Design parameters for fixed bed reactors of activated carbon developed from fertilizer waste for the removal of some heavy metal ions

Activated carbon, developed from fertilizer waste, has been used for the removal of Hg²⁺, Cr⁶⁺, Pb²⁺, and Cu²⁺. Mass transfer kinetic approach has been successfully applied for the determination of various parameters necessary for designing a fixed-bed absorber. Parameters selected are the length of the (PAZ) primary adsorption zone (δ), total time involved for the establishment of primary adsorption zone (t_x), mass rate of flow to the absorber (F_m), time for primary adsorption zone to move down its length (t_δ), amount of adsorbate adsorbed in PAZ from breakpoint to exhaustion (M_s), fractional capacity (f), time of initial formation of PAZ (t_f) and per cent saturation of column at break point. Chemical regeneration has been achieved with 1 M HNO₃.     

Emotional social support and job burnout among high‐school teachers: is it all due to dispositional affectivity?

The authors investigated whether the relationship between the contents of emotional social support and job burnout among high‐school teachers is spurious because of the role of dispositional positive and negative affectivity. A national sample of 339 teachers was surveyed via a web‐based procedure. Hierarchical regression analyses did not support spuriousness; emotional social support was uniquely predictive of three dimensions of burnout controlling for affectivity. As positive emotional social support increased, emotional exhaustion and cynicism decreased, and professional efficacy increased. As negative emotional social support increased, emotional exhaustion and cynicism also increased. Commonality analyses based on the present data and data reported by K. L. Zellars and P. L. Perrewé (2001; Journal of Applied Psychology, 86, 459–467) provided additional support for the unique role of emotional social support on burnout, but these analyses suggest a greater role of affectivity than emotional social support. These findings have implications for research on burnout as well as the prevention of burnout among teachers. Copyright © 2006 John Wiley & Sons, Ltd.     

Assessing the Performance Level of a Water System

Water, Air, &; Soil Pollution: Focus - What should System Managers prefer? Systems that never fail or systems that remain safe during a failure? The present paper tries to give an answer to this...     

Review of in situ remediation technologies for lead,zinc, and cadmium in soil

This article presents a review of in situ technologies for the remediation of soils contaminated with lead, zinc, and/or cadmium. The objective of this review is to assess the developmental status of the available in situ technologies and provide a general summary of typical applications and limitations of these technologies. The literature review identified seven in situ remediation technologies—solidification/stabilization, vitrification, electrokinetic remediation, soil flushing, phytoextraction, phytostabilization, and chemical stabilization. These technologies were considered for their ability to meet a specific set of remediation objectives under a range of conditions. Each of these technologies has both strengths and weaknesses for addressing particular remedial situations discussed in the article for each of the technologies. A general summary of which technologies are most applicable to common remedial scenarios is also provided. © 2004 Wiley Periodicals, Inc.     

Electroremediation: A study of the influence of buffering behavior in contaminated soils

This article presents the results of an experimental study conducted to evaluate the behavior of two types of andisol soils found in Tenerife, Canary Islands, Spain. The soils were evaluated in relation to their buffering capacity when confronted with acid and alkaline fronts generated during electroremediation treatment. The study was conducted using a cell, which established a continuous flow of distilled water through electrode chambers to remove H⁺ and OH^? generated during electrolysis. The results indicate that the soils had sufficient buffer capacity to support variations in pH independent of the maintenance of flow of solution in the electrode chambers. Although the mechanism of migration was not affected, the flow of water favored the movement of ions by diffusion monitoring of the electrolytic current allowed for a real‐time parameter to act as an indicator of the quantity of ions available in regions near the electrodes. © 2004 Wiley Periodicals, Inc.     

TRANSIENT RESPONSE FUNCTIONS FOR CONJUNCTIVE WATER MANAGEMENT IN THE SNAKE RIVER PLAIN,IDAHO1

ABSTRACT: Increasing demands on western water are causing a mounting need for the conjunctive management of surface water and ground water resources. Under western water law, the senior water rights holder has priority over the junior water rights holder in times of water shortage. Water managers have been reluctant to conjunctively manage surface water and ground water resources because of the difficulty of quantification of the impacts to surface water resources from ground water stresses. Impacts from ground water use can take years to propagate through an aquifer system. Prediction of the degree of impact to surface water resources over time and the spatial distribution of impacts is very difficult. Response functions mathematically describe the relationship between a unit ground water stress applied at a specific location and stream depletion or aquifer water level change elsewhere in the system. Response functions can be used to help quantify the spatial and temporal impacts to surface water resources caused by ground water pumping. This paper describes the theory of response functions and presents an application of transient response functions in the Snake River Plain, Idaho. Transient response functions can be used to facilitate the conjunctive management of surface and ground water not only in the eastern Snake River Plain basin, but also in similar basins throughout the western United States.     

Steady-state analyses for reactive distillation control: An MTBE case study

An approach, based purely on steady-state analyses, for synthesizing effective control structures for reactive distillation (RD) columns is presented. The main idea is to analyze the steady-state relationships between the manipulated (input) variables and the potential controlled (output) variables to identify input–output (IO) pairings that are sensitive and avoid steady-state multiplicities providing a large range of nearly linear operating region around the base case design. Traditional SISO control loops are then implemented using these IO pairings to obtain control structures that maintain the column near the design product purity and conversion for the anticipated primary disturbances. The Niederlinski Index is used to eliminate dynamically unstable pairings in control structures with multiple loops. The approach is demonstrated on an example MTBE RD column. The impact of steady-state multiplicities on control structure design is highlighted.     

Effects of Short- and Long-Term Disturbance Resulting from Military Maneuvers on Vegetation and Soils in a Mixed Prairie Area

Loss of grassland species resulting from activities such as off-road vehicle use increases the need for models that predict effects of anthropogenic disturbance. The relationship of disturbance by military training to plant species richness and composition on two soils (Foard and Lawton) in a mixed prairie area was investigated. Track cover (cover of vehicle disturbance to the soil) and soil organic carbon were selected as measures of short- and long-term disturbance, respectively. Soil and vegetation data, collected in 1-m² quadrats, were analyzed at three spatial scales (60, 10, and 1 m²). Plant species richness peaked at intermediate levels of soil organic carbon at the 10-m² and 1-m² spatial scales on both the Lawton and Foard soils, and at intermediate levels of track cover at all three spatial scales on the Foard soil. Species composition differed across the disturbance gradient on the Foard soil but not on the Lawton soil. Disturbance increased total plant species richness on the Foard soil. The authors conclude that disturbance up to intermediate levels can be used to maintain biodiversity by enriching the plant species pool.     

Improving the Urban Stream Restoration Effort: Identifying Critical Form and Processes Relationships

Stream restoration projects are often based on morphological form or stream type and, as a result, there needs to be a clear tie established between form and function of the stream. An examination of the literature identifies numerous relationships in naturally forming streams that link morphologic form and stream processes. Urban stream restoration designs often work around infrastructure and incorporate bank stabilization and grade control structures. Because of these imposed constraints and highly altered hydrologic and sediment discharge regimens, the design of urban channel projects is rather unclear. In this paper, we examine the state of the art in relationships between form and processes, the strengths and weaknesses of these existing relationships, and the current lack of understanding in applying these relationships in the urban environment. In particular, we identify relationships that are critical to urban stream restoration projects and provide recommendations for future research into how this information can be used to improve urban stream restoration design. It is also suggested that improving the success of urban restoration projects requires further investigation into incorporating process-based methodologies, which can potentially reduce ambiguity in the design and the necessity of using an abundant amount of in-stream structures.     

A Comparison of Campfire Impacts and Policies in Seven Protected Areas

Using resource-monitoring data from seven protected areas, the effectiveness of three campfire policies—campfire ban, designated campfires, and unregulated campfires—were assessed based on the number of fire sites and the amount of tree damage. Results indicate that unregulated campfire policies permitted substantial numbers of fire sites and tree damage in campsites, although fire bans did not eliminate or even substantially decrease these problems. A designated campfire policy was effective in decreasing number of fire sites, but little difference was found among policies regarding tree damage. Given the importance of campfires to visitor experiences, campfire prohibitions could be viewed as unnecessarily restrictive based on their limited success in preventing resource damage. Conclusions encourage protected-area managers to consider designated campfire policies and prohibitions on axes, hatchets, and saws to better meet resource protection and visitor experience mandates.