2 significant at 0.001 showed that income, household size, social status, occupation, education and season of the year explained 88.8% of waste generation in Oyo. It was established that 50.90 tonnes of solid waste was generated per day in the city in 2005, and the daily generation in the year 2008 is estimated to be 55.20 tonnes. The study concluded that with an average annual population growth of 13 000 people for the town, an additional 1.3 acres of land will need to be legally acquired annually, implying that 10.92-19.68 hectares ill be required as dump site(s) over the next 20-30 years.     

INTERNATIONAL CONFERENCE ON WATER AND HUMAN HEALTH1

The following paper was presented by Dr. Abel Wolman at the Plenary Session of the 22nd Annual Conference of the American Water Resources Association in Atlanta, Georgia, November 10, 1986. Dr. Wolman is Professor Emeritus of Sanitary Engineering at The Johns Hopkins University. He was educated at Johns Hopkins and has received an Honorary Doctor of Engineering (1937) and Honorary Doctor of Laws (1969) from his alma mater. Dr. Wolman held a number of positions before joing the faculty of The Johns Hopkins University as Professor and Chairman of the Department of Sanitary Engineering (1937–1959). He has served as consultant for many studies and projects, in the United States and overseas, and has a long-term record of service to communities, states and governments. A long list of awards and honors include the Sedgwick Memorial Award, APHA; Arthur Sidney Bedell Award, WPCF; Hemisphere Award, inter-American Association of Sanitary Engineers; U.S. Award of the National Medal of Science; Tyler Award, Ecological Society of America; Ben Gurion Award from the State of israel; and the Gordon Maskew Fair Award, WPCA. He is author, co-author or editor of four books and over 3000 technical publications, most in refereed journals.