Dissolved organic nitrogen regulation in freshwaters

Dissolved organic nitrogen (DON) has been hypothesized to play a major role in N cycling in a variety of ecosystems. Our aim was to assess the seasonal and concentration relationships between dissolved organic carbon (DOC), DON, and NO3- within 102 streams and 16 lakes within catchments of differing complexity situated in Wales. Further, we aimed to assess whether patterns of land use, soil type, and vegetation gave consistent trends in DON and dissolved inorganic nitrogen (DIN) relationships over a diverse range of catchments. Our results reinforce that DON constitutes a significant component of the total dissolved N pool typically representing 40 to 50% of the total N in streams and lakes but sometimes representing greater than 85% of the total dissolved N. Generally, the levels of DON were inversely correlated with the concentration of DIN. In contrast to DIN concentrations, which showed distinct seasonality, DON showed no consistent seasonal trend. We hypothesize that this reflects differences in the bioavailability of these two N types. The amount of DON, DOC, and DIN was significantly related to soil type with higher DON export from Histosol-dominated catchments in comparison with Spodosol-dominated watersheds. Vegetation cover also had a significant effect on DON concentrations independent of soil type with a nearly twofold decrease in DON export from forested catchments in comparison with nonforested watersheds. Due to the diversity in catchment DON behavior, we speculate that this will limit the adoption of DON as a broad-scale indicator of catchment condition for use in monitoring and assessment programs.     

Using PCDD/F congener patterns to determine the source of elevated TEQ concentrations in cows milk: a case study

PCDD/F congener profiles have been used to determine the source of elevated TEQ concentrations in cows' milk collected in the vicinity of several industrial sites. Principal components analysis and modelling of the air-to-milk transfer of individual PCDD/F congeners have shown that the milk fingerprint was related to that of sediment taken from the River Rother adjacent to the farm where the cows had grazed. It is suggested that sediment from the river had been washed onto the grazing land during periods of flooding, and this had been ingested by the grazing cows. This pathway could represent an important route of contaminant intake for livestock grazing on the regularly inundated floodplains of rivers containing contaminated sediments.     

Photocatalytic oxidation of NOx gases using TiO2: a surface spectroscopic approach

The bandgap of solid-state TiO2 (3.2 eV) enables it to be a useful photocatalyst in the ultraviolet (lambda < 380 nm) region of the spectrum. A clean TiO2 surface in the presence of sunlight therefore enables the removal of harmful NOx gases from the atmosphere by oxidation to nitrates. These properties, in addition to the whiteness, relative cheapness and non-toxicity, make TiO2 ideal for the many de-NOX catalysts that are currently being commercially exploited both in the UK and Japan for concrete paving materials in inner cities. There is need, however, for further academic understanding of the surface reactions involved. Hence, we have used surface specific techniques, including X-ray photoelectron spectroscopy and Raman spectroscopy, to investigate the NOx adsorbate reaction at the TiO2 substrate surface.     

Relationship of soil test phosphorus and sampling depth to runoff phosphorus in calcareous and noncalcareous soils

A study was initiated to investigate the relationship between soil test P and depth of soil sampling with runoff losses of dissolved molybdate reactive phosphorus (DMRP). Rainfall simulations were conducted on two noncalcareous soils, a Windthorst sandy loam (fine, mixed, thermic Udic Paleustalf) and a Blanket clay loam (fine, mixed, thermic Pachic Argiustoll), and two calcareous soils, a Purves clay (clayey, smectitic, thermic Lithic Calciustoll) and a Houston Black clay (fine, smectitic, thermic Udic Haplustert). Soil (0- to 2.5-, 0- to 5-, and 0- to 15-cm depths) and runoff samples were collected from each of the four soils in permanent pasture exhibiting a wide range in soil test P levels (as determined by Mehlich III and distilled water extraction) due to prior manure applications. Simulated rain was used to produce runoff, which was collected for 30 min. Good regression equations were derived relating soil test P level to runoff DMRP for all four soil types, as indicated by relatively high r2 values (0.715 to 0.961, 0- to 5-cm depth). Differences were observed for the depth of sampling, with the most consistent results observed with the 0- to 5-cm sampling depth. Runoff DMRP losses as a function of the concentration of P in soil were lower in calcareous soils (maximum of 0.74 mg L(-1)) compared with noncalcareous soils (maximum of 1.73 mg L(-1)). The results indicate that a soil test for environmental P could be developed, but it would require establishing different soil test P level criteria for different soils or classes of soils.     

Behaviour and transport of radionuclides in soil and vegetation of a sand dune ecosystem

A sand dune ecosystem in the vicinity of the British Nuclear Fuels reprocessing plant at Sellafield, Cumbria, UK was used to examine the spatial, temporal and depth distributions of 134Cs, 137Cs, 238Pu, 239 + 240Pu and 241Am in soil and in two species of vegetation (Festuca rubra, Ammophila arenaria). Core samples showed evidence of the accumulation of radionuclides derived mainly from sea-to-land transfer. Accumulated deposits of radioactivity (0-0.1 m) lie within the range: 1.1-3.4 Bq kg-1 (134Cs), 260-440 Bq kg-1 (137Cs), 31-40 Bq kg-1 (238Pu), 150-215 Bq kg-1 (239 + 240Pu) and 190-240 Bq kg-1 (241Am). Soil profiles showed greater activity concentrations in their deeper regions and this is attributed to leaching of radionuclides in percolating drainage water accentuated by the coarse texture, low organic matter and clay mineral content of coastal sands. Radionuclide activity concentrations in F. rubra and A. arenaria were similar, in the ranges 20-70 Bq kg-1 (137Cs), 1-5 Bq kg-1 (238Pu), 10-30 Bq kg-1 (239 + 240Pu) and 10-65 Bq kg-1 (241Am). Clear temporal and spatial variations were observed in both species of vegetation, reflecting the weather conditions antecedent to the sampling period and the influence of sea-to-land transfer. Concentration ratios (vegetation:soil) for activity concentrations in the two species were similar, in the ranges: 0.05-0.14 (137Cs), 0.025-0.097 (238Pu), 0.022-0.057 (239 + 240Pu) and 0.025-0.212 (241Am).     

Development and application of marine gamma-ray measurements: a review

The development of instruments to measure gamma radiation in the marine environment, particularly on the sea floor, and the range of uses to which they have been put is reviewed. Since the first steps in the late 1950s, systems have been developed in at least 10 countries with the main thrust occurring in the 1970s. Development has continued up to the present, primarily in Europe and the USA. Marine gamma-ray spectrometers have been used for a range of applications including the mapping of rocks and unconsolidated sediments, mineral exploration (mainly for heavy minerals and phosphorites), sediment transport studies and investigations in relation to discharged and dumped nuclear wastes and at nuclear weapon test sites.     

EQUILIBRIUM AND TRANSIENT GLOBAL WARMING SCENARIO IMPLICATIONS FOR WATER RESOURCES IN WALES1

ABSTRACT: A methodology has been developed to predict the responses of a range of water supply sources in Wales to global warming scenarios. Hydrologically effective rainfall is predicted from temperature and precipitation for each season based on site specific formulae developed using the Meteorological Office Rainfall and Evaporation Calculation System (MORECS) and UK Surface Water Archive databases. Comparisons are then made between the effects predicted for the scenarios established from equilibrium simulations and the new Hadley Centre High Resolution Model (UKHI) transient mode results. Though very different, both suggest increased stress on water resources late in the hydrological year.     

The impact of environmental assessment on local planning authorities

Studies of two samples of 24 selected local planning authorities (LPAs) in the UK were undertaken to determine the effect of environmental assessment (EA) regulations on planning practice during their first 18 months of operation. EA has been integrated into the UK planning system without significant recourse to the courts and many LPAs regarded EA as a worthwhile and helpful procedure. However, several LPAs did not consider whether to request EA for projects that might be likely to have significant impacts and some LPAs did not follow statutory and recommended consultation procedures. LPAs did not evaluate environmental statements systematically and their quality was often unsatisfactory. However, mitigation of environmental impacts took place in many cases though two‐fifths of the 20 determined applications involving EA were refused. Half the decisions took longer than the 16‐week time limit. While practice is evolving as experience is gained, there is obvious scope for further improvement and suggestions are made to enhance the contribution of EA to the planning system.     

LANGUAGE CONSTRAINTS TO WATER RESOURCE UTILIZATION1

ABSTRACT: Worldwide development of water resources and control of pollution would be improved by the ability for direct, multilateral communication between workers in the dozens of different language communities involved. Current language-based problems which should be eliminated include (1) incomplete diffusion of scientific knowledge, (2) technical inbreeding, (3) unsatisfactory international conferences, (4) money wasted on translation, and (5) unstandardized technical terminology. General education in a common second language for international use can eliminate these conditions. Ethnic languages are not qualified for this purpose, because of their national biases and extreme learning difficulties. The Esperanto language is free of these limitations, and its application is recommended as a means for improving the overall performance of the industry.     

Salinity-temperature profiles in the Panama Canal Locks

In discussions concerning the possible construction of a Panamá sea-level canal it has been assumed that Gatún Lake, part of the present canal, acts as a fresh-water barrier to the migration of marine animals from either end of the Canal to the other. Methodical documentary salinity determinations have not been made previously, and only a few surface salinity observations have been recorded. Determinations of salinity-temperature profiles made in spring and fall, 1972, show essentially freshwater to be present from Miraflores Lake, through the Pedro Miguel Locks, through Gatún Lake, to, and including, the upper chambers of the Gatún Locks. With the exception of those of the lower chamber of the Miraflores Locks, the profiles indicate homogeneity and thorough vertical mixing of all water masses in the lock systems and lakes of the canal. Homogeneity of the water in the lock chambers is thought to be due to turbulence during filling of the chambers, to the piston-effect of large ships moving into the chambers, to the action of ships' propellers, and to density currents established as the lock gates are opened. Water in the approach channel at the Pacific end appears to be more homogeneous than that at the Atlantic end. The Panama Canal does, in fact, constitute a fresh-water barrier to the migration of the stenohaline marine biota of the Pacific and Atlantic Oceans.