Screening Approach for Principal Organic Hazardous Constituents and Products of Incomplete Combustion

The body of information presented in this paper is directed to those individuals concerned with developing or implementing screening strategies for characterizing organic emissions from incinerators and other combustion sources. The need to characterize hazardous waste incinerator emissions for multiple organic compounds has been steadily increasing for several years. The regulatory approach makes use of a type of indicator compound procedure that concentrates on principal organic hazardous constituents (POHCs). In addition to continuing interest in POHCs, interest has been growing in the types and concentrations of products of incomplete combustion (PICs). Sampling and analysis methods have been developed previously for approximately 225 of the more important POHCs and PICs. These methods may be used as components of a cost-effective screening protocol aimed at maximum characterization of emissions, whether the project budget is large or small. This paper contains a discussion of fundamental principles of several kinds of screening strategies and recommends an approach suitable for incinerators and other combustion sources. The concept of a risk-driven analysis strategy is introduced and illustrated with a simplified example.     

Experiences in Controlling Atmospheric Pollution Encountered in Pharmaceutical Manufacturing Processes

Smog aerosol can be related to sources, atmospheric transport, and particle growth through a Lagrangian model. Sample calculations indicate that the midday Pasadena aerosol is dominated by material produced in the atmosphere, and that the afternoon drop in aerosol mass is due to the advection of cleaner air. Numerical experiments suggest that control of primary particulate emissions without corresponding control of reactive gases would not substantially improve visibility.     

Establishing and using study criteria to ensure the rigor and robustness of survival compliance testing at hydroelectric dams

An elaborate set of criteria have been developed by fish managers and regulators to assure the accuracy, precision, representativeness, and robustness of survival compliance studies coordinated within the Federal Columbia River Power System in the northwestern USA. Dam passage survival, defined as survival from the dam face to the tailrace mixing zone, must be ≥96 % for spring out migrating juvenile salmonids [i.e., yearling Chinook salmon (Oncorhynchus tshawytscha) and steelhead (O. mykiss)] and ≥93 % for summer outmigrants (i.e., subyearling Chinook salmon). Survival must be estimated with a standard error ≤1.5 %. However, these quantitative benchmarks are only part of a multifaceted set of criteria, including representative dam operations, river discharge levels, and fish selection, along with tests of model validity that must be satisfied. These criteria are illustrated using acoustic-tag survival compliance studies conducted at The Dalles Dam on the Columbia River, 2010–2012. The results suggest evaluation criteria for survival compliance tests must balance the needs for rigor and robustness with the ability to reasonably perform the tests in naturally varying riverine systems.     

An uncertainty analysis of mean flow velocity measurements used to quantify emissions from stationary sources

Point velocity measurements conducted by traversing a Pitot tube across the cross section of a flow conduit continue to be the standard practice for evaluating the accuracy of continuous flow-monitoring devices. Such velocity traverses were conducted in the exhaust duct of a reduced-scale analog of a stationary source, and mean flow velocity was computed using several common integration techniques. Sources of random and systematic measurement uncertainty were identified and applied in the uncertainty analysis. When applicable, the minimum requirements of the standard test methods were used to estimate measurement uncertainty due to random sources. Estimates of the systematic measurement uncertainty due to discretized measurements of the asymmetric flow field were determined by simulating point velocity traverse measurements in a flow distribution generated using computational fluid dynamics. For the evaluated flow system, estimates of relative expanded uncertainty for the mean flow velocity ranged from ±1.4% to ±9.3% and depended on the number of measurement locations and the method of integration.

Implications:Accurate flow measurements in smokestacks are critical for quantifying the levels of greenhouse gas emissions from fossil-fuel-burning power plants, the largest emitters of carbon dioxide. A systematic uncertainty analysis is necessary to evaluate the accuracy of these measurements. This study demonstrates such an analysis and its application to identify specific measurement components and procedures needing focused attention to improve the accuracy of mean flow velocity measurements in smokestacks.     

Unique phenotypes in the sperm of the earthworm Eudrilus eugeniae for assessing radiation hazards

The earthworm, Eudrilus eugeniae is a segmented worm. It has two pairs of testes whose cells are highly proliferative. It was found that the earthworm, which is irradiated with X-ray, shows the following phenotypic changes in its sperm: fragmented acrosome in the head, break in the tail, and the appearance of zigzag sperm tail. Sperm morphology can be used as a tool to study radiation hazards in local areas. These three phenotypes were not observed in the sperm of worms exposed to different concentration of toxic chemicals such as sodium arsenate, lead acetate, and mercuric chloride. In contrast, exposure of worms to ethidium bromide caused fragmented acrosome in the head of their sperm cells.     

Effects of suburban land use on phosphorus fractions and speciation in the Upper Peruque Creek, Eastern Missouri

This field study was conducted to explore the spatial and seasonal changes in total phosphorus and fraction distribution in relation to land uses. Water samples were collected biweekly at four sampling locations, which represented different potential phosphorus sources along the Upper Peruque Creek in Eastern Missouri. Total phosphorus concentrations of > 0.8 mg/L appeared sporadically at site 2, downstream of a small community, with an average of 0.82 +/- 0.14 mg/L in fall. Particulate phosphorus accounted for approximately 80% of total phosphorus at all sampling sites, except for site 2, where approximately 50 to 75% of dissolved phosphorus was often observed. Approximately 71 and 85% of total phosphorus in the sediment was in the form of iron (III) phosphate at the headwaters and downstream sites, respectively; 29 and 15% was in the form of phytic acid at the two sites. Land uses affect the total phosphorus concentration and alternate phosphorus fraction and speciation in the creek.     

Influences of Water and Sediment Quality and Hydrologic Processes on Mussels in the Clinch River

Segments of the Clinch River in Virginia have experienced declining freshwater mussel populations during the past 40 years, while other segments of the river continue to support some of the richest mussel communities in the country. The close proximity of these contrasting reaches provides a study area where differences in climate, hydrology, and historic mussel distribution are minimal. The USGS conducted a study between 2009 and 2011 to evaluate possible causes of the mussel declines. Evaluation of mussel habitat showed no differences in physical habitat quality, leaving water and sediment quality as possible causes for declines. Three years of continuous water‐quality data showed higher turbidity and specific conductance in the reaches with low‐quality mussel assemblages compared to reaches with high‐quality mussel assemblages. Discrete water‐quality samples showed higher major ions and metals concentrations in the low‐quality reach. Base‐flow samples contained high major ion and metal concentrations coincident to low‐quality mussel populations. These results support a conceptual model of dilution and augmentation where increased concentrations of major ions and other dissolved constituents from mined tributaries result in reaches with declining mussel populations. Tributaries from unmined basins provide water with low concentrations of dissolved constituents, diluting reaches of the Clinch River where high‐quality mussel populations occur.     

Achieving public participation in coastal zone environmental impact assessment

The case is made in this paper for early and integrative public participation in planning decisions concerning proposals major development in the zone. This is perhaps easy to subscribe to in theory but much more difficult in practice. Currently the extent and timing of public involvement in such decisions varies widely. A key benefit is the legitimacy that public participation provides to the planning process and, perhaps as a result, a variety of public involvement methodologies have emerged. Important considerations include which sections of the public to involve and at what stage in the decision-making process to involve them. The multidisciplinary nature of coastla zone issues will tend to engage a wide variety of stakeholder groups who in turn will influence the topics for discussion. A major port expansion proposal in the UK is used to illustrate a range of ways in which the public can be involved. The case study also highlights that public participation is an uncertain science, and to be successful can require skilled personnel and significant resources. The papper concludes that more guidance for developers, some standardisation of public involvement, training for facilitatiors and a more responsible stance from some environmental pressure groups would be advantageous. The complexity of coastal decision-making, tensions between science and policy, and the inter-dependency of coastal activities mutually reinforce the view that inclusive participation is an important issue for all coastal communities.     

Community gardens and sustainable land use planning: A case-study of the Alex Wilson community garden

An analytical account of the history and aspirations of the Alex Wilson Community Garden in Toronto provides an ideal opportunity to examine the connections between two typically distinct enterprises: ecological restoration and community gardening. These are both important contemporary ecological movements, but are rarely combined in a single project that demonstrates the principles of sustainable land use and community planning. The garden is named in memory of Alex Wilson, a landscape designer, community activist and writer who worked and lived in Toronto, Canada. During his life, Wilson established a community garden which was eventually replaced by conventional urban development. After his death in 1993, friends and colleagues decided to honour his memory by establishing a permanent community garden in his name. The Alex Wilson Community Garden opened to the public in June 1998. The case-study explores how the garden reflects Wilson's work by linking community gardening and ecological restoration. These features are unified in Wilson's work as a means of nurturing relationships between people, communities and the landscape—relationships that are social, economic and ecological. In his book,The Culture of Nature: North American landscape from Disney to the Exxon Valdez (1991), Wilson argues that “we must build landscapes that heal and empower, that make intelligible our relations with each other and the natural world”. The Alex Wilson Community Garden illustrates in a practical manner the principles espoused by Wilson through its design, planning and functioning. The case-study reports on the innovative approach to landscape design taken in the garden, which reconstructs the natural and cultural history of southern Ontario, featuring lake-shore, agricultural and woodland sections. The garden has been planted exclusively with native plant species, and is expected to have a positive impact on local biodiversity. The planning process which led up to the design of the garden was participatory in nature, encompassing friends and colleagues of Alex Wilson, local residents and city planning officials, and made use of a number of planning tools not usually applied in an urban setting, including the granting of a conservation easement. The garden also addresses emerging issues associated with globalisation and large cities by providing food production opportunities for local residents, including a low-income housing complex and a nearby drop-in centre. Ecological monitoring and assessment of the naturalised area will be carried out by local residents.     

RECHARGE OF THE SNAKE RWER PLAIN AQUIFER: TRANSITIONING FROM INCIDENTAL TO MANAGED1

ABSTRACT: Declining ground-water levels and spring discharges have heightened water user concerns about the sustainability of the Snake River Plain aquifer in southern Idaho. Diminished recharge from surface water irrigation and increased irrigation pumping have been depleting the aquifer at a rate of about 350,000 acre-feet/year. Previously, aquifer conditions were treated as an uncontrollable consequence of weather and development activities. With increasing competition for available water, the State appears to be progressing through a three-stage process of recharge management. The first stage is that which has occurred historically, where recharge is largely an incidental effect of surface water irrigation. The second stage is the implementation of intentional recharge with little regard to identifying or maximizing benefits. Idaho has been at this stage for the past few years. The State is entering a third stage in which recharge sites will be located and designed to meet specific water user and environmental objectives. Preliminary estimates using numerical and analytical models demonstrate that managed recharge within a few miles of the river will result in short-term increases in spring discharge. More distant recharge sites are needed to provide longer-term benefits. The primary challenge facing implementation of the managed recharge program will be the balancing of economic and environmental costs and benefits and to whom they accrue.